Synthesis of amphiphilic magnetic microspheres by dispersion copolymerization of styrene and poly(ethylene oxide) macromonomer

Amphiphilic magnetic microspheres ranging in diameter from 5 to 100 µm were prepared by dispersion copolymerization of styrene and poly(ethylene oxide) vinylbenzyl (PEO‐VB) macromonomer (MPEO) in the presence of Fe₃O₄ magnetic fluid. The effects of various polymerization parameters on the average particle size were systematically investigated. The average particle size was found to increase with increasing styrene concentration and initiator concentration. It also increased with decreasing stabilizer concentration and molecular weight of MPEO. The content of the hydroxyl groups localized in the microspheres ranged from 0.01 to 0.2 mmol g^?1. © 2003 Society of Chemical Industry     

Recovery of gold cyanide using inherently conducting polymers

Removal of gold from basic solutions containing [Au(CN)₂]^? has been demonstrated using the inherently conducting polymer polypyrrole. Polymers containing sulfonated aromatic dopants have been found to display a significant ability to remove gold from such solutions. Experiments performed in solutions containing both gold and copper cyanide complexes indicate that the recovery process is not highly selective. However, the polypyrroles used display significantly faster rates of gold recovery than activated carbon. © 2003 Society of Chemical Industry     

High-performance MIM capacitor using ALD high-k HfO/sub 2/-Al/sub 2/O/sub 3/ laminate dielectrics

For the first time, we successfully fabricated and demonstrated high performance metal-insulator-metal (MIM) capacitors with HfO/sub 2/-Al/sub 2/O/sub 3/ laminate dielectric using atomic layer deposition (ALD) technique. Our data indicates that the laminate MIM capacitor can provide high capacitance density of 12.8 fF//spl mu/m/sup 2/ from 10 kHz up to 20 GHz, very low leakage current of 3.2 /spl times/ 10/sup -8/ A/cm/sup 2/ at 3.3 V, small linear voltage coefficient of capacitance of 240 ppm/V together with quadratic one of 1830 ppm/V/sup 2/, temperature coefficient of capacitance of 182 ppm//spl deg/C, and high breakdown field of /spl sim/6 MV/cm as well as promising reliability. As a result, the HfO/sub 2/-Al/sub 2/O/sub 3/ laminate is a very promising candidate for next generation MIM capacitor for radio frequency and mixed signal integrated circuit applications.     

Transmission loss allocation based on a new quadratic loss expression

This paper presents a derivation of a new quadratic expression for the transmission loss in a power system. The main advantage of this expression is the improvement in accuracy over the other existing approximations. Furthermore, this improved quadratic form allows the transmission loss to be expressed in terms of nodal power injections. This paper builds on the derived loss expression and proposes a bus-loss matrix. This matrix is useful in quantifying the interactions among different bus power injections and establishing a loss allocation scheme for individual buses. Numerical examples are used to illustrate the accuracy of the derived quadratic form and its use in loss allocation.     

Finite-element analysis of hyperelastic thin shells with large strains

The objective of this contribution is the development of theoretical and numerical models applicable to large strain analysis of hyperelastic shells confining particular attention to incompressible materials. The theoretical model is developed on the basis of a quadratic displacement approximation in thickness coordinate by neglecting transverse shear strains. In the case of incompressible materials this leads to a three-parametric theory governed solely by mid-surface displacements. The material incompressiblity is expressed by two equivalent equation sets considered at the element level as subsidiary conditions. For the simulation of nonlinear material behaviour the Mooney-Rivlin model is adopted including neo-Hookean materials as a special case. After transformation of nonlinear relations into incremental formulation doubly curved triangular and quadrilateral elements are developed via the displacement method. Finally, examples are given to demonstrate the ability of these models in dealing with large strain as well as finite rotation shell problems.The present study is supported by a research grant of the German National Science Foundation (DFG) under Ba 969/3-1.dedicated to Prof. Dr. Dr. Erwin Stein for his 65th birthday anniversary     

Experimental studies of new ductile coupling beams and multi-storey shear walls

The span-depth ratios of coupling beams to interconnect shear walls are generally small, so that brittle shear failure may occur and lead to reduced ductility. In order to improve the ductility of coupling beams for earthquake loading, a new type of ductile coupling beam is proposed in this paper. Along the middle depth of this beam, a slit through the entire thickness (a narrow hole) near each end and two lateral keyways along the remaining middle part of the span are made. The reductions of the stiffness under service load and the ultimate carrying capacity of the beam due to the weakening mentioned above are small and the ductility is greatly increased. Tests of 4-storey walls interconnected by coupling beams in three different constructions (monolithic beams, beams with a through-slit and new-type beams) indicated that shear walls with the new coupling beams possess the best aseismic behaviours under cyclic loading. The proposed new coupling beam has been used in a high-rise building.     

激光光束质量因子的研究进展

本文详细分析了各种光场下光束质量M2因子。在不同的场中,A.E.Siegman当初所定义的M2因子,已经有了很大的变化,因而M2因子的特性也与当初不同,不仅M2因子可以大于等于1,而且可以小于1,甚至小于0。其反映的物理意义,也从经典场中的衍射极限倍数,变化为非经典场中的准直性量度以及对空间相干性的某些反映。此外还列举并分析了几种特殊的光束质量因子,最后讨论了M2因子应用的问题并指出了其局限性。