Crystallization and spectroscopic properties in Er3+ doped oxyfluorogermanate glass ceramics containing Na

The Er³⁺ doped oxyfluorogermanate glasses, with a composition containing Na element, were synthesized by the conventional melting–quenching technique. When Na element was introduced into the composition of oxyfluorogermanate glass, the crystals behavior was investigated in details. Depending on the annealing procedure supplied, thermal annealing of precursor glasses in the system GeO₂/BaF₂/AlF₃/Na₂O/NaF/ZnO/GdF₃/ErF₃ led to the precipitation of different crystal phase nanocrystals. It was confirmed the nanocrystals in GC600 is orthorhombic NaBaAlF₆ which led to enhance obviously in the UC luminescence of Er³⁺. However, the nanocrystals in G585 led to decrease in the UC luminescence, which indicated few Er ions enter into the lattice of this nanocrystal phase. The reason of the decrease in UC emission intensity of GC585 was analyzed.     

Fabrication of BSCF-based mixed ionic-electronic conducting membrane by electrophoretic deposition for oxygen separation application

Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ (BSCF), which exhibits a high mixed oxide ionic-electronic conduction, was used for the fabrication of an oxygen separation membrane. An asymmetric structure, which was a thin and dense BSCF membrane layer supported on a porous BSCF substrate, was fabricated by the electrophoretic deposition method (EPD). Porous BSCF supports were prepared by the uniaxial pressing method using a powder mixture with BSCF and starch as the pore-forming agent (0–50 wt.%). The sintering behaviors of the porous support and the thin layer were separately characterized by dilatometry to determine the co-fired temperature at which cracking did not occur. A crack-free and thin dense membrane layer, which had about a 15 μm thickness and >95% relative density, was obtained after optimizing the processes of EPD and sintering. The dense/porous interface was well-bonded and the oxygen permeation flux was 2.5 ml (STP) min⁻¹ cm^-2 at 850 °C.     

A design of a robust discrete-time controller

In this paper, we proposed a robust discrete-time controller. This control system, which is derived from the idea of the normalized plant, does not include plant parameters. Thus, we obtain a control system independent of plant parameters and that has the same structure as a conventional optimal servo control system. Simulation and experimental results show that the proposed method is fairly robust to plant parameter variations and external disturbances.     

锌粉颗粒形状对机械沉积无结晶镀层结构的影响

以球状锌粉和片状锌粉为原始锌粉借助于机械镀工艺制备了无结晶锌防护层，运用光学显微镜（OM）、扫描电子显微镜（SEM）观察了镀层的结构形貌；采用XRD技术分析了镀层的物相组成；采用贴滤纸法进行了镀层的孔隙率测试。研究结果表明，片状锌粉制备的镀层比球状锌粉制备的镀层表面要平滑、光亮。球状锌粉制备的镀层中锌粉颗粒呈紧密堆积，部分锌粉颗粒发生塑性变形；片状锌粉制备的镀层中的锌粉颗粒呈层片状叠加，镀层中锌粉颗粒没有发生明显塑性变形。两种形状锌粉制备的镀层均为锌基多相混合体系，镀层中没有固溶体、化合物等合金相产生，属于锌基复合镀层。锌粉颗粒形状对镀层中颗粒之间的结合机理没有显著影响，两种镀层中锌粉颗粒间均以机械咬合为主。     

基于 IAS 精确估计的太阳轮齿面剥落检测方法研究

瞬时角速度(instantaneous angular speed, IAS)信号的估计精度易受编码器自身误差影响,影响其故障检测结果。针对上述问题提出了一种局部多项式微分估计方法对IAS信号进行估计。首先通过局部多项式微分抑制编码器细分误差产生的锯齿状噪声和估计误差导致的信号不连续问题,实现了IAS信号的高精度获取,然后使用精确估计的IAS信号通过局部同步拟合技术提取太阳轮故障特征。通过实验和仿真说明,本文提出的局部多项式微分估计能较好地抑制编码器误差导致的IAS信号噪声,提高IAS信号的信号比,结合局部同步拟合能够有效地提取太阳轮齿面剥落故障特征。     

Online adaptive optimal control for continuous-time nonlinear systems with completely unknown dynamics

An online adaptive optimal control is proposed for continuous-time nonlinear systems with completely unknown dynamics, which is achieved by developing a novel identifier-critic-based approximate dynamic programming algorithm with a dual neural network (NN) approximation structure. First, an adaptive NN identifier is designed to obviate the requirement of complete knowledge of system dynamics, and a critic NN is employed to approximate the optimal value function. Then, the optimal control law is computed based on the information from the identifier NN and the critic NN, so that the actor NN is not needed. In particular, a novel adaptive law design method with the parameter estimation error is proposed to online update the weights of both identifier NN and critic NN simultaneously, which converge to small neighbourhoods around their ideal values. The closed-loop system stability and the convergence to small vicinity around the optimal solution are all proved by means of the Lyapunov theory. The proposed adaptation algorithm is also improved to achieve finite-time convergence of the NN weights. Finally, simulation results are provided to exemplify the efficacy of the proposed methods.     

等离子体活化烧结法制备多孔钛研究

采用等离子体活化烧结技术制得孔径大小可调、贯通性良好的多孔钛,确立了使用等离子体活化烧结法制备多孔钛的工艺流程,并确定了相关工艺参数,研究了发泡剂添加量和试块成型压力对多孔钛孔隙特征的影响,观察了多孔钛的显微孔隙特征.     

喷射式浆体冲蚀磨损试验机的研制及其性能考核

冲刷腐蚀磨损广泛存在于现代工业生产中,造成了大量的材料消耗.目前对浆体冲蚀磨损规律的认知还存在较大的局限性,要对浆体冲蚀磨损进行深入的研究,必须研制能较好模拟实际工况条件的试验装置,在比较现有冲蚀磨损试验机优缺点以及考虑制造成本的基础上,设计并制造了一台喷射式浆体冲蚀磨损试验装置.该试验机经过性能考核,证明其性能可靠,参数易于调节,可用于材料耐磨性能对比及浆体冲蚀磨损机理研究.     

用阈值法自动分割某内燃机铁谱磨粒图像

利用计算机图像处理技术实现铁谱图像诊断自动化是铁谱技术发展的目标。铁谱原始图像需要平滑、滤波、磨粒分割等预处理,才能有效地减少噪声污染并简化数据处理。探讨了铁谱图像的预处理技术,采用自动阈值分割法对某内燃机铁谱图像进行处理,验证了该方法的有效性。