Enhanced lithium storage performance of silicon anode via fabricating into sandwich electrode

Silicon electrode with sandwich structure as anode of lithium ion batteries is fabricated by adding a carbon layer between current collector and active coating. The prepared silicon electrode with the sandwich structure can exhibit high reversible capacity of 2500 mAh g⁻¹ for 30 cycles, which is much higher than that of bare silicon electrode with normal structure. The electrochemical impedance spectroscopy and electrode morphologies characterizations show that the improved performance of sandwich electrode is attributed to the carbon layer, which not only enhances the electric conductivity at the current collector/active coating interface but also releases the rigid stress caused by volume change of silicon. The results demonstrate that such sandwich structure is a potential facile method for performance improvement of silicon-based anode compared with the previous reports.     

秘鲁特罗莫克铜矿SABC流程考查及优化措施研究

对秘鲁特罗莫克铜矿SABC流程进行了详细的考查及数据分析,查明了当前生产中SABC流程存在半自磨机磨矿效率不高、球磨机循环负荷高、旋流器分级效率低等问题。比如半自磨机的电机功率利用系数为65%～68%,排料粒度大于设计值;球磨机的循环负荷率过高,其循环负荷平均575. 71%,磨矿产品粒度组成中粗粒(≥147μm)及微细粒级(≤20μm)含量高,尤其是≤20μm粒级含量高达25%～32%,该粒级区间的金属分布率高达30. 50%～40. 81%等,没有给浮选回路创造良好的给料条件。针对这些问题,提出了提高半自磨机的入料粒度、优化半自磨机排料端结构、调整补水点位置、增加一段分级等详细的改进方案,为下一步选矿厂技术改造提供了科学依据。     

基于门控循环图卷积网络的交通流预测

交通流预测在智能交通系统的建设中起着关键性的作用,然而现有预测方法无法准确地挖掘其潜在的时空相关性,而且大都采用全连接网络进行单步预测。为了进一步挖掘数据的时空特性以及提升长短期预测的精度,提出了一种门控循环图卷积网络（GR-GCN）模型。首先,利用频域上的图卷积结合门控循环单元（GRU）构建一个时空组件（STC）以同时捕获节点的时空相关性,充分地提取数据的时空特征;然后,利用该时空组件构成编码器单元,并将时间序列数据和路网结构数据输入其中;最后,使用门控循环单元作为解码器单元,并按照时间顺序将两者组成一个编码器—解码器（encoder-decoder）结构,依次解码出每个时刻的预测结果。在加利福尼亚交通局（Caltrans）性能评估系统中高速公路数据集PeMSD4和PeMSD8进行了实验。结果表明,所提模型GR-GCN在预测未来15 min、30 min、45 min和60 min的交通流量方面优于大多数现有基准模型,尤其是在长期预测方面。     

Inhomogeneity of microstructure and mechanical properties of a 500 mm diameter heavy section semi-continuous cast AZ61 magnesium alloy ingot简

For the large magnesium alloy ingot, there is a considerable difference in cooling rate of different parts in the ingot, which leads to non-uniform distribution of the secondary phases, solute segregation and tensile properties. In the present research, an heavy AZ61 alloy ingot with a diameter of 500 mm was made by semi-continuous casting. The microstructure and mechanical properties at different positions along the radial direction of the large ingot were investigated by using an optical microscope(OM), a scanning electron microscope(SEM), an energy dispersive spectroscope(EDS), and a micro-hardness tester. The results indicate that the microstructure of the AZ61 ingot is non-uniform in different locations. It changes from equiaxed to columnar grains from the center to the edge; the average grain size gradually reduces from 1,005 μm to 763 μm, the secondary dendrite arm spacing reduces from 78 μm to 50 μm, and the Mg17(Al,Zn)12 phase is also refined. The micro-hardness value increases from 55.4 HV at the center to 72.5 HV at the edge of the ingot due to the microstructure differences, and the distribution of micro-hardness at the edge of the ingot is more uniform than that in the center. The tensile properties at room temperature show little difference from the center to the edge of the ingot except that the elongation at the edge is only 3.5%, much lower than that at other areas. The fracture mechanism is ductile fracture at the center and cleavage fracture at the edge of the ingot, and at the 1/2 radius of the ingot, a mixture of ductile and cleavage fracture is present.     

基于DIC的镍基焊材焊接接头局部力学性能研究

本文通过显微组织分析、数字图像相关技术（DIC）试验以及硬度测试,系统研究了15CrMoR母材与镍基焊材焊接接头各区域的局部力学性能。基于DIC方法获取了镍基焊材焊接接头拉伸过程的全场应变云纹发现：焊缝区域应变较小且不均匀,母材区域应变量大,热影响区均匀过渡。在此基础上构建了焊接接头不同区域的局部应力应变曲线,并揭示了焊接接头局部力学性能参数的分布规律。由焊接接头显微组织的分析可知,局部力学性能参数的分布与显微组织的分布存在密切联系。最后,结合显微硬度与强度参量在焊接接头的分布规律,构建了两者的关联方程,便于镍基焊材焊接接头局部力学参数的估算。