Electrolytic MgO/ZrO2 duplex-layer coating on AZ91D magnesium alloy for corrosion resistance

By a two-step fabrication process of electrolytic deposition and annealing treatment, an MgO/ZrO₂ duplex-layer coating has been prepared on AZ91D magnesium alloy as a protective film against corrosion. Owing to the chemical bonding formed after the condensation of precursory hydroxides, the adhesion strength, thickness and compactness of MgO coating on the substrate are significantly enhanced by the intermediate ZrO₂ layer which prevents the formation of corrosion product Mg₂(OH)₃Cl·4H₂O. As a result, the MgO/ZrO₂ duplex-layer coated specimen reveals relatively high corrosion resistance and superior stability in 3.5 wt% NaCl solution with respect to the MgO single-layer coated specimen.     

Effect of excess lanthanum on corrosion and magnetocaloric property of LaFe11.5Si1.5 compounds

The corrosion and magnetocaloric property of LaFe_11.5Si_1.5 compound with excess La from 0 wt% to 15 wt% were investigated by a scanning electron microscope (SEM), electrochemical workstation and a vibrating sample magnetometer (VSM). With the increase of excess La from 0 wt%, 5 wt% to 10 wt% and 15 wt%, most of the La-rich phase changes from granular La₂O₃ phase to grain boundary LaFeSi phase. The La₂O₃ is more stable than the main 1:13 phase, while LaFeSi phase is easy to be corroded than the 1:13 phase. The maximum entropy change ?ΔS_max is 18.60, 21.48, 19.66 and 16.28 J/(kg·K) for 0 wt%, 5 wt%, 10 wt% and 15 wt% excess of La, respectively. As adding 5 wt% excess La in LaFe_11.5Si_1.5 compound leads to nearly single 1:13 phase, the largest magnetic entropy change and better corrosion resistance are obtained.     

烧结保温时间对40Mo-ZrO2和40Mo-8YSZ金属陶瓷导电性能的影响

以金属钼粉、氧化锆粉和稳定氧化钇锆粉作为原料,采用粉末冶金方法制备了40Mo-ZrO₂和40Mo-8YSZ金属陶瓷试样,采用四电极法对试样的高温电导率进行了测量,研究了烧结保温时间对金属陶瓷孔隙率和导电性能的影响。结果表明: 延长烧结保温时间,颗粒出现片状集聚现象,烧结体更加致密,气孔率下降,金属陶瓷电导率提高。40Mo-ZrO₂金属陶瓷的电导率受金属相电子导电与陶瓷相离子导电的混合导电机制影响,其电导率分别在850 ℃和1200 ℃附近出现峰值。40Mo-8YSZ金属陶瓷电导率随温度升高而降低,主要受金属相电子导电机制影响。     

Coercivity kinetics upon step annealing of sintered Sm(Co_(0.88-x)Fe_xCu_(0.09)Zr_(0.03))_7 magnets

Behavior of the coercivity of the high-temperature Sm(Co_(0.88-x)Fe_xCu_(0.09)Zr_(0.03))_7 magnets depending on the temperature and time of annealing with the temperature decreasing stepwise from 700 to 400℃ was investigated.It is shown that the growth rate of coercivity abruptly increases at the initial stage of annealing in the vicinity of the Curie temperature of the SmCo_5 phase.The origin of the effect is the counter diffusion of Cu and Co atoms through dislocation tubes,which form because of enhanced stresses and a partial breakage of coherent coupling at the interface of the Sm_2 Co_(17) and SmCo_5 phases.Diffusive enrichment of the SmCo_5 phase in Cu close to the interface with Sm_2 Co_(17) leads to relaxation of stresses and increases in the gradient of the magnetic domain-wall energy and coercivity.     

Monte Carlo方法模拟晶粒在气-液-固三相体系下的各向异性生长

基于Monte Carlo方法,建立了气-液-固三相体系下晶粒生长的传质路径;根据最小能量原理,确立了最优和非最优生长取向上能量值的选取准则;采用各向异性的液-固和固-气界面能,对陶瓷晶粒的生长进行了二维模拟,并探讨了各向异性界面能量差值对晶粒形貌的影响规律。结果表明,在状态点发生相变时,引入寻找能量最低状态的过程,不仅消除了液相分布不合理现象,且晶粒边界更平直,形状更规则,质点在晶粒最优生长方向上的生长几率明显高于非最优方向;随着各向异性界面能差值的增加,晶粒的长径比基本呈线性变化,各向异性生长更突出。     

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Based on the discrete element method, a 2D slot model of COREX melter gasifier has been established. The solid flow pattern, velocity field and voidage distribution were analyzed by using the proposed model at a particle level. The results show that the solid flow pattern changes from linear mode to curving down on the both sides by means of joining tracer particles. Judging from the velocity field distribution, the solid flow can be divided into several different flow zones including dead zone, the plug flow zone and the channel flow zone. The influence of raceway in the vertical direction is limited to the region of 0. 18m from the hearth bottom level. The decrease of raceway size causes that the region of faster particles becomes small and the height of dead zone increases remarkably. The velocity distribution is asymmetric in the furnace which shows that there exits segregation phenomenon, and the voidage distribution also clarifies this phenomenon. The voidage is 0. 37 in the dead zone, while in the raceway the voidage is about 0. 65, and the voidage in the plug flow is between 0. 37 and 0. 65.     

铜对中碳硅锰钢连续冷却相变的影响

 为了探索含铜中碳硅锰钢连续冷却转变过程中的相变规律,采用DIL805L型膨胀仪研究了铜对中碳硅锰钢连续冷却过程中显微组织和硬度的影响,借助高分辨透射电镜研究了连续冷却过程中含铜相的析出行为。结果表明,在中碳硅锰钢的连续冷却过程中,铜的加入使得铁素体转变的孕育期延长,且降低贝氏体和马氏体开始转变温度。富铜颗粒在铁素体中弥散析出,细化连续相变组织。冷却速度小于21 ℃/s时,含铜中碳硅锰钢由于富铜颗粒析出以及贝氏体和马氏体组织增加引起显微硬度增加。当冷却速度大于21 ℃/s时,铜反而会降低钢中贝氏体和马氏体组织的显微硬度。     

一种有限元网格节点编号的优化算法

为提高有限元的计算效率,减少计算数据所需在存储量,提出节点编号优化算法。通过对在网格半带宽最小时的节点排列的一些特征进行分析,从其中归纳出3条规律,通过算例验证了该规律的正确性和可靠性。结果表明,对于任意划分的有限元网格,利用该方法对节点重新编号,可得到较小的半带宽值,节省了计算机的内存空间,提高了计算效率。