海洋环境中铝合金表面改性涂层的电化学性能

目的对换热管用6061铝合金表面进行改性防护,研究一种在其表面具有牺牲性阳极保护效果且腐蚀速率小的涂层材料。方法采用线材火焰喷涂工艺在6061铝合金表面制备不同成分的锌铝涂层,分别为纯Zn、Zn50、Al95、Al、Al-RE共5种涂层,使用SEM、EDS、XRD分析测试方法对涂层形貌及成分进行分析,并测定涂层在3.5%NaCl溶液中的Tafel曲线。结果相同参数下在铝合金表面制备的涂层表观质量良好,无明显缺陷,符合热喷涂对于涂层质量的要求。常温环境下,Zn、Zn50、Al95、Al、Al-RE涂层的电位比6061铝合金的电位更负,5种涂层对6061铝合金都具有阳极性保护层的作用。结论从腐蚀电流和腐蚀电位考虑,Al95、Al-RE作为牺牲性阳极保护涂层的作用会更好。     

Study on methods to optimize laser-sharpening quality,efficiency and topography

This paper aims to improve bond surface smoothness, sharpening quality and efficiency as well as control grain protrusion height. Systematic research was performed on pulsed fiber laser sharpening of a coarse-grained bronze-bonded diamond grinding wheel. The results show that bond surface smoothness is related to the laser spot overlap ratio U_c and the laser scan track overlap ratio U_l. In the range 10–70%, an increase in U_c and U_l improved the sharpened bond surface smoothness. Sharpening quality and efficiency are both related to laser power density I_p. In the range 2.115–6.344 × 10⁷ W cm⁻², an increase in I_p gradually improved sharpening efficiency, but the sharpening quality trend initially improved followed by a subsequent decline. The grain protrusion height is related to the laser scan cycles N. An excessively small N will result in an insufficient chip space such that the grinding wheel is likely blocked. Grains will likely fall off due to an insufficient holding force if N is excessively large. Compared with silicon carbide grinding wheel sharpening, a pulsed laser-sharpened grinding wheel exhibits less surface grain fall-off, better grain height uniformity, more chip space around the grain and superior grinding wheel surface topography.