Doping-free hybrid white organic light-emitting diodes with fluorescent blue,phosphorescent green and red emission layers

Industrialized white organic light-emitting diodes (OLEDs) currently require host-guest doping, a complicated process necessitating precise control of the guest concentration to get high efficiency and stability. Two doping-free, hybrid white OLEDs with fluorescent blue, and phosphorescent green and red emissive layers (EMLs) are reported in this work. An ultra-thin red phosphorescent EML was situated in a blue-emitting electron transport layer (ETL), while the ultra-thin green phosphorescent EML was placed either in the ETL (Device 1), or the hole transport layer (HTL) (Device 2). Device 2 exhibits higher efficiency and more stable spectrum due to the enhanced utilization of excitons by ultra-thin green EML at the exciton generation zone within the HTL. Values of current efficiency (CE), power efficiency (PE), and CRI obtained for the optimized hybrid white OLEDs fabricated through a doping-free process were of 23.2 cd/A, 20.5 lm/W and 82 at 1000 cd/m², respectively.     

Nickel foam-supported Fe,Ni-Polyporphyrin microparticles: Efficient bifunctional catalysts for overall water splitting in alkaline media

Developing highly active, stable and sustainable electrocatalysts for overall water splitting is of great importance to generate renewable H₂ for fuel cells. Herein, we report the synthesis of electrocatalytically active, nickel foam-supported, spherical core-shell Fe-poly(tetraphenylporphyrin)/Ni-poly(tetraphenylporphyrin) microparticles (FeTPP@NiTPP/NF). We also show that FeTPP@NiTPP/NF exhibits efficient bifunctional electrocatalytic properties toward both the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER). Electrochemical tests in KOH solution (1 M) reveal that FeTPP@NiTPP/NF electrocatalyzes the OER with 100 mA cm⁻² at an overpotential of 302 mV and the HER with 10 mA cm⁻² at an overpotential of 170 mV. Notably also, its catalytic performance for OER is better than that of RuO₂, the benchmark OER catalyst. Although its catalytic activity for HER is slightly lower than that of Pt/C (the benchmark HER electrocatalyst), it shows greater stability than the latter during the reaction. The material also exhibits electrocatalytic activity for overall water splitting reaction at a current density of 10 mA cm⁻² with a cell voltage of 1.58 V, along with a good recovery property. Additionally, the work demonstrates a new synthetic strategy to an efficient, noble metal-free-coordinated covalent organic framework (COF)-based, bifunctional electrocatalyst for water splitting.     

简易人体穴位识别治疗仪

为了解决非专业人群寻找穴位难、不准确、不易操作等难题,设计了一种以SPCE061A为核心MCU（Micro Control Unit）的简易人体穴位识别治疗仪。给出了系统结构和实现流程,提出了一种基于层次分析原理的新型穴位检测方法,并讨论了环境因素对穴位识别结果的影响。通过人体穴位检测实验表明,本系统的穴位与非穴位正确识别率可分别达到95%和98%以上,且输出频率可调、波形可变的脉冲电压可达到模拟中医针灸治疗的作用。与传统找穴位方法相比,该方案具有操作简单、功耗低、性价比高等优点。     

基于System View的QAM和OFDM调制性能研究

针对无线通信和移动通信中的信道干扰和码间干扰等问题,对正交幅度调制（QAM）和OFDM的调制性能进行了研究,首先,在System View仿真环境下,搭建一个通信系统,然后分别将两种调制方式应用其中,最后得到OFDM与QAM的比特误码率（BER）性能曲线。仿真结果表明,OFDM具有良好的误比特率性能,而且在相同的信噪比（SNR）下OFDM的BER性能比QAM更优越。     

探针对原子力显微镜成像的影响

原子力显微镜（Atomic Force Microscope,AFM）的一个重要应用就是对样品表面的微纳米级尺寸特征进行成像,但在扫描成像的过程中,由于针尖的影响作用,使得扫描所获图像是原子力探针和样品共同作用的结果,而不是样品形貌的真实描述。本文通过用具有不同形状、尺寸针尖的探针对同一样品进行成像,将所得图像进行分析、对比,模拟和实验结果表明,为获得更准确的特征尺寸成像,对有不同特征尺寸的样品,需要选择适合的探针对其实施成像。     

One- and two-photon absorption properties of a series of derived pyrazolines

The one-photon absorption and two-photon absorption (TPA) properties of a series of pyrazoline derivatives have been theoretically investigated by means of density functional theory and ZINDO-SOS method. On the basis of optimized geometry and UV–vis spectrum, the position and strength of the TPA for molecules are reported. The theoretical findings are consistent with the experimental observations. It is found that a most crucial role in increasing TPA cross-section is played by the conjugated length and the introduction of donors. The calculated maximum TPA cross-section values are in the range of 360–1760 × 10⁻⁵⁰ cm⁴ s/photon. The TPA response will be as another possible application for derived pyrazoline.     

A near edge X-ray absorption fine structure study of oxidized single crystal and polycrystalline diamond surfaces

The influence of oxidizing environments on single crystal diamond and polycrystalline chemical vapor deposited CVD diamond films was studied using the near edge X-ray absorption fine structure (NEXAFS) pre-edge region in both bulk and surface sensitive modes. The NEXAFS of (100) oriented single crystal diamond was measured following (i) exposure to a microwave (MW) hydrogen plasma, (ii) annealing to 1000 °C, (iii) exposure of the as annealed surface to H₂O, and (iv) exposure of the as annealed surface to O₂. From these measurements particular surface bonding configurations have been assigned to features in the pre-edge structure. The NEXAFS of microcrystalline CVD diamond films was studied following different oxidative treatments using (i) a thermal atomic oxygen (AO) environment, (ii) a hyperthermal (5 eV) AO source, and (iii) an RF oxygen plasma exposure. The nature of the surface layer was found to be different for differently oxidized surfaces. These treatments were carried out as part of a study of CVD diamond durability in the low Earth orbit space environment.     

Detecting outlier pairs in complex network based on link structure and semantic relationship

In this paper, we propose an outlier pair detection method, called LSOutPair, which discovers the vast differences between link structure and semantic relationship. LSOutPair addresses three important challenges: (1) how can we measure the target object's link similarity among multi-typed objects and multi-typed relations? (2) how can we measure the semantic similarity using the short texts? (3) how can we find the objects’ maximum differences between link structure and semantic relationship? To tackle these challenges, LSOutPair applies three main techniques: (1) two matrices are used to store link similarity and semantic similarity, (2) a k-step index algorithm, which calculates the term weighting for each object, (3) applying the linear transformation of Frobenius norm to matrices can obtain the top-K outlier pairs. LSOutPair considers link and semantics in complex network simultaneously, which is a new attempt in data mining. Substantial experiments show that LSOutPair is very effective for outlier pair detection.     

Spin-polarized transport properties of Fe-oligoporphyrin dimer-based molecular device

By applying the density functional theory and the nonequilibrium Green’s function formalism, we investigate the spin-polarized transport properties of a Fe-oligoporphyrin dimer (Fe-P2TA) sandwiched between two armchair single-walled carbon nanotube electrodes. The results show that the system can present high-efficiency magnetoresistance, spin-filtering, and low-bias negative differential resistance effects with the help of magnetic field modulation. The above results are explained by the evolution of the spin-polarized transmission spectra and the molecular projected self-consistent Hamiltonian eigenstates with applied bias. Therefore, the system provides the possibilities for a multifunctional molecular spintronic device design.