全文获取类型
收费全文 | 284篇 |
免费 | 6篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 1篇 |
化学工业 | 105篇 |
金属工艺 | 17篇 |
矿业工程 | 4篇 |
能源动力 | 82篇 |
轻工业 | 7篇 |
水利工程 | 1篇 |
石油天然气 | 1篇 |
无线电 | 23篇 |
一般工业技术 | 43篇 |
冶金工业 | 2篇 |
原子能技术 | 2篇 |
自动化技术 | 5篇 |
出版年
2023年 | 34篇 |
2022年 | 9篇 |
2021年 | 15篇 |
2020年 | 34篇 |
2019年 | 42篇 |
2018年 | 5篇 |
2017年 | 8篇 |
2016年 | 8篇 |
2015年 | 19篇 |
2014年 | 17篇 |
2013年 | 12篇 |
2012年 | 3篇 |
2011年 | 4篇 |
2010年 | 3篇 |
2009年 | 4篇 |
2008年 | 4篇 |
2007年 | 16篇 |
2006年 | 8篇 |
2005年 | 4篇 |
2004年 | 1篇 |
2003年 | 8篇 |
2002年 | 2篇 |
2001年 | 5篇 |
2000年 | 2篇 |
1999年 | 7篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1986年 | 3篇 |
排序方式: 共有293条查询结果,搜索用时 15 毫秒
1.
Hengrui Wang Yue Jiang Zhewen Ma Yongqian Shi Yanjun Zhu Ruizhe Huang Yuezhan Feng Zubin Wang Min Hong Jiefeng Gao Long-Cheng Tang Pingan Song 《Advanced functional materials》2023,33(49):2306884
MXene aerogels have shown great potential for many important functional applications, in particular electromagnetic interference (EMI) shielding. However, it has been a grand challenge to create mechanically hyperelastic, air-stable, and durable MXene aerogels for enabling effective EMI protection at low concentrations due to the difficulties in achieving tailorable porous structures, excellent mechanical elasticity, and desired antioxidation capabilities of MXene in air. Here, a facile strategy for fabricating MXene composite aerogels by co-assembling MXene and cellulose nanofibers during freeze-drying followed by surface encapsulation with fire-retardant thermoplastic polyurethane (TPU) is reported. Because of the maximum utilization of pore structures of MXene, and conductive loss enhanced by multiple internal reflections, as-prepared aerogel with 3.14 wt% of MXene exhibits an exceptionally high EMI shielding effectiveness of 93.5 dB, and an ultra-high MXene utilization efficiency of 2977.71 dB g g−1, tripling the values in previous works. Owing to the presence of multiple hydrogen bonding and the TPU elastomer, the aerogel exhibits a hyperelastic feature with additional strength, excellent stability, superior durability, and high fire safety. This study provides a facile strategy for creating multifunctional aerogels with great potential for applications in EMI protection, wearable devices, thermal management, pressure sensing, and intelligent fire monitoring. 相似文献
2.
Cheng-Jie Li Jin Hu Ge Gao Jia-Hao Chen Cheng-Shuang Wang Hong Zhou Guangxu Chen Peng Qu Peng Lin Wei-Wei Zhao 《Advanced functional materials》2023,33(8):2211277
Incorporating biomolecules into metal-organic frameworks (MOFs) as exoskeletons to form biomolecules-MOFs biohybrids has attracted great attention as an emerging class of advanced materials. Organic devices have been shown as powerful platforms for next-generation bioelectronics, such as wearable biosensors, tissue engineering constructs, and neural interfaces. Herein, biomolecules-incorporated MOFs as innovative gating module is realized for the first time, which is exemplified by biocatalytic precipitation (BCP)-oriented horseradish peroxidase (HRP)-embedded zeolitic imidazolate framework-90 (HRP@ZIF-90)/CdIn2S4 gated organic photoelectrochemical transistor under light illumination. In connection to a sandwich immunocomplexing targeting the model analyte human IgG, the IgG-dependent generation of H2O2 and the tandem HRP-triggered BCP reaction can cause the in situ blocking of the pore network of ZIF-90, leading to variant gating effect with corresponding responses of the device. This representative biodetection achieved good analytical performance with a wide linear range and a low detection limit of 100 fg mL−1. In the view of the plentiful biomolecule-MOF complexes and their potential interactions with organic systems, this study provides a proof-of-concept study for the generic development of biomolecules-MOFs-gated electronics and beyond. 相似文献
3.
《材料科学技术学报》2019,35(10):2345-2356
The corrosion kinetics and patina (corrosion products) layer evolution of galvanized steel submitted to wet/dry cyclic corrosion test in a simulated coastal-industrial atmosphere was investigated. The results show that zinc coating has a greater corrosion rate during the initial period and a lower corrosion rate during the subsequent period, and the patina composition and structure can greatly affect the corrosion kinetics evolution of zinc coating. Moreover, Zn5(OH)6(CO3)2 and Zn4(OH)6SO4 are identified as the main stable composition and exhibit an increasing relative amount; while Zn12(OH)15Cl3(SO4)3 cannot stably exist and diminish in the patina layer as the corrosion develops. 相似文献
4.
《Optical Materials》2005,27(3):503-507
We report a comparative study of the spectroscopic and stimulated emission properties of a model oligo(phenylene vinylene) with those of the corresponding partially conjugated poly(phenylene vinylene). The model oligomer exhibits dual Amplified Spontaneous Emission (ASE) at 430 and 450 nm attributed to two independent vibrational modes in the excited state of the molecule. The corresponding polymer exhibits single ASE at 453 nm implying that in the polymer chains the amplification originates from a single vibrational mode. The efficiency of ASE and laser action is lower in the polymer than in the oligomer because of defects in the polymer chains. 相似文献
5.
《International Journal of Hydrogen Energy》2019,44(31):16110-16119
The activity of transition metal dichalcogenides (TMD) toward hydrogen evolution reaction (HER) derives from the active sites at the edges, but the basal surface still remain catalytic insert. Herein, ultrathin MoSSe alloy nanosheets array on multiwalled carbon nanotubes (MWCNTs) to form a core shell structure via a simple solvothermal process. These three-dimensional (3D) MoSSe hybrids show a high activity in hydrogen evolution reaction (HER) with a small Tafel slope of 38 mV dec−1 and a low overpotential of 102 mV at 10 mA cm−2. In addition, their HER activity remains remarkably stable without significant decay after 100 h polarization. Such superior catalytic HER activity springs from the 3D hierarchical heterostructure, which is abundant of catalytic edge sites, and the alloy effect between S and Se, which will create huge defects and strain to form vacancy sites on the basal plane. This strategy may open a new avenue toward the development of nonprecious high-performance HER catalysts. 相似文献
6.
《International Journal of Hydrogen Energy》2019,44(12):6172-6181
Graphitized carbon (GC) nanocages have been successfully prepared via a sustainable carbon powder buried-type Ni catalysis-growth technology from Tween-80 molecule precursor. The GC nanocages are used as support for the further construction of GC/Pd electrocatalyst towards ethanol oxidation reaction. The material structures and surface morphologies are studied by XRD, SEM and TEM techniques. The electrochemical properties are investigated by CV, LSV, EIS and CP techniques. The results showed that GC nanocages have good graphited structure and plentiful opening gaps, and the Pd nanoparticles were evenly distributed on the inner and outer surfaces of GC nanocages. The GC/Pd electrocatalyst exhibits excellent electrocatalytic performance towards ethanol oxidation. The positive scanning peak current density of GC/Pd electrode is up to 1612 A/g Pd in 1.0 mol/L NaOH +1.0 mol/L ethanol electrolyte, which is much higher than those (500–1100 A/g Pd) of traditional Pd electrodes supported with carbon nanotubes or graphene nanosheets. 相似文献
7.
《International Journal of Hydrogen Energy》2019,44(57):30185-30195
Nowadays, energy shortage is one of the major problems in the world. Photocatalytic hydrogen production is a new type of energy technology with good application prospect. As a new type of photocatalytic semiconductor material, g-C3N4 has attracted much attention as a photocatalyst. By ultrasonic treatment of a mixed solution of g-C3N4 and bovine serum albumin, followed by adding a certain amount of silver nitrate solution and then directly hydrothermal treatment, a special dandelion-like g-C3N4/Ag (D-g-C3N4/Ag) was prepared. The scanning electronic microscopy, transmission electronic microscopy, X-ray diffraction, Fourier transform infrared, fluorescence and physicochemical adsorption methods were used to characterize the morphology and structure of D-g-C3N4/Ag. In addition, the photocatalytic H2 production of D-g-C3N4/Ag with different Ag loadings or in different sacrificial agents and different pH conditions were investigated. The results indicated that when triethanolamine was used as sacrificial agent, photocatalytic hydrogen efficiency was the best, and the rate of photocatalytic hydrogen production reached 862 μmol g−1 h− 1 as the Ag loading was 4%. 相似文献
8.
The Density of States (DOS) is an ingredient of critical importance for the accurate physical understanding of the optoelectronic properties of organic semiconductors. The disordered nature of this class of materials, though, renders the task of determining the DOS far from trivial. Its extraction from experimental measurements is often performed by driving the semiconductor out of thermal equilibrium and therefore requires making assumptions on the charge transport properties of the material under examination. This entanglement of DOS and charge transport models is unfavorable since transport mechanisms in organic semiconductors are themselves still subject of debate. To avoid this, we propose an alternative approach which is based on populating and probing the DOS by means of capacitive coupling in Metal Insulator Semiconductors (MIS) structures while keeping the semiconductor in thermal equilibrium. Assuming a Gaussian shape, we extract the DOS width by numerical fitting of experimental Capacitance–Voltage curves, exploiting the fact that the DOS width affects the spatial distribution of accumulated charge carriers which in turn concurs to define the MIS capacitance. The proposed approach is successfully tested on two benchmark semiconducting polymers, one of n-type and one of p-type and it is validated by verifying the robustness of the extraction procedure with respect to varying the insulator electrical permittivity. Finally, as an example of the usefulness and effectiveness of our approach, we study the static characteristics of thin film transistors based on the aforementioned polymers in the framework of the Extended Gaussian Disorder transport model. Thanks to the extracted DOS widths, the functional dependence of current on the gate voltage is nicely predicted and physical insight on transistor operation is achieved. 相似文献
9.
Potassium-ion batteries (PIBs) have aroused considerable interest as a promising next-generation advanced large-scale energy storage system due to the abundant potassium resources and high safety. However, the K+ with large ionic radius brings restricted diffusion kinetics and severe volume expansion in electrode materials, resulting in inferior actual rate characteristics and rapid capacity fading. Designing electrode materials with one-dimensional (1D) nanostructure can effectively enhance various electrochemical properties due to the well-guided electron transfer pathways, short ionic diffusion channels and high specific surface areas. In this review, we summarize the recent research progress and achievements of 1D nanostructure electrode materials in PIBs, especially focusing on the development and application of cathode and anode materials. The nanostructure, synthetic methods, electrochemical performances and structure-performance correlation are discussed in detail. The advanced characterizations on the reaction mechanisms of 1D nanostructure electrode materials in PIBs are briefly summarized. Furthermore, the main future research directions of 1D nanostructure electrode materials are also predicted, hoping to accelerate their development into the practical PIBs market. 相似文献
10.
《Ceramics International》2016,42(6):7309-7314
Metal oxide nanocomposite sensors based on γ-Fe2O3 and WO3 were investigated in acetone vapor of various concentrations (1–100 ppm) at operating temperatures between 250 and 350 °C. The composites were prepared by simple solid state mixing and porous thick-film gas sensors were fabricated on alumina substrates. The γ-Fe2O3:WO3 (50:50) nanocomposite showed a marked enhancement in sensing response down to 1 ppm acetone vapor detection at 300 °C. The response was ~2-fold better compared to pure WO3 or pure γ-Fe2O3 with a very fast response (1 s) and very short recovery time (3 s). No appreciable sensitivity was observed towards alcohol vapor (an interfacing agent for diabetics) and in moisture (present in breath). The enhanced performance was due to n–n heterojunction effect. 相似文献