高温氧气条件下CrNiMo钢的摩擦磨损特性研究

以CrNiMo钢和H96黄铜组成配副,利用QG-700型高温气氛摩擦磨损试验机,研究了高温氧气气氛环境中滑动速度、接触压力等对CrNiMo钢摩擦学特性的影响.采用扫描电子显微镜(SEM)和能谱仪(EDS)对磨损表面进行表征.结果表明:在高温氧气气氛中,随着滑动速度和接触压力的增大,摩擦因数逐渐减小,磨损率逐渐增大.在滑动速度和接触压力逐渐增大的过程中,CrNiMo钢的主要磨损机制由粘着磨损转变为氧化磨损.     

氮/氧混合气氛环境下钢/铜摩擦副摩擦学性能研究

应用QG-700型高温气氛摩擦磨损试验机,研究了常温下CrNiMo钢/黄铜配副在不同氮/氧混合气氛比例条件下的干滑动摩擦磨损性能,利用扫描电子显微镜(SEM)、EDAX能谱仪(EDS)和X射线光电子能谱仪(XPS)分析其磨损机制。试验结果表明:随着氮/氧混合气氛中氧气气氛比例的增加,销试样磨损率和配副的摩擦因数整体均呈现降低趋势;磨损机制逐渐由黏着磨损和磨粒磨损向氧化磨损、磨粒磨损和黏着磨损共同作用机制转变;摩擦表面生成铁和铜的氧化物,且氧化物的成分随着氧气含量不同而有所不同。     

二氧化碳气氛下钢铜摩擦副摩擦磨损特性研究

应用MMS-1G销盘式高温高速摩擦磨损试验机,研究了二氧化碳气氛条件下CrNiMo钢/H96黄铜配副的干滑动摩擦磨损特性。结果表明:摩擦因数随着载荷和速度的增加而减小;磨损率随着载荷和速度的增加而增加,在逐步增加速度与载荷的过程中,存在着摩擦磨损机制的转变,CrNiMo钢的磨损机制主要表现为粘着磨损和磨粒磨损。     

氧气气氛条件下钢铜摩擦副摩擦磨损特性研究

利用MMS-1G销盘式高温高速摩擦磨损试验机,研究了氧气气氛条件下CrN iMo钢/H96黄铜配副的干滑动摩擦磨损特性,并分析了磨损机制,结果表明:纯氧气气氛条件下,摩擦因数随着载荷和速度的增加而减小;磨损率随着载荷和速度的增加而增加。在逐步增加速度与载荷的过程中,存在着摩擦磨损机制的改变。CrN iMo钢磨损失效机制主要表现为氧化磨损、剥落磨损、粘着磨损和磨粒磨损。     

CrNiMo钢在不同氧气含量气氛中的高温摩擦磨损性能

利用QG-700型摩擦磨损试验机,研究与H96黄铜配副的CrNiMo在不同氧气含量环境中的高温摩擦磨损性能,并利用扫面电镜对磨损表面进行表征。结果显示,在较低速度和载荷条件下,气氛环境中氧气含量的增加对与黄铜配副的CrNiMo钢摩擦磨损性能影响较小;在较高速度和载荷条件下,CrNiMo钢摩擦因数与磨损率随气氛环境中氧气含量的增加而减小。随气氛中氧气含量的增加,在摩擦接触表面形成不同的表面膜,使CrNiMo钢的磨损机制发生变化,由黏着磨损为主转变为黏着磨损和氧化磨损共同作用然后到氧化磨损。     

高温不同气氛环境中的CrNiMo钢磨损表面SEM和XPS分析

在200 ℃温度条件下,分别在氧气和氮气气氛环境中,以 CrNiMo 钢销试样和 H96 黄铜盘配副,在QG-700型销盘摩擦试验机上进行了摩擦磨损试验.利用 SEM 和 XPS 对 CrNiMo 钢磨损表面进行了表征.结果表明,在2种气氛环境中,都发生了粘着磨损;在氧气气氛环境和较低载荷条件下,粘着较氮气气氛环境中的严重,且磨损表面有 CuO存在,而在氮气气氛环境中,表面粘着物主要为单质铜.     

不同湿度环境中钢/铜配副摩擦磨损性能研究

应用QG-700型高温气氛摩擦磨损试验机研究了CrNiMo钢/黄铜配副在不同环境湿度条件下的滑动摩擦磨损性能,利用三维形貌轮廓仪、EDAX能谱分析仪(EDS)分析了其磨损机制。结果表明:随着环境气氛湿度的增加,配副的摩擦因数、销/盘试样磨损率和摩擦温度均呈降低趋势,摩擦学性能得到改善。销试样的磨损机制主要为黏着磨损,环境湿度的增大弱化了配副材料的黏着磨损。     

高速干滑动条件下钢/铜摩擦副摩擦磨损表面摩擦热规律研究

利用MMS-1G高温高速销-盘摩擦磨损试验机,以钢/铜摩擦副为研究对象,进行摩擦磨损试验,使用热电偶对摩擦表层进行测温,应用JSM-5610LV型扫描电子显微镜对摩擦表面进行观察,研究在高速干摩擦条件下摩擦热的影响因素及对表面磨损机制的影响。结果表明:摩擦表面的温度随着速度、载荷的增加而增加;在摩擦初期摩擦温度显著增加,摩擦因数快速下降,当达到某一数值后形成一个动态的平衡;随着摩擦温度的升高,磨损机制发生转变,由粘着磨损转变为磨粒磨损和粘着磨损共同作用。     

永磁场条件下45钢与GCr15钢摩擦磨损性能试验研究

基于HSR-2M高速往复摩擦磨损试验机,研究在永磁体磁场条件下滑动速度、载荷等参数对45#钢/GCr15钢摩擦副摩擦学性能的影响,通过磨痕形貌分析其磨损机制,并与无磁场条件下的试验结果进行对比。试验结果表明:磁场的引入可以在一定程度上减小摩擦因数和降低磨损率,证明磁场能够改善45#钢/GCr15钢摩擦副的摩擦学性能;增大滑动速度将降低摩擦因数和磨损率,增大载荷将降低摩擦因数,增加磨损率。无磁场时,摩擦副的摩擦磨损为典型的磨粒磨损,磨损系统的磨损率和摩擦因数较大;有磁场时,磨损形式主要为黏着磨损,摩擦因数和磨损率较小。     

紫铜/铬青铜摩擦副在干摩擦和水雾条件下的载流摩擦磨损性能研究

在HST-100载流高速摩擦磨损试验机上,对比考察了紫铜/铬青铜摩擦副在干摩擦和水雾2种状态下的载流摩擦磨损性能,采用扫描电镜(SEM)对磨损表面形貌进行了观测。结果表明:水雾条件下销试样载流摩擦磨损时,其摩擦因数及磨损率均低于纯载流状态下;该试样在纯载流条件下的磨损机制主要为粘着磨损和电气磨损,在水雾条件下主要为电弧侵蚀、塑性变形和轻微的粘着磨损。这是因为水有利于降低摩擦副接触表面的温度,有效地抑制了铜的转移,阻止了粘着磨损的发生。水因素的介入也导致了电弧发生频率的增多,但在综合影响下,水可以有效地改善该试样的磨损性能。     

Thermal wear and electrical sliding wear behaviors of the polyimide modified polymer-matrix pantograph contact strip

In the present study, the polyimide resin (PI)/cashew-modified resin (YM) polymer-matrix pantograph contact strip (PMPCS) was prepared by using hot repressing, hydro-solidification and dipping treatment processes. The thermal properties of cured resins were studied by thermogravimetry analyzer and differential scanning calorimetry. The thermal wear and electrical sliding wear behaviors of PMPCS against copper were evaluated by a ring block wear tester at elevated temperature under dry sliding conditions and a wear tester which simulated the train motion under laboratory conditions, respectively. Worn surfaces and wear debris of PMPCS were analyzed by scanning electron microscopy and energy dispersive spectrometer, and the wear mechanism was discussed. It has been found that the thermal stability of the PI/YM is superior to that of the YM under the same testing conditions. The results also showed that PI/YM-PMPCS had superior wear resistance than that of YM-PMPCS at elevated temperature and with electrical current. At elevated temperature, the wear mechanism of tribological pair evolved from adhesive wear to oxidative wear with mild delamination wear. Arc erosion wear, oxidative wear, and adhesive wear were the dominant mechanisms of tribological pair during the electrical wearing process.     

Environmental effects on the formation process of adhesive wear particles

Three kinds of experiments have been conducted to study the effect of environmental molecules on the formation process of adhesive wear particles. First, the growth process of transfer particles was continuously observed by scanning electron microscope. It was understood that the growth of the transfer particles was due to the continuous conversion of the disc surface material into transfer particles. Next, wear tests between a Sn pin and Sn disc were conducted in an oxygen environment from 7 × 10⁻³ Pa to 1.0 × 10⁵ Pa. The size and hardness of wear particles and the wear volume increased with increasing oxygen pressure. Wear tests between Sn and Sn were also conducted while Au metals were sputter-deposited onto the friction surface. The deposition of Au had the same effect on the size and hardness of the wear particles as the oxygen atmosphere. In general, the hardness of metals is increased by the small amount of impurity atoms in them. The inclusion of oxygen or gold atoms on the surface and in the transfer particle is supposed to have the same effect of enhancing the shear strength of the interface and the transfer particles. This is the possible mechanism of the continuous shear fracture within the bulk which results in the growth of transfer particles.     

The Effects of Sodium Chloride Solution on Fretting Wear Behavior of Nickel Based Alloy in Partial Slip Regime

The investigations on fretting wear behaviors of nickel based alloy in NaCl solution and atmosphere indicated that wear mechanism and regional transformation from partial slip regime (PSR) to the mixed regime (MR) are significantly affected by NaCl solution. The crevice corrosion induced by synergy of chloride ion and deformed asperities caused wear mechanism changed from adhesive and oxidation wear (PSR in atmosphere) to abrasive and oxidation wear (PSR in NaCl solution) and to oxidation and delamination wear (MR in NaCl solution), meanwhile accelerated the regional transformation from PSR to MR. However, the annular fatigue crack was almost unaffected by NaCl solution, which propagated along the direction of 40-50^° to surface in the mode of transgranular and intergranular in all conditions.     

Wear of spray deposited Al–6Cu–Mn alloy under dry sliding conditions

The dry sliding wear of spray deposited Al–6Cu–Mn alloy was studied as a function of applied load in the range of 5–400 N. The variation of wear rate with applied load was obtained, from which four regions can be observed. On the basis of observations and analyses on the worn surface, the worn subsurface, the wear debris and friction coefficient, wear mechanism in different regions has been identified. Two wear regimes, i.e. mild and severe wear, were displayed in the entire applied load range. The transition from mild to severe wear occurred at a critical load. Mild wear involves three regions in the wear rate vs. load variation, and the wear in each region was controlled by different wear mechanism. With increasing load, the dominant wear mechanism in the period of mild wear displays successively oxidative wear, delamination and subsurface-cracking assisted adhesive wear. Severe wear was operated by the adhesive wear mechanism and the wear debris was formed by the shear fracture of subsurface material of the pin. The transition from mild to severe wear depended on the strength of the material of the pin adjacent to the contact surface and the strain-induced shear stress created by applied load.     

Effect of Sintering Temperature and Atmosphere on Nonlubricated Sliding Wear of Nano-Yttria-Dispersed and Yttria-Free Duplex and Ferritic Stainless Steel Fabricated by Powder Metallurgy

The nonlubricated sliding wear behavior of nano-yttria-dispersed and yttria-free duplex and ferritic stainless steel against a diamond tip was studied. The stainless steel samples were fabricated by a conventional powder metallurgy route in which nano-yttria-dispersed and yttria-free duplex and ferritic stainless steel powders were cold compacted and then conventionally sintered at either 1000, 1200, or 1400°C in an argon atmosphere. For comparison, another set of samples was sintered at 1000°C in a nitrogen atmosphere. The wear behavior of sintered stainless steel samples against a diamond indenter was investigated using a pin-on-disc apparatus at 10 and 20 N loads and at a constant speed of 0.0041 m/s. It is proposed that yttria-dispersed stainless steels showed higher wear resistance compared to yttria-free stainless steel due to their improved hardness and density. Stainless steel sintered in a nitrogen atmosphere exhibited better wear resistance than those sintered in an argon atmosphere due to the formation of hard and brittle Cr₂N. The wear mechanisms of stainless steels against diamond were found to be mainly abrasive and oxidative. Semiquantitative analysis of the worn surfaces and wear debris confirmed the occurrence of oxidation processes during wear.     

Effect of Cold Rolling on the Fretting Wear Behavior and Mechanism in Inconel 690 Alloy

The influence of cold rolling on the fretting wear behavior and mechanism of Inconel 690 alloy at 320?°C in air was studied. The wear volume and worn surface were obtained and analyzed using laser scanning confocal microscopy, electron back-scattering diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The grinding surface and strain distribution were also studied by electron back-scattering diffraction to analyze the mechanism of fretting damage. The results indicated that with an increase in cold rolling reduction, the microhardness was increased. However, the friction coefficient and wear volume first increased and then decreased. The characteristics of fretting areas changed from a gross slip regime to a partial slip regime. Accordingly, the damage mechanism in the gross slip regime was a combination of oxidative wear, abrasive wear, and delamination, whereas the damage mechanism in the partial slip regime was mainly adhesive wear.     

Microstructures and High-Temperature Friction–Wear Performance of Laser-Remelted WC-12Co Coatings by HVOF

A WC-12Co coating prepared by high-velocity oxygen fuel (HVOF) was remelted with a CO₂ laser, and the surface–interface morphologies, plane energy spectrum, and phases of the coating were analyzed by means of field emission scanning electron microscopy (FESEM), energy-dispersive spectrometry (EDS), and X-ray diffraction (XRD), respectively. The friction and wear behaviors of the WC-12Co coating were investigated at high temperature with a wear test, and the morphologies and the changes in chemical elements on the wear scar after the wear test were analyzed with SEM and EDS, respectively. In addition, the influence of high temperature on the coefficient of friction (COF) and wear performance is discussed. The results show that the substrate is closely bonded with the substrate after laser remelting (LR), which includes mechanical bonding accompanied by metallurgical bonding. The average coefficient of friction (COF) at 600, 700, and 800°C is 0.6832, 0.3957, and 0.1922, respectively. The wear mechanisms of WC-12Co coating at 600 and 700°C are adhesive wear, abrasive wear, and oxidative wear, respectively, and the wear mechanism of the coating at 800°C is serious oxidative wear.     

低温液氮冷却下高速切削淬硬钢的切屑形成及刀具磨损

针对低温液氮冷却下淬硬钢高速车削过程中切屑形成及刀具磨损机理尚缺乏相关研究的问题,开展了液氮冷却下的淬硬钢高速切削研究,并与干切进行了对比.分析了切削力、切削温度、切屑特征以及刀具磨损特征,讨论了冷却润滑、切屑形成及刀具磨损机理.结果表明:与干切相比,各组实验中低温液氮冷却切削的切削温度降低了6.9％～9.9％,因材料...     

The influence of oxygen on the friction and wear behaviour of a copper—steel couple under electric current

The tribological behaviour of a copper—steel couple similar to those in electrified railways has been studied as a function of mechanical, electrical, and environmental parameters. The experimental results obtained in an oxygen atmosphere show that this factor has a major influence on the wear behaviour. While there was a reduction in the average coefficient of friction compared to in argon, under oxygen there was twice the wear found under air, and six times that found under argon. In the absence of an electric current, the nature of the wear was essentially mild adhesive. However, with an electric current at the interface, fluctuations, particularly at high intensities, were recorded in both the coefficient of friction and the electrical contact resistance, and there was severe wear. Discussion of the results is based on examination of the wear surfaces and analysis of the phenomena observed during sliding contact.