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Most researches on graphene/polymer composites are focusing on improving the mechanical and electrical properties of polymers at low graphene content instead of paying attention to constructing graphene’s macroscopic structures. In current study the homo-telechelic functionalized polyethylene glycols (FPEGs) were tailored with π-orbital-rich groups (namely phenyl, pyrene and di-pyrene) via esterification reactions, which enhanced the interaction between polyethylene glycol (PEG) molecules and chemical reduced graphene oxide (RGO) sheets. The π–π stacking interactions between graphene sheets and π-orbital-rich groups endowed the composite films with enhanced tensile strength and tunable electrical conductivity. The formation of graphene network structure mediated by the FPEGs fillers via π–π stacking non-covalent interactions should account for the experimental results. The experimental investigations were also complemented with theoretical calculation using a density functional theory. Atomic force microscope (AFM), scanning electron microscope (SEM), X-ray diffraction (XRD), nuclear magnetic resonance (NMR), thermal gravimetric analysis (TGA), UV–vis and fluorescence spectroscopy were used to monitor the step-wise preparation of graphene composite films.  相似文献   
3.
SrLa[Ga1−x(R0.5Ti0.5)x]O4 (R = Mg, Zn) ceramics were prepared by a standard solid state sintering method. The single-phase ceramics with K2NiF4-type layered perovskite structure and I4/mmm space group were obtained, indicating that SrLa(R0.5Ti0.5) and SrLaGaO4 can form the unlimited solid solutions. With increasing x for = Mg and Zn, εr increases monotonously, the Qf value first increases and then decreases, while τf increases from a negative to a positive value. The optimized microwave dielectric properties were obtained as following: εr = 23.3, Qf = 89 400 GHz, τf = −0.8 ppm/°C for SrLa[Ga0.6(Mg0.5Ti0.5)0.4]O4 and εr = 23.3, Qf = 76 200 GHz, τf = 0.2 ppm/°C for SrLa[Ga0.7(Zn0.5Ti0.5)0.3]O4, indicating that the present solid solution ceramics are the promising candidates as microwave resonator materials for the telecommunication applications.  相似文献   
4.
The Ca(1+2y)Sn(1-x)Si(1+y)O(5-2x+4y) low-permittivity microwave dielectric ceramics were prepared through solid-state reaction at 1350–1450 °C for 5 h. The relations between microwave dielectric properties and phase compositions for non-stoichiometric Ca(1+2y)Sn(1-x)Si(1+y)O(5-2x+4y) ceramics have been investigated. A single CaSnSiO5 phase with abnormally positive temperature coefficient of resonant frequency (τf = + 62.5 ppm/°C) was synthesised at 1450 °C. This composition was an effective τf compensator of CaSiO3 and Ca3SnSi2O9 phases with typically negative τf value. The CaSiO3 second phase was related to the Sn deficiency in the CaSn(1-x)SiO(5-2x) (0 < x < 1.0) composition, whereas the Ca3SnSi2O9 second phase was obtained by controlling the Ca:Sn:Si ratios on the basis of the Ca(1+2y)SnSi(1+y)O(5+4y) (0 < y < 1.0) composition. A promising low-permittivity millimetre-wave ceramic with most excellent microwave dielectric properties (εr = 10.2, Q×f = 81,000 GHz and τf = −4.8 ppm/°C) was produced from the Ca(1+2y)SnSi(1+y)O(5+4y) (y = 0.4) ceramic.  相似文献   
5.
Big data is one of the most important resources for the promotion of smart customisation. With access to data from multiple sources, manufacturers can provide on-demand and customised products. However, existing research of smart customisation has focused on data generated from the physical world, not virtual models. As physical data is constrained by what has already occurred, it is limited in the identification of new areas to improve customer satisfaction. A new technology called digital twin aims to achieve this integration of physical and virtual entities. Incorporation of digital twin into the paradigm of existing data-driven smart customisation will make the process more responsive, adaptable and predictive. This paper presents a new framework of data-driven smart customisation augmented by digital twin. The new framework aims to facilitate improved collaboration of all stakeholders in the customisation process. A case study of the elevator industry illustrates the efficacy of the proposed framework.  相似文献   
6.
In this paper we introduce a multi-method multiple criteria approach for evaluating the performance of organizations. Performance analysis may include both strategic and operational performance, as well as financial and other less tangible factors. This paper introduces the use of Fuzzy C-Means and TOPSIS for organizational performance evaluation purposes. Using real company data and balanced scorecard accounting and performance dimensions the methodology is applied and evaluated. The predictive abilities of the technique from an organizational performance evaluation approach are evaluated using this data. One of the results from the illustrative application is that economic performance evaluation is not the best predictor of overall viability of some organizations, especially e-commerce based organizations.  相似文献   
7.
The inverse Gaussian distribution has considerable applications in describing product life, employee service times, and so on. In this paper, the average run length (ARL) unbiased control charts, which monitor the shape and location parameters of the inverse Gaussian distribution respectively, are proposed when the in-control parameters are known. The effects of parameter estimation on the performance of the proposed control charts are also studied. An ARL-unbiased control chart for the shape parameter with the desired ARL0, which takes the variability of the parameter estimate into account, is further developed. The performance of the proposed control charts is investigated in terms of the ARL and standard deviation of the run length. Finally, an example is used to illustrate the proposed control charts.  相似文献   
8.
In this paper, an improved global-best harmony search algorithm, named IGHS, is proposed. In the IGHS algorithm, initialization based on opposition-based learning for improving the solution quality of the initial harmony memory, a new improvisation scheme based on differential evolution for enhancing the local search ability, a modified random consideration based on artificial bee colony algorithm for reducing randomness of the global-best harmony search (GHS) algorithm, as well as two perturbation schemes for avoiding premature convergence, are integrated. In addition, two parameters of IGHS, harmony memory consideration rate and pitch adjusting rate, are dynamically updated based on a composite function composed of a linear time-varying function, a periodic function and a sign function in view of approximate periodicity of evolution in nature. Experimental results tested on twenty-eight benchmark functions indicate that IGHS is far better than basic harmony search (HS) algorithm and GHS. In further study, IGHS has also been compared with other eight well known metaheuristics. The results show that IGHS is better than or at least similar to those approaches on most of test functions.  相似文献   
9.
Object detection is a critical step of many image recognition systems. In this paper, we discuss the problem of circular shape object detection in still color images. An isotropic edge detector merged with spatial information and region based analysis is employed to extract image edge and obtain accurate gradient information of edge pixels, which assures the high accuracy of the subsequent circle detection. Then three circle parameters are estimated efficiently with only one 2-dimensional accumulator array and one 1-dimensional accumulator array, which greatly reduces the storage requirements and time complexity of our approach. Experimental results show that our method is robust in locating objects with complete or incomplete or concentric circle boundary in real color images without any prior knowledge.  相似文献   
10.
In the last years focus has been put in the development of distributed Model Predictive Control (MPC) algorithms. With a few exceptions, they have been mostly developed in the discrete-time framework. However, discretization of large-scale systems may destroy the sparsity of the original continuous-time models, making distributed control design and implementation more difficult. Also, more in general, discrete-time control of continuous-time systems does not allow to consider the process inter-sampling behavior. In this paper we present a novel non-cooperative distributed predictive control algorithm for continuous-time systems based on robust MPC concepts. The convergence properties of the proposed control scheme are stated, and its realizability is tested through a simulation case study.  相似文献   
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