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排序方式: 共有217条查询结果,搜索用时 31 毫秒
1.
Grzegorz Moskal 《Microscopy research and technique》2020,83(5):523-530
The presented article characterized microstructural aspects of thermal barrier coatings (TBCs) analysis using methods of electron microscopy such as electron backscatter diffraction (EBSD), transmission/scanning electron microscopy (S/TEM), and TEM. The analyzed TBC system is based on gadolinium zirconate deposited by air plasma spraying method, and additionally, it was subjected to an oxidation test for 500 hr at a temperature of 1,100°C. Moreover, the morphological characterization of feedstock powder was showed. EBSD analysis revealed the inhomogeneity of feedstock materials in the form of complex phase composition. In the case of deposited coating, this method was used to characterize the crystallite size of zirconate coating and phase composition of thermally grown oxide zone. S/TEM and TEM analysis showed morphological details of this zone but not revealed such phase as perovskite oxide of GdAlO3 type. 相似文献
2.
Federico Cernuschi Paolo Bison Daniel E. Mack Marco Merlini Stefano Boldrini Stefano Marchionna Stefano Capelli Stefano Concari Alessia Famengo Alessandro Moscatelli Werner Stamm 《Journal of the European Ceramic Society》2018,38(11):3945-3961
In the perspective of fuelling the future generations of gas turbines by hydrogen rich syngas, the evaluation of the effect of a higher water vapour content into the flue gases on the TBC used, or potentially usable, is a need. For this purpose YPSZ APS TBC with two different microstructures have been exposed for 500?h at different temperatures in the range 1000?°C–1250?°C either in air and air +20% vol. H2O. The comparison between the different testing conditions has been performed in terms of sintering kinetics and phase stability, as evaluated by thermal diffusivity measurements and Synchrotron X-Rays diffraction, respectively. Furthermore the characterisation of thermal properties of two innovative TBCs (GZO-YPSZ and YAG) potentially able to withstand the CMAS attack and erosive environments, respectively, has been carried out.No clear evidence of a different behaviour of TBC has been observed, at least in the considered aging time and temperature range. 相似文献
3.
Advanced high-energy plasma systems are being used to achieve the benefits of the high-velocity oxy-fuel (HVOF) system without
losing the inherent advantages of plasma for coating of gas turbine parts. MCrAlY coatings play a very important role in the
performance and reliability of gas turbine components. One of the important considerations for next generation of gas turbines,
which have more demanding conditions and need to withstand ever increasing operating temperatures, is that they should possess
very low oxygen content levels in the coating. Low oxygen content coatings are applied by the expensive low-pressure plasma
spray (LPPS)/vacuum plasma spray (VPS) technique for critical components in aero- and land-based gas turbines. This work deals
with the development of low-cost LPPS equivalent coatings (having low oxygen content) using the high-energy high-velocity
plasma spray (HEHVPS) gun and inert gas shroud. A comparison has also been made with CoNiCrAlY coatings by HVOF. 相似文献
4.
通过咪唑基离子液体和蒙脱土在甲苯溶液中的离子交换反应,将热稳定性高的咪唑基有机阳离子[C14mim]+交换吸附进入蒙脱土片层间,制备了蒙脱土负载的有机阳离子固体催化剂[C14mim]+/MMT。利用XRD和TGA对催化剂的结构与性能进行了表征和测定,研究了蒙脱土负载有机阳离子固体催化剂的催化性能,初步考察了其稳定性及再次使用效率。研究结果表明,[C14mim]+/MMT在合成无毒增塑剂柠檬酸三丁酯的酯化反应中表现出较高的催化活性,可循环使用。与未负载的C14mimBF4相比,[C14mim]+/MMT具有催化活性高、稳定性好和易分离的特点。 相似文献
5.
关于基体曲率的热障涂层残余应力分析 总被引:1,自引:0,他引:1
采用空心和实心四相同心圆模型,导出了轴对称温度应力状态下的位移公式,分析了基体曲率对热障涂层残余应力的影响。结果表明:热障涂层结构中各层内既有环向应力,又有径向应力,应力大小与温降成线性关系;当陶瓷层在外层时,在氧化层/陶瓷层和粘结层/氧化层界面上产生垂直界面的拉应力,且实心模型的拉应力远大于空心模型的拉应力;当陶瓷层在里层时,空心模型中相应界面上的应力为压应力。 相似文献
6.
A durable ceramic thermal barrier coating is applied directly to a smooth, highly oxidation resistant intermetallic alloy
in two layers. The first layer of ceramic is applied by low pressure plasma spraying and the second layer is applied by conventional
atmospheric pressure plasma spraying. This approach would allow the use of plasma sprayed ceramic coatings in applications
where a metallic bond coat is not desirable. 相似文献
7.
8.
Synthesis and thermophysical properties of RETa3O9 (RE = Ce,Nd, Sm,Eu, Gd,Dy, Er) as promising thermal barrier coatings 下载免费PDF全文
Lin Chen YeHua Jiang XiaoYu Chong Jing Feng 《Journal of the American Ceramic Society》2018,101(3):1266-1278
Thermal barrier coatings (TBCs) are one of the most important materials in gas turbine to protect the high temperature components. RETa3O9 compounds have a defect‐perovskite structure, indicating that they have low thermal conductivity, which is the critical property of TBCs. Herein, dense RETa3O9 bulk ceramics were fabricated via solid‐state reaction. The crystal structure was characterized by X‐ray diffraction (XRD) and Raman Spectroscope. Scanning electron microscope (SEM) was used to observe the microstructure. The thermophysical properties of RETa3O9 were studied systematically, including specific heat, thermal diffusivity, thermal conductivity, thermal expansion coefficients, and high‐temperature phase stability. The thermal conductivities of RETa3O9 are very low (1.33‐2.37 W/m·K, 373‐1073 K), which are much lower than YSZ and La2Zr2O7; and the thermal expansion coefficients range from 4.0 × 10?6 K?1 to 10.2×10?6 K?1 (1273 K), which is close to La2Zr2O7 and YSZ. According to the differential scanning calorimetry (DSC) curve there is not phase transition at the test temperature. Due to the high melting point and excellent high‐temperature phase stability with these oxides, RETa3O9 ceramics were promising candidate materials for TBCs. 相似文献
9.
《Materials at High Temperatures》2013,30(2):197-203
AbstractThe degradation of thermal barrier coatings is closely linked to their spalling resistance which depends on the stability of the protective oxide scale produced by oxidation of the bond-coat. This study deals with a characterisation of the oxide layer, its interfaces with the bond-coat and the ceramic and their evolution during isothermal oxidation at 1,100°C. The microstructural evolution of the bond-coat, the outer part of the superalloy and the ceramic layer was also studied. 相似文献
10.
目的 提高YSZ涂层的服役寿命.方法 采用火焰喷涂和等离子喷涂的方法,在GH4169高温合金上分别制备NiCoCrAlY粘结层和8YSZ陶瓷层.在制备陶瓷层之前,通过低压喷砂的方法对粘结层表面进行处理,改变粘结层的表面粗糙度.利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、3D测量激光显微镜,表征涂层的物相、微观形貌和表面粗糙度.使用马弗炉进行1100℃的热震实验,表征YSZ涂层的热震性能.结果 通过喷涂方法制备的粘结层,表面较为粗糙,喷砂处理后,有效地改善了表面情况,表面粗糙度下降了1~3μm.随着热震实验的进行,陶瓷层和粘结层中间形成的热生长氧化物(TGO)不断增厚.喷砂处理后,涂层的氧化速率降低.热震实验后,涂层边缘处会萌生微裂纹,随着裂纹的累积扩展,最终贯通,形成局部的涂层剥离.失效前后,YSZ没有相变发生.结论 涂层失效多发生在TGO界面处,粘结层的高温氧化引起TGO层生长增厚,会导致涂层的失效.平整的TGO生长界面可以减少接触面,降低粘结层的氧化速率.平整界面可以避免局部起伏造成的TGO过度生长.经过表面喷砂处理改善粘结层粗糙度的涂层,具有更优异的抗热震性能.TGO层的形成和生长,容易导致微裂纹的萌生和扩展.粘结层表面处理后,能够为TGO的形成和生长提供相对平整的界面,有效提高TGO的质量,进而提高涂层的抗热震性能. 相似文献