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排序方式: 共有854条查询结果,搜索用时 15 毫秒
1.
《International Journal of Hydrogen Energy》2019,44(11):5189-5202
Independent hydrogen production from petrochemical wastewater containing mono-ethylene glycol (MEG) via anaerobic sequencing batch reactor (ASBR) was extensively assessed under psychrophilic conditions (15–25 °C). A lab-scale ASBR was operated at pH of 5.50, and different organic loading rates (OLR) of 1.00, 1.67, 2.67, and 4.00 gCOD/L/d. The hydrogen yield (HY) progressed from 134.32 ± 10.79 to 189.09 ± 22.35 mL/gMEGinitial at increasing OLR from 1.00 to 4.00 gCOD/L/d. The maximum hydrogen content of 47.44 ± 3.60% was achieved at OLR of 4.0 gCOD/L/d, while methane content remained low (17.76 ± 1.27% at OLR of 1.0 gCOD/L/d). Kinetic studies using four different mathematical models were conducted to describe the ASBR performance. Furthermore, two batch-mode experiments were performed to optimize the nitrogen supplementation as a nutrient (C/N ratio), and assess the impact of salinity (as gNaCl/L) on hydrogen production. HY substantially dropped from 62.77 ± 4.09 to 6.02 ± 0.39 mL/gMEGinitial when C/N ratio was increased from 28.5 to 114.0. Besides, the results revealed that salinity up to 10.0 gNaCl/L has a relatively low inhibitory impact on hydrogen production. Eventually, the cost/benefit analysis showed that environmental and energy recovery revenues from ASBR were optimized at OLR of 4.0 gCOD/L/d (payback period of 7.13 yrs). 相似文献
2.
Muhammad Khurram Tufail Niaz Ahmad Le Yang Lei Zhou Muhammad Adnan Naseer Renjie Chen Wen Yang 《中国化学工程学报》2021,39(11):16-36
The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm-1, and deformability, the sulfide-based Li7P3S11 solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li7P3S11 could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li7P3S11-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries. 相似文献
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超支化聚合物改性环氧树脂固化体系力学性能研究 总被引:1,自引:0,他引:1
研究了羟端基脂肪族超支化聚酯(HBPE)对环氧树脂(EP)固化体系力学性能的影响。结果表明,加入较低含量的HBPE就能较好地改善体系的拉伸强度和冲击强度,同时对拉伸弹性模量的影响不大。其中,第三代和第四代HBPE的质量分数为3%时,固化体系的拉伸强度分别提高20.54%和18.64%,断裂伸长率分别提高41.02%和58.66%,冲击强度分别提高71.14%和117.36%。对固化体系的拉伸断面进行了分析,发现引入HBPE后,材料表现出韧性断裂;HBPE以微分散相的形式均匀分散在EP基体中。 相似文献
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羧甲基香豆胶的制备与表征 总被引:2,自引:0,他引:2
通过加入NaOH与一氯乙酸钠(SMCA)固体进行香豆胶(FG)的碱化和醚化,制备了不同取代度的羧甲基香豆胶(CMFG)。研究了不同分散介质、反应温度与时间、NaOH与SMCA用量等因素对取代度与反应效率的影响。以异丙醇/水为分散介质,产物取代度与反应效率最大,优化的反应温度为50℃、反应时间5h、醇水体积比52.5∶7.5。醇水体积比为50∶10、n(SMCA)∶n(NaOH)∶n(FG)=1∶1∶1时取代度为0.75,反应效率达75%。NaOH对取代度的影响大于SMCA。采用一步羧甲基化反应制备取代度1.05的CMFG,反应效率可达到70%。CMFG溶液黏度随取代度增大而增大,w(CMFG)=2%时,取代度为0.78,溶液黏度为116mPa.s。CMFG水溶液黏度4d降低8.6%~28.0%,黏度稳定性高于在w(NaCl)=1%的盐水溶液中的稳定性。 相似文献
7.
研究了两亲性超支化聚(胺-酯)(A-HPAE)对PVC/PP共混体系的增容作用,讨论了其用量对PVC/A-HPAE/PP共混体系力学性能和复数黏度的影响。结果表明,在PVC/PP共混物中加入2份(质量份,下同)A-HPAE时,能很好地改善共混体系的相容性,使共混物的拉伸强度和断裂伸长率分别达到26.18mPa和18.72%,比未加的分别提高了107.67%和34.68%;共混体系的绝对复数黏度随着A-HPAE用量的增大而降低;扫描电子显微镜分析表明,A-HPAE增强了PVC和PP之间的界面黏结作用,减小了共混体系中分散相的尺寸。 相似文献
8.
采用铜模浇铸的方法成功制备了最大直径为12mm的Mg65Cu20Ag5Gd10非晶合金,并对其结构、热稳定性能、非晶形成能力、压缩性能及断口形貌进行了分析.结果表明,Mg65Cu20Ag5Gd10具有较强的玻璃形成能力和良好的热稳定性能;合金的断裂强度达895MPa,弹性应变为2.35%. 相似文献
9.
《Journal of the European Ceramic Society》2021,41(14):6791-6804
The toughening mechanism in continuous fiber toughened ZrB2-SiC ceramic matrix (Cf/ZrB2-SiC) composites was studied upon introduction of pyrolytic carbon coating at the fiber/matrix interface. The real-time deformation behavior, surface crack initiation and evolution of Cf/ZrB2-SiC composites under tensile load were studied using in-situ scanning electron microscopy (SEM) to determine the typical damage modes and toughening mechanisms. A refined microscopic representative volume element (RVE) inserting the cohesive zone elements was established to study the PyC interface layer damage by using finite element method. It was found that PyC interface layer damage induced by thermal residual stress (TRS) was one of critical factors affecting the mechanical performance of the Cf/ZrB2-SiC composites. The critical thickness of the interface layer was also further determined by analyzing the effect of interface layer thickness on the distribution of TRS, which can guide the design of PyC interface layer for manufacturing the Cf/ZrB2-SiC composites. 相似文献
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