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1.
G. Biallas Dr.‐Ing. C. Sick J. Schneider K.‐H. Trautmann 《Materialwissenschaft und Werkstofftechnik》2007,38(9):705-711
Biaxial fatigue of friction stir welded stiffened panels Within the framework of the European WelAir project, cruciform specimens made from stiffening FSW overlap joints were fatigued in the DLR biaxial test rig. To resemble the loading situation of pressurized fuselage structures, proportional loading without any phase shift, but with different load ratios λ between the loading components in both directions was applied.Natural crack initiation and subsequent crack growth were governed by the stiffness gradient caused by introducing the stringer. Cracks initiated and propagated at run‐in and run‐out locations in a direction perpendicular to the weld seam. The shortest fatigue life was observed for uniaxial loading in welding direction (λ = 0). An additional stress component perpendicular to the joint line (λ > 0) resulted in a higher number of cycles to failure. Similar to single stringer panels, increasing the load ratio also increased the number of cycles to failure for FSW clip‐stringer structural members, but additionally gives a different location of the fatal crack. 相似文献
2.
Effect of atmospheric pollutants on the corrosion of high power electrical conductors: Part 1. Aluminium and AA6201 alloy 总被引:2,自引:0,他引:2
Rosa Vera 《Corrosion Science》2006,48(10):2882-2900
The aim of this study was to evaluate the joint effect of marine and industrial pollutants on the atmospheric corrosion of aluminium and its AA6201 alloy. Weight loss was determined after 4, 11, 16 and 24 months exposure being morphology and attack intensity analysed through SEM-EDX. Both materials showed the most intense attack for the highest SO2 contents. Good correlation among weight loss, attack depth and tensile strength to rupture with time and with pollutant contents was determined for both materials in most sites. The cause for low aggressiveness of the heaviest Cl− polluted atmosphere on aluminium was electrochemically demonstrated. 相似文献
3.
J.M. Montero-Moreno 《Surface & coatings technology》2007,201(14):6352-6357
1050 Aluminum alloy sheets were used to analyze the influence of a surface treatment on the characteristics of the alumina layer formed in a two-step anodizing. The study was mainly focused on two pretreatment steps, electropolishing and acid etching, as well as on the intermediate stripping step. The pretreatment procedure was optimized by accounting for the chemical nature of the substrate, with the results indicating that additional pretreatment steps enhanced the self-ordered porous arrangement. The E-t curves recorded during the experiments demonstrated that the best alumina layers were obtained when the first barrier layer had a high resistance; i.e., a high anodizing potential. The application time of the stripping step was optimized to clean the surface from alumina remains, without damaging the aluminum substrate. By optimizing all of these experimental conditions, we were able to obtain porous anodic aluminum oxide layers displaying ordered domains several hundreds of nanometers in length. 相似文献
4.
VAc/AA改性的VAE乳液高速接嘴卷烟胶的研制 总被引:4,自引:0,他引:4
介绍了VAc/AA改性的VAE乳液高速接嘴卷烟胶的制备方法。研究了各种因素对胶粘剂性能的影响。结果表明 :VAc/AA用量增加 ,VAE乳液的粘接性能增强。选择与VAE乳液相适应的乳化剂和控制适宜的pH值 ,可以增加VAE乳液的稳定性。采用滴加引发剂和混合单体的方法 ,可以避免过速反应产生及大粒径胶粒生成 相似文献
5.
Neung‐Ju Lee Ja‐Chul Koo Sung‐Suk Ju Seong‐Bae Moon Won‐Jei Cho In‐Cheol Jeong Song‐Jae Lee Moo‐Youn Cho Emmanuel A Theodorakis 《Polymer International》2002,51(7):569-576
The attachment of anticancer agents to polymers is a promising approach towards reducing the toxic side‐effects and retaining the potent antitumour activity of these agents. A new tetrahydrophthalimido monomer containing 5‐fluorouracil (ETPFU) and its homopolymer and copolymers with acrylic acid (AA) and with vinyl acetate (VAc) have been synthesized and spectroscopically characterized. The ETPFU contents in poly(ETPFU‐co‐AA) and poly(ETPFU‐co‐VAc) obtained by elemental analysis were 21 mol% and 20 mol%, respectively. The average molecular weights of the polymers determined by gel permeation chromatography were as follows: Mn = 8900 g mol?1, Mw = 13 300 g mol?1, Mw/Mn = 1.5 for poly(ETPFU); Mn = 13 500 g mol?1, Mw = 16 600 g mol?1, Mw/Mn = 1.2 for poly(ETPFU‐co‐AA); Mn = 8300 g mol?1, Mw = 11 600 g mol?1, Mw/Mn = 1.4 poly(ETPFU‐co‐VAc). The in vitro cytotoxicity of the compounds against FM3A and U937 cancer cell lines increased in the following order: ETPFU > 5‐FU > poly(ETPFU) > poly(ETPFU‐co‐AA) > poly(ETPFU‐co‐VAc). The in vivo antitumour activities of all the polymers in Balb/C mice bearing the sarcoma 180 tumour cell line were greater than those of 5‐FU and monomer at the highest dose (800 mg kg?1). © 2002 Society of Chemical Industry 相似文献
6.
The influence of copper on the morphologies of porous anodic alumina has been investigated under current and voltage control using a sputtering-deposited Al-2.7 at.% Cu alloy and a commercial AA 2024-T3 aluminium alloy anodized in either sulphuric acid electrolyte or the same electrolyte but with addition of tartaric acid. The findings indicate that film development involves repeated formation of embryo cells of anodic alumina at the metal/film interface. During the initial stages of anodizing at constant voltage, cell formation is accompanied by current peaks in the current-time response. The porosity of the resultant films has a lateral aspect due to the layering of embryo cells. The thickness of individual layers is proportional to the formation voltage, with a ratio of the order 1 nm V−1. The cell formation is accompanied by enrichment of copper in the alloy, incorporation of copper species into the anodic film, in low amounts relative to the alloy, and evolution of oxygen. These processes disrupt the formation of the classical pore morphology, characteristic of high purity aluminium, due to continuous formation of fresh embryo cells and re-direction of pores. The main effect of the tartaric acid addition to the sulphuric acid was to reduce the rate of anodizing of the alloys at constant voltage by about 10-20%. 相似文献
7.
Danqing Zhu 《Corrosion Science》2003,45(10):2163-2175
This study consists of two parts. In the first part, the corrosion of 2024-T3 aluminum alloy (AA 2024-T3) was studied using scanning electron microscopy and energy-dispersive X-ray spectroscopy. The results showed that the anodic S phase (Al2CuMg) particles dealloyed Al and Mg during the 3.5 h of immersion in a neutral 0.6 M sodium chloride (NaCl) solution; with the dealloying of Mg being the most severe. Simultaneously, a heavy dissolution was also observed for the surrounding Al matrix of the S phase particles. This Al dissolution is likely to be caused by a local alkalization resulting from the coupled cathodic reaction (water and/or oxygen reduction). Such corrosion in AA 2024-T3, however, can be inhibited efficiently after the treatment of bis-[3-(triethoxysilyl)propyl]tetrasulfide (bis-sulfur silane). The associated studies on bis-sulfur silane treated AA 2024-T3 will be presented in the second part. 相似文献
8.
A. Gnanavelbabu Kaliyamoorthy Rajkumar P. Saravanan 《Materials and Manufacturing Processes》2018,33(12):1313-1323
Aluminum metal matrix composites (AMMCs) explicitly show better physical and mechanical properties as compared to aluminum alloys and results in a more preferred material for a wide range of applications. The addition of reinforcements embargo AMMCs employment to industry requirements by increasing order of machining complexity. However, it can be machined with a high order of surface integrity by nonconventional approaches like abrasive water jet machining. Hybrid aluminum alloy composites were reinforced by B4C (5–15?vol%) and solid lubricant hBN (15?vol%) particles and fabricated using a liquid metallurgy route. This research article deals with the experimental investigation on the effect of process parameters such as mesh size, abrasive flow rate, water pressure and work traverse speed of abrasive water jet machining on hybrid AA6061-B4C-hBN composites. Water jet pressure and traverse speed have been proved to be the most significant parameters which influenced the responses like kerf taper angle and surface roughness. Increase in reinforcement particles affects both the kerf taper angle and surface roughness. SEM images of the machined surface show that cutting wear mechanism was largely operating in material removal. 相似文献
9.
Shih Hao Huang Hwa Seng Khoo Shang Yu ChangChien Fan Gang Tseng 《Microfluidics and nanofluidics》2008,5(4):459-468
Monodisperse copolymer particles carrying surface carboxyl groups in the range of 50–200 μm were prepared by in situ UV polymerization
of ethyleneglycol dimethacrylate (EGDMA) with acrylic acid (AA) via a microfluidic flow-focusing device (MFFD). The design
of the coaxial orifices in the MFFD enables the confinement of the comonomer liquid thread to the central axis of the microchannel,
which can avoid the wetting problem of comonomer liquid with the microchannel and can successfully produce monodisperse copolymer
microspheres with coefficient of variance below 5%. The effects of concentration of EGDMA and AA on droplet diameters and
the distribution of carboxyl group on particle surfaces were examined. It has been found that, increasing the concentration
of AA would decrease particle sizes, but increase the distribution of carboxyl group on particle surfaces. Bioconjugation
of the carboxylated copolymer particles with the anti-rabbit IgG–Cy3 conjugates was successfully demonstrated. By increasing
the concentration of AA accompanied with decreasing the particle sizes, high efficiency of bioconjugation on carboxylated
copolymer particles was achieved. The rapid continuous synthesis of carboxylated copolymer particles via a microfluidic device
provides a reliable control of particle sizes and composition for massive production in biotechnological applications. 相似文献
10.
丙烯酸与丙烯酰胺共聚制备高吸水纤维的研究 总被引:2,自引:0,他引:2
采用溶液聚合法合成了丙烯酸/丙烯酰胺共聚物纺丝液,并纺制成纤维.研究了丙烯酰胺用量、中和度、引发剂用量、聚乙烯醇用量、交联时间等因素对纤维吸水倍率的影响,并用扫描电镜观察纤维的横截面和纵向表面,对制得的高吸水纤维进行SEM分析. 相似文献