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《International Journal of Hydrogen Energy》2019,44(31):16548-16556
Development of supported ligand-free ultrafine Rh nanocatalysts for efficient catalytic hydrogen evolution from ammonia borane (AB) is of importance but remains a tremendous challenge. Here, ultrafine and ligand-free Rh nanoparticles (NPs) (2.19 nm in diameter) were in-situ decorated on porous phosphorus-functionalized carbon (PPC) prepared by pyrolyzing hyper-cross-linked networks of triphenylphosphine and benzene. The resultant Rh/PPC showed excellent hydrogen production activity from AB hydrolysis (Turnover frequency: 806 min−1). Kinetic investigations indicated that AB hydrolysis using Rh/PPC exhibited first-order and zero-order reactions with Rh and AB concentrations, respectively. Activation energy (Ea) toward hydrogen generation from AB with Rh/PPC is as low as 22.7 kJ/mol. The Rh/PPC catalyst was recyclable and reusable for at least four times. The oxygen- and phosphorus-functional groups are beneficial for the affinity of Rh complex on the PPC surface, resulting in ultrafine and ligand-free Rh NPs with high dispersity and ability to supply abundant surface accessibility to catalytically active sites for AB hydrolysis. This study proposes a feasible approach for the synthesis of ultrafine and ligand-free metal NPs supported on heteroatom-doped carbon by using hyper-cross-linked networks. 相似文献
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The aim of this study was to evaluate the susceptibility of the egg stage of the rice moth Corcyra cephalonica to modified atmospheres (MAs) enriched with CO2 or N2 at 25, 30 and 35 °C combined with various exposure times. The tested modified atmospheres containing CO2 were 20% CO2, 16% O2 and 64% N2; 40% CO2, 12% O2 and 48% N2; 60% CO2, 8% O2 and 32% N2 and 80% CO2, 4% O2 and 16% N2. The tested modified atmospheres containing N2 were 97% N2 and 3% O2 and 98% N2 and 2% O2. The results showed that the hatchability responding to modified atmospheres enriched with either CO2 or N2 decreased significantly with an increase in exposure time, gas content (%) and temperature. All tested combinations provided complete (100%) egg control in less than 4 days. Based on 100% mortality, shorter exposures were obtained with 80% CO2 than with N2 at most tested temperatures. The modified atmospheres enriched with 98% N2 were more effective than 97% N2 against C. cephalonica eggs, especially at 35 °C. It is recommended to use high levels of CO2 in air (80%) and N2 (98%) in controlling 0–24-h-eggs of C. cephalonica within 24–36 h for CO2 and 18–72 h for N2. 相似文献
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Potassium-ion batteries (PIBs) have aroused considerable interest as a promising next-generation advanced large-scale energy storage system due to the abundant potassium resources and high safety. However, the K+ with large ionic radius brings restricted diffusion kinetics and severe volume expansion in electrode materials, resulting in inferior actual rate characteristics and rapid capacity fading. Designing electrode materials with one-dimensional (1D) nanostructure can effectively enhance various electrochemical properties due to the well-guided electron transfer pathways, short ionic diffusion channels and high specific surface areas. In this review, we summarize the recent research progress and achievements of 1D nanostructure electrode materials in PIBs, especially focusing on the development and application of cathode and anode materials. The nanostructure, synthetic methods, electrochemical performances and structure-performance correlation are discussed in detail. The advanced characterizations on the reaction mechanisms of 1D nanostructure electrode materials in PIBs are briefly summarized. Furthermore, the main future research directions of 1D nanostructure electrode materials are also predicted, hoping to accelerate their development into the practical PIBs market. 相似文献
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《Ceramics International》2016,42(14):15876-15880
The influence of ZnO nanoseeds on the formation of ZnO nanorods from ε-Zn(OH)2 in NaOH solution at 80 °C was investigated, using ZnO nanoparticles with a diameter of 4–10 nm as the seeds. The experimental results indicated that the presence of ZnO nanoseeds promoted the rapid heterogeneous formation of ultrathin ZnO nanorods. Compared with the ZnO submicron rods with a diameter of 0.5–1.0 µm, the ultrathin ZnO nanorods with a diameter of 10–15 nm were found to be more sensitive for detecting NO2 at room temperature owing to their higher variation of channel conduction to the diameter. 相似文献
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《Food Control》2016
Zearalenone (ZEA) contamination in food samples plays a critical role in food safety, since it causes serious health problems. Usage of microorganisms, such as lactic acid bacteria (LAB), is a promising new approach for detoxification. Eight Lactobacillus pentosus strains were evaluated for their ability to remove ZEA from a sodium acetate buffer solution with initial ZEA concentrations of 5.51–74.70 μg/mL. The adsorption capacity increased with increasing ZEA concentrations. The strain JM0812 showed the highest adsorption capability, at 83.17%, in solution containing 74.70 μg/mL ZEA, followed by UM054 (82.78%) and UM055 (81.69%), respectively. Three adsorption isotherms were applied to predict the removal efficiency of ZEA and the Freundlich isotherm appeared to have the best-fit for ZEA sorption onto bacterial cells. Our results indicate that Lb. pentosus strains are novel promising strains to reduce mycotoxin contamination in food products. 相似文献
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《材料与设计》2015
With regard to the adiabatic principle of insulation, a novel multilayer cladding structure composites (MCSC) with vacuum inside was put forward, which could be used in high temperature insulation field. In the composites, SiO2 was used to fill the microcracks and protect the carbon matrix from oxidizing. This novel material was composed of two parts, one was the core material consisted of SiC foam ceramic, the other was the flawless outer shell consisted of carbon fiber reinforced composites with vacuum inside that produced by Chemical Vapor Infiltration (CVI) Pyrolytic Carbon (PyC) and silicasol-infiltration–sintering methods. Material density was 0.81 g/cm3. The effective thermal conductivity of MCSC ranged from 0.193 W/m · K to 0.721 W/m · K within the temperature from 303 K to 703 K, which was 13.5–23.3% lower than the value of SiC ceramic foam core materials. However, at 1473 K, the measured data of MCSC and SiC foam were 1.815 W/m · K and 1.911 W/m · K, respectively. It was only 5.02% lower than that of SiC foam. 相似文献