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排序方式: 共有489条查询结果,搜索用时 31 毫秒
1.
Polymers play an important role in the advancement of materials for use in cutting-edge applications. A direct consequence of an increased demand for more sophisticated materials has been a drive toward developing polymers that exhibit a higher level of structural control, especially in terms of the number and type of functionalities provided within the polymer framework. A family of polymers that meets such a challenge is based on the readily available AB2 monomer 2,2-bismethylolpropionic acid (bis-MPA) building block. Due to the ease with which the monomers can be synthesized, an array of multifunctional polymers have been produced including monodisperse dendrimers and dendrons and well-defined linear polymers as well as linear-dendritic hybridizations. This review outlines the evolution of the synthetic strategies for developing novel polymeric architectures based on bis-MPA and their assessment in both solution and substrate-based innovative applications. 相似文献
2.
The acidic zeolite HZSM-5 (Si/Al = 25) achieved 58.9% selectivity of methyl furfuryl ether (MFE) and 44.8% selectivity of ethyl furfuryl ether (EFE) from etherification of furfuryl alcohol with methanol and ethanol. MFE and EFE were quantitatively hydrogenated into methyl tetrahydrofurfuryl ether (MTE) and ethyl tetrahydrofurfuryl ether (ETE) using a Raney Ni catalyst. 相似文献
3.
Guangbo Zeng Dongqing Zhang Liuming Yan Baohua Yue Ting Pan Yidong Hu Shufa He Hongbin Zhao Jiujun Zhang 《International Journal of Hydrogen Energy》2021,46(39):20664-20677
Side-chain optimized poly (2,6-dimethyl-1,4-phenylene oxide)-g-poly (styrene sulfonic acid) (PPO-g-PSSA) is designed with balanced water-resistance and sulfonation degree. The PPO-g-PSSA is synthesized by controlled atom-transfer radical polymerization (ATRP) from brominated poly (2,6-dimethyl-1,4-phenylene oxide) (PPO-xBr) and ethyl styrene-4-sulfonate and followed by hydrolysis. A series of PPO-g-PSSA are prepared possessing different bromination degree (x) of PPO-xBr and polymerization degree (m) of the side-chains and the water-resistances of the fabricated membranes are investigated. The results show that a PPO-g-PSSA at relatively low x (x < 0.2) and high m (m > 4) exhibits good balance between the water-resistance and the sulfonation degree. Namely, it displays suitable proton conductivity with compromised water-resistance. Moreover, a maximum ion exchange capacity (IEC) of 3.24 mmol g?1 is reached without the sacrifice of water-resistance. In addition, PPO-g-0.08PSSA-13 and PPO-g-0.14PSSA-4 are chosen characterized by thermogravimetric analysis, proton conductivities and mechanical properties. At 90% RH, the optimized PPO-g-0.08PPSA-13 possesses a proton conductivity of 37.9 mS cm?1 at 40 °C and 45.5 mS cm?1 at 95 °C, respectively. 相似文献
4.
Ma Xin Zhang Guoqiang Li Fengting Jiao Mingyang Yao Shunyu Chen Zhipeng Liu Ziyong Zhang Yongyu Lv Ming Liu Licheng 《Catalysis Letters》2021,151(10):2939-2949
Catalysis Letters - Microbial electrosynthesis (MES) is an effective approach to driving the CO2 reduction to multi-carbon organic products using renewable energy. In this work, the MES of acetate... 相似文献
5.
海上漏油的频繁发生以及采油废水、工业含油污水的大量排放造成水资源大片污染和生态系统平衡的严重破坏。目前,从水体中分离油品和有机污染物已受到越来越多的商业和学术的关注。石墨烯基气凝胶是由二维石墨烯片层组装成的三维宏观材料,因其孔隙率高、比表面积大、密度低、机械性能强等特点在油水分离领域具有广阔的应用前景,已成为当今的研究热点之一。本文结合最新研究进展系统地总结了石墨烯基气凝胶的结构设计、组装及干燥方法,归纳了近年来其在油水分离中的应用进展,并对石墨烯基气凝胶在油水分离领域的研究现状和未来研究方向做了简要评述,以期为该领域的深入探索提供新的视角。 相似文献
6.
Baoju Li Zitao Wang Zhuangzhuang Gao Jinquan Suo Ming Xue Yushan Yan Valentin Valtchev Shilun Qiu Qianrong Fang 《Advanced functional materials》2023,33(16):2300219
Covalent organic frameworks (COFs) are proposed as promising candidates for engineering advanced molecular sieving membranes due to their precise pore sizes, modifiable pore environment, and superior stability. However, COFs are insoluble in common solvents and do not melt at high temperatures, which presents a great challenge for the fabrication of COF-based membranes (COFMs). Herein, for the first time, a new synthetic strategy is reported to prepare continuous and intact self-standing COFMs, including 2D N-COF membrane and 3D COF-300 membrane. Both COFMs show excellent selectivity of H2/CO2 mixed gas (13.8 for N-COF membrane and 11 for COF-300 membrane), and especially ultrahigh H2 permeance (4319 GPU for N-COF membrane and 5160 GPU for COF-300 membrane), which is superior to those of COFMs reported so far. It should be noted that the overall separation performance of self-standing COFMs exceeds the Robeson upper bound. Furthermore, a theoretical study based on Grand Canonical Monte Carlo (GCMC) simulation is performed to explain the excellent separation of H2/CO2 through COFMs. Thus, this facile preparation method will provide a broad prospect for the development of self-standing COFMs with highly efficient H2 purification. 相似文献
7.
Dendrite‐Free Lithium Deposition via Flexible‐Rigid Coupling Composite Network for LiNi0.5Mn1.5O4/Li Metal Batteries
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Jingchao Chai Bingbing Chen Fang Xian Peng Wang Huiping Du Jianjun Zhang Zhihong Liu Huanrui Zhang Shanmu Dong Xinhong Zhou Guanglei Cui 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(37)
Notorious lithium dendrite causes severe capacity fade and harsh safety issues of lithium metal batteries, which hinder the practical applications of lithium metal electrodes in higher energy rechargeable batteries. Here, a kind of 3D‐cross‐linked composite network is successfully employed as a flexible‐rigid coupling protective layer on a lithium metal electrode. During the plating/stripping process, the composite protective layer would enable uniform distribution of lithium ions in the adjacent regions of the lithium electrode, resulting in a dendrite‐free deposition at a current density of 2 mA cm?2. The LiNi0.5Mn1.5O4‐based lithium metal battery presents an excellent cycling stability at a voltage range of 3.5–5.0 V with the induction of 3D‐cross‐linked composite protective layer. From an industrial field application of view, thin lithium metal electrodes (40 µm, with 4 times excess lithium) can be used in LiNi0.5Mn1.5O4 (with industrially significant loading of 18 mg cm?2 and 2.6 mAh cm?2)‐based lithium metal batteries, which reveals a promising opportunity for practical applicability in high energy lithium metal batteries. 相似文献
8.
《Ceramics International》2016,42(3):4556-4561
Eu-doped Ca-α-SiAlON phosphors, featuring high phase purity, uniform particle size of 3–5 μm and good luminescent properties with a yellow emission spectrum under blue light excitation, were prepared by a highly efficient combustion synthesis (CS) method. A certain amount of NaCl was applied as an innovative additive to regulate and control the properties of synthesized phosphors. Further, the effects of NaCl additive in the CS system were systematically investigated and rational proposed. It was found that the effect on accelerating nitridation and crystallization played a dominant role in the reaction as the content of NaCl was less than 6 wt%, while the effect of absorbing reaction heat through vaporization was dominant with the further-increased content of NaCl. The intensity of the emission spectrum for the sample doped with 6 wt% of NaCl was remarkably enhanced, nearly 40% more than the sample which was not NaCl-doped. Moreover, a continuous blue-shift phenomenon in emission spectra was observed with the increased content of NaCl. 相似文献
9.
A serial of novel A-D-A type small molecules with BODIPY linked through alkynyl with various electron donor units such as fluorene, carbazole, benzodithiophene and phenothiazine, namely F-BDP, C-BDP, B-BDP and P-BDP, respectively, were designed and synthesized. Introducing the alkynyl bridge leads to extending the molecular absorption spectrum to the range of 320–700 nm with high molar extinction coefficients (105 cm−1 M−1) and strong fluorescence quenching. The molecules showed relatively low HOMO ranging from −5.02 to −5.24 eV as estimated from cyclic voltammetry measurements. Interestingly, B-BDP with BDT as donor exhibits more obviously red-shifted absorption in the solid state compared to F-BDP, C-BDP and P-BDP. Furthermore, the solution-processed bulk-heterojunction organic solar cell based on B-BDP/PC71BM present superior charge transport property and more favorable nanoscale morphology, resulting in a significant higher Jsc of 11.84 mA cm2 and FF than the other counterparts, thus achieved a higher PCE of 4.65%, which is one of the best values among the ever reported BODIPY based organic solar cells. 相似文献
10.
In this work, we reported efficient polymer solar cells with balanced hole/electron mobilities tuned by the acceptor content in bulk heterojunction blend films. The photovoltaic cells were fabricated with two new wide band-gap D-A polymers PBDDIDT and PBDDIDTT as the donor material. The molecular conformations of new polymers are carefully evaluated by theoretical calculations. The results of photovoltaic studies show that two devices reach their optimal conditions with rich PC71BM content up to 80% in blend films, which is uncommon with most of reported PSCs. The as-cast devices based on PBDDIDT and PBDDIDTT reveal good photovoltaic performance with PCE of 7.04% and 6.40%, respectively. The influence of PC71BM content on photovoltaic properties is further detailed studied by photoluminescence emission spectra, charge mobilities and heterojunction morphology. The results exhibit that more efficient charge transport between donor and acceptor occurs in rich PC71BM blend films. Meanwhile, the hole and electron mobilities are simultaneously enhanced and afford a good balance in rich PC71BM blend films (D/A, 1:4) which is critical for the improvement of current density and fill factors. 相似文献