合成己二腈反应技术研究——(Ⅴ)己二腈工业反应过程模拟与反应器改造

对己二腈工业反应器提出了两釜串联带回流的模型,通过模拟计算得出模型的级间返混系数 f=6的结论。该模型能较好地预测工业反应器中物料组分浓度变化和气、液两相的流动特性;指出了现工业反应器的鼓泡中和段体积偏小是造成己二酸浓度偏高的关键;提出了可以通过增加串连一个鼓泡预反应段的改造方案,能有效地降低己二酸的浓度,从7%降至4%左右,从而能较好地减缓腐蚀和结焦。     

HPMBP与伯胺N_(1923)对希土元素(Ⅲ)的协同萃取

本文研究了HPMBP与伯胺N_(1923)的二甲苯溶液,从盐酸介质中协同萃取希土(Ⅲ)的机理。用斜率法、恒摩尔法确定了协萃配合物的组成为:RNH_3Ln(PMBP)_4。求得关于Pr(Ⅲ)协萃反应的平衡常数及协萃配合物的生成常数分别为:logK_(12)=-1.95;logβ_(12)=3.94。实验发现,协萃系数(R)随希土元素的原子序数(Z)递变而呈现“双峰效应”。还研究了协萃配合物的IR,NMR谱。     

兰州重离子加速器大型真空室

已建成的兰州重离子加速器的真空室是一个大型整体结构的超高真空容器,直径约10m,高4.5m,重65000kg,内表面积211m~2,容积100m~3,工作真空度为5×10~(-5)Pa。采用有限单元法在计算机上用SAP-5C程序对真空室受力分析进行了计算。真空室结构材料选用瑞典Uddeholm钢厂生产的316 L 超低碳不锈钢。承制此大型容器的是航天工业部风华机器厂。由于结构庞大,首先将真空室分成八大块和几小块在工厂制造,然后运至现场焊制成一整体容器并进行机械加工。所有密封焊缝均用着色渗透液,X-射线探伤和氦质谱探漏仪进行检查和探漏。     

基于DELPHI的镍氢电池管理系统软件设计

通过对镍氢电池性能的研究，给出了一个应用ISA总线技术构建的、基于DELPHI编程平台的镍氢电池管理系统的设计方案，重点介绍了该系统的软件技术和实现方法。     

防水墙技术初探

防水墙技术是一种防止内部信息向外扩散的技术。论文给出了防水墙的定义及功能特性,并通过对防水墙系统WaterBox的介绍分析,探讨了利用防水墙技术构筑内网信息安全的可行性及发展趋势。     

MSTP在3G的应用

讨论了MSTP的技术特点,指出MSTP能高效可靠传输各种业务,并结合3G网络的业务发展以及3G传输关注的接口,提出采用引入ATM功能的MSTP技术解决3G传输网络的方案.     

论王光祈的“少年中国”理想

王光祈的“少年中国”理想，是以“少年意大利”为基础，汲取五四时期社会主义思潮的积极成分而形成的。创造“少年中国”在“人”的方面，是从改造中国少年入手，同时注重青年学生与平民的改造，注重劳动阶级、智识阶级与资产阶级的改造与联合；在“事”的方面，积极开展社会事业和社会活动，且必须经过社会分工与国际分工。可见，他的这种理想是典型的社会改革主张，在早期带有无政府主义色彩，自始至终具有强烈的民族主义情感。     

Variations in Spectral Slope in Lake Taihu,a Large Subtropical Shallow Lake in China

Spectral slope (S), describing the exponential decrease of the absorption spectrum over a given wavelength range, is an important parameter in the study of of chromophoric dissolved organic matter (CDOM) dynamics, and also an essential input parameter in remote sensing models. Furthermore, S is often used as a proxy for CDOM composition, including the ratio of fulvic to humic acids and molecular weight. The relative broad range in S values reported in the literature can be explained by the different spectral ranges and fitting methods used. A single exponential model is used to fit the S values for 17 investigations involving 458 samples in Lake Taihu from January to October in 2004. The average S value was 15.18 ± 1.39 μm⁻¹ for the range of 280–500 nm, which fell within the range reported in the literature. The frequency distribution of S value basically obeyed a normal distribution. Significant differences in S values between summer and other seasons showed that phytoplankton degradation was one of the important sources of CDOM in summer, whereas CDOM mainly came from the river input in other seasons. Furthermore, the estimated S value decreased with increasing wavelength range used in regression. The maximum and minimum values derived from the regression were 17.89 ± 1.25 μm⁻¹ and 13.62 ± 2.11 μm⁻¹ for the wavelength ranges of 280–380 nm and 400–500 nm, respectively, a decrease of 23.9%. S values significantly decreased with the increase of CDOM absorption coefficients. CDOM absorption coefficients could be more appropriately estimated from exponential model introducing the variation of S with absorption coefficients, making them useful for a remote sensing bio-optical model of Lake Taihu. DOC-specific absorption coefficient a*(λ) and the parameter M describing molecular size of the humic molecules could also be used as a proxy for the sources and types of CDOM. A general relationship was found between S and a*(λ), and M values. S increased with the decrease of DOC-specific absorption coefficient and the increase of M corresponding to the decrease of molecular weight.     

锌基合金模具的应用及探讨

本文分析了锌基合金模具制造及使用过程中容易出现热裂、翘曲、收缩的问题，并提出了解决这些问题的措施。     

大型水轮发电机组励磁变压器参数及绝缘方式的选择--由三峡机组励磁系统投运引起的思考

结合三峡机组励磁系统的调试及投运经验,对大型水电机组静止自励系统选型中存在的一些关键性技术课题进行分析与论证,期望得出的结论有助于在大型水轮发电机组励磁系统参数选择和在提高机组运行安全、可靠性方面提供有益的借鉴。文中提出的励磁系统设计新理念仅代表个人的观点。