全文获取类型
收费全文 | 78篇 |
免费 | 13篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 2篇 |
综合类 | 10篇 |
化学工业 | 37篇 |
建筑科学 | 1篇 |
矿业工程 | 6篇 |
能源动力 | 21篇 |
轻工业 | 8篇 |
石油天然气 | 4篇 |
一般工业技术 | 3篇 |
冶金工业 | 1篇 |
出版年
2022年 | 1篇 |
2021年 | 3篇 |
2020年 | 7篇 |
2019年 | 3篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 3篇 |
2015年 | 5篇 |
2014年 | 3篇 |
2013年 | 2篇 |
2012年 | 8篇 |
2011年 | 11篇 |
2010年 | 8篇 |
2009年 | 4篇 |
2008年 | 1篇 |
2007年 | 8篇 |
2006年 | 3篇 |
2005年 | 4篇 |
2004年 | 3篇 |
2003年 | 5篇 |
排序方式: 共有93条查询结果,搜索用时 15 毫秒
1.
Characterisation of two biomass fuels (pelletised Miscanthus Giganteus and wood) was performed using thermogravimetric analysis with measurement of products by means of Fourier transform infrared spectroscopy (TG-FTIR). Three heating rate profiles were applied (10, 30 and 100 °C/min), with a final temperature of 900 °C. HCN and HNCO were found to be the major N-products, while the NH3 fraction was detected to a minor extent. Kinetic parameters were obtained from the TG-FTIR results using a model based on parallel first-order reactions with a Gaussian distribution of activation energies. On the basis of the above kinetic analysis and product yields, input files for the functional group-devolatilisation, vaporisation, cross-linking biomass-pyrolysis model were prepared. The fit of model parameters to TG-FTIR product-evolution data was found to be generally good, but the model-predicted yields for some species did not fit experimental data at all heating rates. Further improvements in the model are needed to resolve above difficulty. 相似文献
2.
利用热重-红外联用(TG-FTIR)分析了Adaro煤与棕榈空果串(EFB)在富氧混烧工况下的特性.热重分析仪记录样品在加热过程中的质量损失,而FTIR则分析其释放的气体产物.对在18%O_2/82%CO_2,Air(21%O_2/79%N_2),21%O_2/79%CO_2,30%O_2/70%CO_24种工况下Adaro coal+30%EFB样品进行燃烧.热重分析表明,与O_2/N_2工况相比,O_2/CO_2条件下CO_2气体对燃烧有抑制作用,且空气工况下与30%O_2/70%CO_2的燃烧特性相当.FTIR分析释放的气体主要是CO_2,CO,H_2O. 相似文献
3.
4.
利用热重-红外联用仪对城市污泥、神华煤水煤浆及污泥水煤浆的气化特性进行了分析,考察了污泥对神华煤水煤浆气化特性的影响。结果表明:污泥和神华煤基础性质不同,气化过程中两者总失重率、失重速率和气化起始温度存在明显差异;污泥反应后的气体产物中含有少量的烃类物质,且污泥产生CO的初始温度和含量均低于神华煤水煤浆;污泥水煤浆的气化起始温度因污泥的掺入降低约30℃,随着污泥掺混比例的提高,污泥水煤浆的气化起始温度逐渐降低,反应完成所需的时间逐渐减少,反应特性指数Rs逐渐增大。通过对污泥碱性指数B的计算,可以看出污泥的"碱性指数"B>1,说明污泥对污泥水煤浆气化具有促进作用。 相似文献
5.
生物质催化热解的TG-FTIR研究 总被引:2,自引:0,他引:2
借助综合热分析仪和傅立叶红外联用技术(TG-FTIR),考察了HUSY、REY和HZSM-53种分子筛以及重油催化裂化催化剂MLC和馏分油催化裂解催化剂CIP对生物质催化热解的活性和选择性。研究结果表明,分子筛对生物质热解产物的脱氧活性顺序为:REY≈HUSY>HZSM-5,生成高辛烷值烃类的选择性顺序为:REY>HUSY≈HZSM-5;MLC催化剂和CIP催化剂都表现出较高的选择活性,前者的脱氧活性略高于后者;择形分子筛HZSM-5的引入对调整催化剂酸强度、提高催化转化选择性和抑制焦炭生成产生一定作用。 相似文献
6.
利用TG-FFIR技术研究陕西关中地区小麦秸秆(麦秆)、聚对苯二甲酸乙二醇酯(PET)及其两者混合物麦秆-PET(质量比1∶1)在20 K/min的升温速率下的热解行为、主要热解产物、协同效应和动力学.研究结果表明:PET热解初始温度为375℃,最大热失重速率处的温度为454.9℃,失重率为62.87%,其热解残余质量... 相似文献
7.
Mannose was selected as a model compound of hemicellulose and its thermal behavior over zeolites has been investigated using a TG-FTIR analyzer. There was an initial study of the chemical structure of mannose and a characterization of the catalysts. All three catalysts, HZSM-5, H-β and USY, had a significant influence on the dehydration, cracking and deoxygenation reactions during the pyrolysis of mannose. The dehydration reaction in the initial stage was enhanced, resulting in two separate water release processes, while the char formation was suppressed. USY had the best effect on dehydration, and HZSM-5 obtained the highest deoxygenation efficiency. The presence of HZSM-5 and H-β catalyzed the formation of water and CO2, while suppressing the formation of oxygenated compounds and char residues. 相似文献
8.
Ming Sun Dan Zhang Minghui Huang Jing Chen Xing Tang Chao He 《Petroleum Science and Technology》2017,35(7):674-680
This study focuses on the effects of the tetrahydrofuran-soluble fraction of direct coal liquefaction residue as a modifier to modify asphalt with formaldehyde. The properties and carbonization behavior of matrix asphalt and the modified asphalts were studied. The results indicate that the ductility properties of modified asphalts have been effectively improved. The morphology of modified asphalts without the addition of formaldehyde is a set of uniform distribution point, and it is converted from linear distribution to clustered distribution observed in fluorescence microscope images with the increase of the adding amount of formaldehyde. 相似文献
9.
运用热重-傅立叶红外光谱联用技术(TG-FTIR),以麦秸为对象,探讨催化与非催化条件下生物质的加压热解特性,分析研究热解压力、温度、催化剂种类对生物质热解主要析出产物的影响。通过热重TG和DTG曲线,获得相关热解特性参数及动力学参数,结果表明添加NiO和CaO的加压催化热解均促进麦秸热解反应进行,降低表观活化能,其中NiO对提高热解析出产率作用更显著。通过红外光谱对热解产物的分析表明,提高热解压力以及加入适当的催化剂NiO和CaO均有利于增加CO和CH_4的生成。而且热解压力增加提高了NiO和CaO的催化作用,其中添加NiO时,在800℃以上具有更好的催化作用,且提高压力更有利于促进CH_4的生成;而添加CaO时,提高热解压力有利于减少CO_2的生成。 相似文献
10.