Cu基络合物催化甲醇液相氧化羰化反应

针对甲醇液相氧化羰基化法合成碳酸二甲酯(DMC)工艺,开发了新型Cu基络合催化剂(CuB rnLm)。对CuB rnLm催化剂的活性及其稳定性进行了研究。实验结果表明,采用该催化剂,甲醇转化率和DMC选择性较高;元素价态和物质结构分析表明,CuB rnLm催化剂循环使用5次后仍保持较好的稳定性。采用正交设计和中心响应曲面法设计实验,并使用S tatistica软件进行统计分析,寻求出反应的主要影响因素,并得到优化的工艺条件:反应温度100~110℃、反应压力3.0~3.5M Pa、反应时间4~6h、CuB rnLm催化剂质量浓度(以甲醇的体积计)0.15~0.20g/mL。在此工艺条件下,甲醇转化率可达23%以上,DMC的选择性为96%~98%。     

泌阳凹陷复杂断块群油气分布控制因素

泌阳凹陷北部斜坡复杂断块群油田以断鼻、断块及断层+岩性油气藏为主,垂向含油层系多,平面上叠合连片,油气主要富集在鼻状构造主体部位的断鼻断块内。通过对研究区油气控制因素的分析,指出继承性的鼻状构造控制了油气聚集方向和富集程度,油气藏含油范围和油气藏高度则主要受断层封闭性和封闭程度的控制,油气分布规律受伸展构造所伴生的各种断块群构造型式的控制。     

A Study on Turbo—rotor Multi—fault Diagnosis Based on a Neural Network

The multi-fault phenomena are common in the turbo-rotor system of a liquid rocket engine.As it has many excellent qualities,the neural network might be used to solve the problems of multi-fault diagnasis of a turbo-rotor system.First,the feature expression of a common turbo-rotor fault was studied in order to build up the standard fault pattern and satisfy the need of neural network studying and diagnosing.Then.the turbo-rotor fault identification and diagnosis problems were investigated by using a BP(back-propaga-tion)neural network.According to the BP neural network problems,the parallel BP neural network method of multi-fault diagnosis and classification was presented and investigated.The results indicated that the parallel Bp neural network method could solve the turbo-rotor multi-fault diagnosis problems.     

Ca掺杂钨镁酸铅陶瓷材料的制备及其介电性能

研究了Ca掺杂钨镁酸铅(PMW)陶瓷材料的合成、结构、烧结以及介电性能。结果发现：在Ca^2 摩尔分数小于15％时，能形成单相的PCMW钙铁矿相，结构由原来的斜方相向立方相转变。用二步合成法制备的样品容易致密烧结，气孔率比一步法制备的样品小。Ca的加入降低了材料的介电损耗，在频率为1MHz时，介质损耗达到了10^-4。当Ca^2 摩尔分数大于10％时，材料的Curie峰宽化显著，介电常数温度系数降低。     

低温高速离心泵的研制与应用

阐述了适合于输送低温介质的高速离心泵的水力设计和结构设计方法，结构上采有长，中，短叶片相间的复合叶轮及双密封结构，理论上采用以效率为目标函数的优化水力设计方法，保证了低温高速离心泵具有很好的工人可靠性和优越的性能指标。     

聚合物载体－稀土金属络合物的研究 ⅩⅢ．聚［苯乙烯－甲基丙烯酸β（甲基亚硫酰基）乙酯］的结构与其稀土金属络合物催化丁二烯聚合的活性

从测得的竞聚率计算了单体链节在聚［苯乙烯－甲基丙烯酸β（甲基亚硫酰基）乙酯］（ＰＳＭ）中的序列分布。苯乙烯（Ｓ）或甲基丙烯酸β（甲基亚硫酰基）乙酯（Ｍ）的长序列的概率随着ＰＳＭ中相应单体含量的增加而增加。对于Ｓ和Ｍ摩尔分数大致相等的ＰＳＭ，单体链节的长序列分布函数值相接近。用与此结构相近的ＰＳＭ合成的稀土金属络合物，其催化活性不佳。在Ｍ短序列分布和Ｓ长序列分布较高的情况下，络合物的催化活性最好。所得聚丁二烯的微观结构与ＰＳＭ中单体单元的分布无关。     

千米桥潜山构造特征及其在油气成藏中的作用

千米桥潜山是黄骅坳陷最典型的新生古储型油气藏，恢复潜山古构造是认识其油气藏特征的重点和难点之一，运用地质力学方法研究潜山内幕构造之后认为，该潜山的形成基础是古生界印支期宽缓复背斜，在燕山期挤压构造作用下形成由逆冲叠瓦扇和反冲断层构成的三角带内幕构造，抬升受侵蚀形成潜山主体，喜马拉雅的两次古旋拉张使潜山掀斜定型。晚第三纪以来发生整体热沉降，潜山两侧凹陷沙三段生成油气向潜山侧向运移成藏。     

Host/guest complex of Me-β-CD/2,2-dimethoxy-2-phenyl acetophenone for initiation of aqueous photopolymerization: Kinetics and mechanism

Methylated-β-cyclodextrin (Me-β-CD) was used to complex the photoinitiator, 2,2-dimethoxy-2-phenyl acetophenone (DMPA), yielding a water-soluble host/guest complex. The comparative studies demonstrated that the Me-β-CD complexed DMPA exhibited a high photoreactivity identical to the uncomplexed DMPA, while the CD complex obviously influenced the products of primary photolysis of DMPA and the photopolymerization kinetics due to the steric effect of CD on the subsequent initiation reactions. The photopolymerization rate of acrylamide can be described by the equation: R_p=K[2a]^0.62[M]^1.37[I]^0.5[Me-β-CD]⁰. The mechanism of polymerization was also discussed.     

Operation of superconducting fault current limiter using vacuum interrupter driven by electromagnetic repulsion force for commutating switch

Using conventional high‐temperature superconducting wire, a model superconducting fault current limiter (SFCL) is made and tested. Solenoid coil using Bi2223 silver sheath wire is so made that inductance is as small as possible and a vacuum interrupter is connected in series to it. A conventional reactor coil is connected in parallel. When the fault current flows in this equipment, superconducting wire is quenched and current is transferred into the parallel coil because of voltage drop of superconducting wire. This large current in parallel coil actuates magnetic repulsion mechanism of vacuum interrupter. Due to opening of vacuum interrupter, the current in superconducting wire is broken. By using this equipment, current flow time in superconducting wire can be easily minimized. On the other hand, the fault current is also easily limited by large reactance of parallel coil. © 2008 Wiley Periodicals, Inc. Electr Eng Jpn, 164(1): 52–61, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20315