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Phase Equilibria in the Quaternary System Ti-Al-C-N 总被引:2,自引:0,他引:2
The quaternary system Ti-Al-C-N and its binary and ternary boundary systems are investigated using powder methods and XRD analysis. Phase equilibria at 1375°C are presented in an isothermal network for alloys up to 50 at.% Ti. In the vertical section Ti2 AIC1-x -Ti2 AlN1-x a complete series of solid solutions exists at 1495°C, but a wide miscibility gap occurs at 1375°C. The vertical section Ti3 AlC1-x -Ti3 AlN1-x is more complex because of the occurrence of the quaternary, tetragonally distorted phase Ti3 Al(C,N)1-x ( a = 0.41135(4) nm, c = 0.41366(5) nm) and the transformation of perovskite-type Ti3 AlN1-x into filled Re3 B-type Ti3 AlN1-x below 1200°C. 相似文献
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Polyurethane prepared from tetramethylene glycol and diisocyanate was exposed in the form of films to small pressures of NO2 and to NO2 plus air. Tensile strength was measured as a function of exposure time and temperature with an apparatus especially constructed for the purpose of measuring mechanical properties in different environmental “atmospheres.” 相似文献
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Douwe W. van der Meer Daniel Milazzo Aldo Sanguineti G. Julius Vancso 《Polymer Engineering and Science》2005,45(4):458-468
It is known that friction deposited polytetrafluoroethylene (PTFE) layers are able to nucleate crystallization of thin films of isotactic polypropylene (iPP). In order to investigate the influence of PTFE on the crystallization behavior and morphology of iPP in bulk, PTFE‐particles of two different sizes in various concentrations were melt‐blended with iPP and subsequently processed by injection molding. For one size of particles, high resolution scanning electron microscopy (HR‐SEM) showed the presence of a PTFE scaffold consisting of highly fibrillated PTFE particles. With X‐ray diffraction (WAXD) pole‐figures, it was evidenced that, after melting and recrystallization of the iPP matrix, a strongly oriented crystallization of iPP on this PTFE scaffold takes place (quiescent crystallization conditions). With WAXD it was also shown that under processing conditions, PTFE acts as a nucleating agent for iPP and that PTFE strongly enhances the formation of processing induced morphologies. Impact and tensile performance of the mixtures were measured. Both the strain energy release rate (GI) and the E‐modulus were found to increase upon introducing PTFE in iPP. POLYM. ENG. SCI., 45:458–468, 2005. © 2005 Society of Plastics Engineers. 相似文献
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Julius Parulek Daniel Jönsson Timo Ropinski Stefan Bruckner Anders Ynnerman Ivan Viola 《Computer Graphics Forum》2014,33(6):276-287
Molecular visualization is often challenged with rendering of large molecular structures in real time. We introduce a novel approach that enables us to show even large protein complexes. Our method is based on the level‐of‐detail concept, where we exploit three different abstractions combined in one visualization. Firstly, molecular surface abstraction exploits three different surfaces, solvent‐excluded surface (SES), Gaussian kernels and van der Waals spheres, combined as one surface by linear interpolation. Secondly, we introduce three shading abstraction levels and a method for creating seamless transitions between these representations. The SES representation with full shading and added contours stands in focus while on the other side a sphere representation of a cluster of atoms with constant shading and without contours provide the context. Thirdly, we propose a hierarchical abstraction based on a set of clusters formed on molecular atoms. All three abstraction models are driven by one importance function classifying the scene into the near‐, mid‐ and far‐field. Moreover, we introduce a methodology to render the entire molecule directly using the A‐buffer technique, which further improves the performance. The rendering performance is evaluated on series of molecules of varying atom counts. 相似文献