Reusable Polyacrylonitrile-Sulfur Extractor of Heavy Metal Ions from Wastewater

Mercury, lead, and cadmium are among the most toxic and carcinogenic heavy metal ions (HMIs), posing serious threats to the sustainability of aquatic ecosystems and public health. There is an urgent need to remove these ions from water by a cheap but green process. Traditional methods have insufficient removal efficiency and reusability. Structurally robust, large surface-area adsorbents functionalized with high-selectivity affinity to HMIs are attractive filter materials. Here, an adsorbent prepared by vulcanization of polyacrylonitrile (PAN), a nitrogen-rich polymer, is reported, giving rise to PAN-S nanoparticles with cyclic π-conjugated backbone and electronic conductivity. PAN-S can be coated on ultra-robust melamine (ML) foam by simple dipping and drying. In agreement with hard/soft acid/base theory, N- and S-containing soft Lewis bases have strong binding to Hg²⁺, Pb²⁺, Cu²⁺, and Cd²⁺, with extraordinary capture efficiency and performance stability. Furthermore, the used filters, when collected and electrochemically biased in a recycling bath, can release the HMIs into the bath and electrodeposit on the counter-electrode as metallic Hg⁰, Pb⁰, Cu⁰, and Cd⁰, and the PAN-S@ML filter can then be reused at least 6 times as new. The electronically conductive PAN-S@ML filter can be fabricated cheaply and holds promise for scale-up applications.     

Study on maximum power point tracking of photovoltaic array in irregular shadow

Traditional maximum power point tracking (MPPT) methods can hardly find global maximum power point (MPP) because output characteristics curve of photovoltaic (PV) array may have multi local maximum power points in irregular shadow, and thus easily fall into the local maximum power point. To address this drawback, Considering that sliding mode variable structure (SMVS) control strategy have such advantages as simple structure, fast response and strong robustness, and P&O method have the advantages of simple principle and convenient implementation, so a new algorithm combining SMVS control method and P&O method is proposed, besides, PI controller is applied to reduce system chattering caused by switching sliding surface. It is applied to MPPT control of PV array in irregular shadow to solve the problem of multi-peak optimization in partial shadow. In order to verity the rationality of the proposed algorithm, the experimental circuit is built, which achieves MPPT control by means of the proposed algorithm and P&O method. The experimental results show that compared with the traditional P&O algorithm, the proposed algorithm can fast track the global MPP, tracking speed increases by 60% and the relative error decreased by 20%. Moreover, the system becomes more stable near the MPP, the fluctuations of output power is greatly reduced, and thus make full use of solar energy.     

从《左传》录诗看孔子是否删诗

孔子是否删诗，这是一个历史遗留问题。司马迁首言在前，孔颖达怀疑在后。宋之后，争议遂起，延至近代。今人夏传才先生断日：孔子是否删诗，“在没有发掘出新史料的情况下，哪怕再争论八百年，也是搞不清楚的”。以此止息纷争。话虽不错，但问题并没有解决。我认为，在没有发掘出新史料的情况下，可以从《左传》入手，来考察孔子是否删诗。     

Simulating Experiment for Temperature Field of Frozen Subgrade Using Regulation Tubes

The main factors that influence the temperature field of frozen subgrade were analyzed.The experimental equipment for simulating frozen subgrade was built up,and the declining regulating tubes were placed at the foot of the embankment. By means of this equipment two simulating experiments of controlling temperature filed of frozen subgrade were carried out in the laboratory. One method is to collect natural cold energy, and the other one is to collect natural cold energy ccompanied by artificial refrigeration simultaneously. The result indicates that the latter is an effective method for maintaining the stability of the frozen subgrade.     

承压水漏斗地区地下水位时空分布预报的BP网络模型

依据水均衡原理，导出承压水漏斗区任意一点水位与其影响因素之间的复杂的非线性关系，在此基础上提出承压水漏斗水位时空分布预报的BP神经网络模型。该模型具有 分布参数模型的特征，且不需用到区域的水文地质参数。最后针对某实例进行了模型设计及预报分析，通过对部分观测井后期实测数据的训练，优选出双隐层的网络结构及其网络参数。随后用这些观测井的前3年数据进行了检验，并对其他观测井数据进行预报。计算表明，该模型对地下水位拟合与预报的合格率较高，可以获得研究区域某一时刻水位在空间上的分布。     

基于Delphi的“虚拟胶片打印系统”的技术实现

利用Delphi和VS这两种开发平台,结合Oracle数据库,实现胶片排版、胶片调整、虚拟打印,自助打印、系统管理等功能。重点介绍了系统开发过程中针对特殊问题采用的几种技术。目的是完成胶片的集中打印管理,胶片存储备份,减少开支。     

芝麻渣中蛋白质的提取与纯化

采用超声波—微波协同提取法提取芝麻渣中蛋白质,并用超滤法进行纯化.实验考察了影响粗蛋白提取率的固液比、溶液pH值、微波功率、提取时间等因素,确定了最佳提取条件;同时考察了超滤膜的截留分子质量以及压力对超滤效果的影响.结果表明：超声波—微波协同提取最佳条件为超声波功率40 W,固液比1∶20,溶液pH11,微波功率250 W、提取时间90 s,提取率约55.32%;采用10万截留分子质量的超滤膜在0.18 MPa压力下对芝麻渣蛋白质纯化后,蛋白质纯度提高了15.67%.     

脂肪醇生物活性和理化性质的QSAR/QSPR研究

为了研究脂肪醇结构-性质(活性)的定量关系,用相对键长取代拓扑距离,结合距离矩阵,提出了距离调和拓扑指数Te,Te和醇的许多理化性质和生物活性具有良好的相关性.用Te及δ(醇中和羟基相连的碳原子的支化度)与脂肪醇的溶解度、辛醇/水分配系数、急性生物毒性、蒸发热、摩尔磁化率关联,复相关系数分别为0.9955,0.9951,0.9941,0.9964,0.9968,优于文献.同时与脂肪醇的气相色谱保留指数也相关得很好,相关系数为0.9956.结果表明,Te指数可用于醇多种理化性质和生物活性的预测.     

OFDM系统二维变换域信道估计算法

着重分析OFDM系统的二维变换域(2-D transform-domain)的导频辅助信道估计。在变换域中对导频位置的信道频率响应(CFR)矩阵采用右下补零和中间补零两种方式进行插值,以获得整个信道的频率响应。考虑到上述两种方法带来的插值误差,提出了根据时间、频率方向的导频数目采用不同的补零数量和补零方式。采用Simulink®构建基带仿真系统,仿真改进前后的系统误比特率(BER)并和其他二维插值方式进行比较。结果表明,该改进方法显著地提高了基于变换域信道估计的准确性,降低了系统的误比特率。     

C0-半群的概率型逼近

借助于算子值数学期望以及概率论方法,利用适当的随机变量的矩生成函数估计式,讨论了Banach空间上C0-半群的概率表示式及收敛速度的估计式.