磨料射流铣削工艺参数优化

目的对表面粗糙度和材料去除率作为输出参数的磨料水射流铣削45#钢过程进行研究,旨在寻找最优加工参数。方法对射流去除材料机理进行了分析,设计并进行了以磨料粒度、射流压力、横向进给距离、靶距为加工工艺参数的田氏正交实验。采用Minitab对不同实验参数组合下磨料水射流加工45#钢的表面粗糙度、材料去除效率进行了数据分析,并从材料去除机理方面,对4种加工工艺参数对于铣削表面质量和材料去除效率的影响程度和影响趋势,以及各因素之间的交互作用进行了分析。结果对射流铣削面表面粗糙度影响较显著的因素是横向进给距离,射流压力次之;对于材料去除效率,磨料粒径的影响最显著,横向进给距离次之。结论综合材料去除效率和表面粗糙度值,选出最优加工参数:磨料粒径2000目,射流压力120~160 MPa,喷嘴横移距离1.0~1.5 mm,靶距约30 mm。     

折叠式托盘箱货架弯曲的有限元分析及试验验证

目的市场上的托盘箱普遍根据经验设计,其设计周期长,成本高。拟研究利用有限元模拟托盘箱性能的可行性。方法先利用三维软件Solidwokrs完成托盘箱的建模,再导入有限元分析软件Workbench模拟其货架弯曲性能,根据模拟结果修改模型,直至满足要求后进行打样制造,然后进行实际托盘箱样品的实验。结果托盘箱货架弯曲的实验结果和模拟结果总体上吻合度较高,托盘上5个试验位置挠度的相对误差随着载荷的增大而逐渐减小,并趋于稳定。结论使用有限元软件Workbench来进行托盘箱结构的设计和性能模拟分析是可行且有效的。     

Thermal conductivity and tensile response of defective graphene: A molecular dynamics study

In this study, effects of point vacancy, Stone–Wales and bivacancy defects on thermal conductivity and tensile response of single-layer graphene sheets are studied using classical molecular dynamics (MD) simulations. Using non-equilibrium molecular dynamics (NEMD) method, we found that thermal conductivity of graphene is considerably sensitive to existence of defects. It was observed that only 0.25% concentration of defects in graphene lead to significant reduction of graphene thermal conductivity by around 50%. By applying uniaxial tensile loading, we studied the deformation process of graphene. We found that elastic modulus, tensile strength and strain at failure of graphene decrease by increase of defects concentrations. Obtained results suggest that thermal conduction in graphene is much more vulnerable to defects in comparison with mechanical properties. Reported results by this work provide an overall viewpoint concerning the intensity of defects’ effects on the graphene thermal and mechanical response.     

New mechanism and improved kinetics of hydrogen absorption and desorption of Mg(In) solid solution alloy milling with CeF3

This paper presents improving the hydrogen absorption and desorption of Mg(In) solid solution alloy through doped with CeF₃. A nanocomposite of Mg_0.95In_0.05-5 wt% CeF₃ was prepared by mechanical ball milling. The microstructures were systematically investigated by X-ray diffraction, scanning electron microscopy, scanning transmission electron microscopy. And the hydrogen storage properties were evaluated by isothermal hydrogen absorption and desorption, and pressure-composition-isothermal measurements in a temperature range of 230 °C–320 °C. The mechanism of hydrogen absorption and desorption of Mg_0.95In_0.05 solid solution is changed by the addition of CeF₃. Mg_0.95In_0.05-5 wt% CeF₃ nanocomposite transforms to MgH₂, MgF₂ and intermetallic compounds of MgIn and CeIn₃ by hydrogenation. Upon dehydrogenation, MgH₂ reacts with the intermetallic compounds of MgIn and CeIn₃ forming a pseudo-ternary Mg(In, Ce) solid solution, which is a fully reversible reaction with a reversible hydrogen capacity～4.0 wt%. The symbiotic nanostructured CeIn₃ impedes the agglomeration of MgIn compound, thus improving the dispersibility of element In, and finally improving the reversibility of hydrogen absorption and desorption of Mg(In) solution alloy. For Mg_0.95In_0.05-5 wt% CeF₃ nanocomposite, the dehydriding enthalpy is reduced to about 66.1 ± 3.2 kJ⋅mol⁻¹⋅H₂, and the apparent activation energy of dehydrogenation is significantly lowered to 71.9 ± 10.0 kJ⋅mol⁻¹⋅H₂, a reduction of ～73 kJ⋅mol⁻¹⋅H₂ relative to that for Mg_0.95In_0.05 solid solution. As a result, Mg_0.95In_0.05-5 wt% CeF₃ nanocomposite can release ～57% H₂ in 10 min at 260 °C. The improvements of hydrogen absorption and desorption properties are mainly attributed to the reversible phase transition of Mg(In, Ce) solid solution combing with the multiphase nanostructure.     

The antimicrobial effects and synergistic antibacterial mechanism of the combination of ε-Polylysine and nisin against Bacillus subtilis

The aim of the present study was to evaluate the combined effects of ε-Polylysine (ε-PL) and nisin and investigate the synergistic action of these compounds against Bacillus subtilis (B. subtilis).The combination of ε-PL and nisin showed synergistic anti-microbial activity against Escherichia coli (E. coli), B. subtilis and Staphylococcus aureus (S. aureus). SEM and TEM microscopy revealed that combined treatment with ε-PL and nisin synergistically damaged the morphology of tested bacterial cells. Propidium iodide (PI) infiltration experiments indicated that combined treatment with ε-PL and nisin synergistically enhanced the permeability of the bacterial cell membrane, likely reflecting the inhibition of both Na⁺K⁺- and Ca⁺⁺ Mg⁺⁺-ATPase activities through these compounds. The fluorescence spectrum showed an interaction between ε-PL and DNA, but not between nisin and DNA. The mode of ε-PL in binding with DNA was similar to that of ethidium bromide (EB). These results indicated that the uptake of ε-PL into cells was promoted through nisin, and subsequently, ε-PL interacted with the intracellular DNA achieving a synergistic effect.     

A theoretical analysis of cohesive energy between carbon nanotubes,graphene and substrates

Explicit solutions for the cohesive energy between carbon nanotubes, graphene and substrates are obtained through continuum modeling of the van der Waals interaction between them. The dependence of the cohesive energy on their size, spacing and crossing angles is analyzed. Checking against full atom molecular dynamics calculations and available experimental results shows that the continuum solution has high accuracy. The equilibrium distances between the nanotubes, graphene and substrates with minimum cohesive energy are also provided explicitly. The obtained analytical solution should be of great help for understanding the interaction between the nanostructures and substrates, and designing composites and nanoelectromechanical systems.     

基于LS-DYNA仿真的射流加工参数分析

目的通过LS-DYNA对磨料射流冲蚀切削进行仿真,研究相关工艺参数对切削参数的影响。方法采用磨料水射流对Al_2O_3陶瓷进行了单点冲蚀仿真和切削仿真研究,其中水和磨料粒子采用SPH方法建模,氧化铝陶瓷工件采用FEM方法建模,并通过SPH-FEM耦合算法,实现射流冲蚀切削过程的仿真。结果分析射流冲蚀过程仿真和切削过程仿真可知,射流加工前期,由于射流中磨粒碰撞与反弹,使壁面成不规则"V"型。初始阶段,切深随计算时间呈线性增加,同时壁面对磨粒产生制约作用,从而使加工处的孔深基本不再增加。由于磨粒在冲蚀处壁面底部的冲蚀作用,使凹坑底部宽度增加并迅速趋于稳定。同时切削仿真与冲蚀仿真也存在一定区别,主要由于切削过程设定了移动速度。结论将仿真结果与实验结果进行比较可知,切削深度随着泵压的增大而成线性增大,切深随磨料流量的增大而增大,随靶距和横移速度的增大而减小。其中切深与磨料流量、靶距、横移速度均为非线性关系,工件最大切深与计算时间不呈线性关系增长。     

Citral-loaded nanocellulose/sodium alginate aerogel packaging liner for fresh pork preservation

The composite aerogels were prepared by using nanocellulose (CNF) and sodium alginate (SA) as the matrix materials and CaCl₂ as the cross-linking agent using a simple freeze-drying process, and the antimicrobial agent (citral) was loaded by using the porous network structure of the aerogels. The results showed that the composite aerogel had a homogeneous structure, excellent mechanical properties, and outstanding water absorption when the ratio of CNF to SA was 1:1. The citral-loaded composite aerogels showed excellent antibacterial properties against Escherichia coli and Staphylococcus aureus. Under ambient conditions, the citral-loaded composite aerogel can be used as a fresh packaging liner to absorb the blood water produced by pork while effectively slowing down the changes in color, pH, and total viable count of fresh pork and extending the shelf life of pork.