中空激光光内送粉熔池温度控制研究

在激光增材制造过程中,熔池温度的稳定性是表征加工过程稳定性的一个重要指标.设计一套控制熔池温度的闭环反馈系统,以达到控制熔池温度,提高成形件质量.基于C#编程软件实现了温度信号的传递,采用PID控制算法设计了温度控制器.实验结果表明,此系统能实时、准确地实现熔池温度的闭环控制,能够有效消除直壁墙熔覆过程中因热累积而造成的“蘑菇云”现象,且成形件几何精度有显著提高,各处显微组织差异较小,组织致密均匀.     

油库油料计量操作中存在的问题及其解决办法

介绍了油库油料计量中，在油品高度、油品温度和油品密度测量中存在的问题及应遵循的操作规范和注意事项。     

基于量化规则格的关联规则渐进更新*

提出一种基于量化规则格的规则更新算法,重点讨论了在新增格节点的过程中规则更新的思想,实现在格的渐增生成过程中,相应的关联规则也得到渐进更新.最后给出简单实例说明规则更新算法的正确性.     

溶液缩聚物分子量分布及其控制的研究

本文根据溶液缩聚基本原理及反应过程的基本事实，用随机过程方法，得到缩聚产物分子量分布函数，并对分子量及其分布的控制作了讨论。     

Fabricating Water-Insoluble Polyelectrolyte into Multilayers with Layer-by-layer Self-assembly

Summary A water insoluble azo-containing polyelectrolyte (PEAPB6P-AC) was successfully fabricated into multilayer films based on the layer-by-layer adsorption technique by using N, N-dimethylformamide (DMF) as the assembling media. The multilayer growth and structure were studied with UV-vis spectroscopy, and the multilayer surface were imaged with Atomic Force Microscopy and compared with that fabricated in water. The results show that assembling PEAPB6P-AC in DMF can effectively eliminate the hydrophobic aggregation of the azo units and consequently results in a much smoother multilayer surface than that fabricated in water. This improvement to the layer-by-layer adsorption technique, which can avoid some major difficulties faced when assembling hydrophobic polyelectrolytes in aqueous solutions, seems to be a versatile way to fabricate high quality multilayer films when using the hydrophobic even water-insoluble polyelectrolytes as assembling units.     

碳黑水分离技术的研究

脱油沥青作为谢尔气化工艺的气化原料生产化肥在国内尚属首次,由于沥青原料中的灰分和重金属比渣油原料大得多,若仍采用石脑油萃取碳黑技术,灰分和重金属随碳黑返回气化装置,将造成设备的堵塞、磨损,无法保证设备安稳长期运行.通过对碳黑水分离技术进行多方面的研究,寻找到适宜的工艺路线与解决方案.     

基于多判据的散乱点云特征点提取算法

为了有效获取散乱点云中的尖锐特征点和边界特征点,提出一种利用多判据融合的特征点提取算法。首先利用一种改进的k-d tree构建点云拓扑,搜索样点的K局部邻域;然后利用法向夹角判定准则、核密度判定准则、场力和判定准则分别求取各个样点局部邻域的三个特征参数,最后通过加权计算特征参数得到每个样点的特征值与全局判定阈值,特征值比阈值大的点即为特征点。实验证明,该算法能有效的获取散乱点云中边沿特征点与尖锐特征点。     

Study on performance characteristics of fused deposition modeling 3D-printed composites by blending and lamination

Component contacting degree in a composite material is an important reference for evaluation the performance characteristics. In this article, two composite material systems involving polylactic acid (PLA) with acrylonitrile butadiene styrene (ABS) and PLA with thermoplastic polyurethane (TPU) were prepared by blending and laminating through fused deposition modeling (FDM) 3D printing technology. The mechanical and thermal properties of the as-prepared composite materials were examined. The results indicated that PLA and TPU played a dominant role in tensile strength and breaking elongation, respectively, in individual composite material. ABS and TPU changed the glass transition peek, crystallinity, and modulus of PLA. The results also suggested that although the processing design of the blending method was more suitable for the contact between two components, but the mechanical properties of laminated composites were closer to theoretical predictions. The structural design and processing technology provide a comparative method and reference basis for studying the performance characteristics of composite materials.     

Engineering all-aromatic polyamide surface from hydrophilic to superhydrophobic and the accelerated strategy

Being a new kind of nanomaterials, aromatic polyamide nanofibers (ANF) have been much highlighted in recent studies. We here demonstrate an isopropyl alcohol (IPA) accelerated chemical cleavage on poly (p-phenylene terephthalamide) chopped fibers, which provides an efficient preparation method of ANF. The comprehensive study on the processes accelerated by different alcohols revealed that the preparation time of ANF in the mixed medium of dimethyl sulfoxide (DMSO)-alcohol (20:1 in volume) was shorten to 45 min and 75 min for methanol (ethanol) and isopropanol, respectively. However, the nanofibers prepared in DMSO-IPA exhibited the minimum in axial and radial dimensions, providing the finest and most uniform diameter of 16 nm. The corresponding ANF films through vacuum assisted filtration also showed the highest tensile strength of 150 MPa, in comparison with those of the ANF films prepared using other alcohols, which were about 110 MPa. Furthermore, ANF/silicon hybrid films were prepared by the ionic ring-opening reaction followed by the alkoxysilane condensation and nanoparticle fabrication. By changing the organo functional groups in the alkoxysilane, the surface of the films were adjustable in a wide contact angle range from 56° (hydrophilic) to 150° (superhydrophobic), suggesting the amendable interfacial properties potential applicable to composite fabrication with most of the resin matrix.     

高膜厚PU防腐系统在油气管道上的应用

高膜厚PU防腐系统可解决防腐工程上的死角，包括异形、补口、三通、弯头、法兰、阀门等几何形状复杂金属外表面的防腐，以及老龄在役管线的防腐结构的修复。这种防腐系统的使用寿命可达30a。对国内油气管道防腐涂层常用的国产环氧粉末防腐结构和高膜厚PU防腐结构各项技术性能指标进行了对比，又以环氧粉末和高膜厚PU防腐系统用于管道防腐和储罐防腐进行了详细的对比，论证了使用高膜厚PU防腐系统技术的可行性和经济性。