碳基采暖电热材料研究进展

近几年,由于节能与环保的需求,电取暖的方式得到大力的推广,电热材料的研究与应用受到人们广泛的重视。非金属碳基电热材料是新型的节能型电热采暖材料,本文重点对影响非金属碳基电热材料中的炭黑基电热材料、碳纤维基电热材料、碳晶电热材料电热性能的因素及相关应用进行了综述。     

CDMA通信系统的MATLAB仿真

在简要介绍MATLAB语言的基础上，对使用MATLAB语方仿真的CDMA通信系统进行描述。     

Flashover voltage characteristics of contaminated station insulators under temporary ac overvoltages in the ac system connected with a frequency converter station

According to the recent analysis results of temporary ac overvoltage in the ac system connected with a frequency converter station, large-magnitude over-voltages were confirmed to occur under some special system conditions. Most of the station insulators currently used cannot withstand such overvoltages according to an evaluation based on the data obtained earlier. The necessity of tests to be done to evaluate such performance more accurately was recognized. Both power frequency and switching impulse overvoltage flashover tests were made on contaminated insulators by the method well simulating the natural wetting condition. Switching impulse flashover voltage with the waveshape having a long wavefront time of 2 ms can be well correlated with the flashover voltage characteristics of temporary ac overvoltage. Higher flashover voltage characteristics were obtained by a clean fog test method compared with those obtained by equivalent fog test method.     

光纤接入网步入快速发展期

光纤接入一直是多年来人们不断追求的梦想和探索的技术方向，但由于成本、技术、需求等方面的障碍，至今还没有得到大规模推广与发展。然而，这种局面最近有了很大的改观，出现可迅速发展的势头。主要是因为一些国家政策的扶持、运营商竞争的需要、对收入的追求，以及设备本身价格的下降，光纤接入技术由于各种原因，至今尚未在全球广泛应用，但在日本、美国、瑞典和意大利等国都获得了较多的应用。在中国，光纤接入也有了良好的开端，将在大城市广泛应用，并逐渐推广到全国。     

焊铝合金用IGBT交流矩形波弧焊逆变器

本文介绍了新型开关元件ＩＧＢＴ管作为逆变开关元件的交流矩形波逆变器的原理。并通过实验证明，该电源具有良好的引弧和稳弧性能，在铝合金焊接方面具有较好的工艺性能。     

A new approach to the mechanism of chlorine evolution: Separate examination of the kinetic steps using ac impedance on a rotating thin ring electrode

In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl⁻ Cl_ad + e) is followed by a slower surface combination reaction (2Cl_ad → Cl₂), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved.     

基于三维特征向量的非侵入式电热负荷细分算法

非侵入式负荷监测分解（NILMD）技术是当前居民用能服务深化提升和电力供需互动的重要数据获取手段,然而当前工程上应用广泛的事件驱动型NILMD技术一直无法准确细化分解电热负荷。针对这一问题,文中提出了一种基于三维特征向量的典型电热负荷细化分解算法。首先,基于有功、无功功率和电流谐波等电气负荷特征采用事件检测方法提取电热事件,在有功功率的基础上,引入运行时长、频繁启停次数等非电气负荷特征共同构建三维特征向量电器模型。然后,采用序贯覆盖法设计典型电热负荷细化分解命题学习规则和细化分解算法。最后,基于实证实验数据进行分解验证,发现4种典型电热负荷的细化分解准确率超过85%。实验结果表明,文中所提典型电热负荷细化分解算法有效地提高了4种典型电热负荷分解的准确率。     

Low frequency ac conduction and dielectric relaxation behavior of solution grown and uniaxially stretched poly(vinylidene fluoride) films

The measurements of ac conductivity [σ_m(ω)], dielectric constant [?′(ω)] and loss [?″(ω)] have been performed on solution grown (thickness ∼85 μm) and uniaxially stretched (thickness ∼25, 45 and 80 μm) films of poly(vinylidene fluoride) (PVDF) in the frequency range 0.1 kHz-10 MHz and in the temperature range 77-400 K. The σ_m(ω) can be described by the relation σ(ω) = Aω^s, where s is close to unity and decreases with increase in temperature. Three relaxations, observed in the present investigation, have been designated as the α_c-, the α_a- and the β-relaxations appearing from high temperature side to the low temperature side. The α_c-relaxation could not be observed in the case of uniaxially stretched poly(vinylidene fluoride) films. The α_c- and α_a-relaxations are associated with the molecular motions in the crystalline regions and micro-Brownian motion in the amorphous regions of the main polymer chain, respectively, whereas the β-relaxation is attributed to the rotation of side group dipoles or to the local oscillations of the frozen main polymer chain.     

Dielectric properties of SBR vulcanizates loaded with HAF carbon black and BaTiO3 ceramics

The influence of HAF carbon black and BaTiO₃ ceramic powder contents in SBR vulcanizates on the dielectric constant (ε′) at different frequencies and at fixed temperature of 303 K is studied well in this article. The temperature dependence of the ac conductivity (σ_ac) was also studied. ε′ appreciably decreases as frequency increased for both filled and unfilled SBR vulcanizates. At each frequency, ε′ gradually decreased with BaTiO₃ loading, but its change at any fixed frequency with BaTiO₃ filler loading is not uniform. For HAF group ε′ (at loading ≥ 40 phr), drops rapidly with frequency. Meanwhile, it increased appreciably beyond a certain HAF filler loading (≈ 20 phr). Experimental values of the dielectric constant of both BaTiO₃ and HAF contents were compared with those calculated by using Tsangaris, Clausius and Bruggman models. Tsangaris model with simple modifications was applied and a fairly good agreement was obtained. The HAF particles or aggregates was found to take the shape of oblate ellipsoids with the minor axes parallel to the applied frequency as detected from the decreasing behavior of the depolarizing factor (Y) with HAF contents. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2227–2234, 2007     

丁腈胶乳的加氢反应

采用水合肼/过氧化氢氧化还原体系，以硼酸为催化剂，在常压下进行丁腈胶乳的氢化反应，研究了过氧化氢加入方式，硼酸和水合肼用量，反应温度及反应时间对丁腈胶乳加氢度的影响。结果表明，过氧化氢连续滴加再附加室温条件，氢化反应效果最好。当硼酸用量为2.64mmol，水合肼用量为95.2mmol，过氧化氮用量为79.3mmol。在60℃，6h下，丁腈胶乳的加氢度可达到90%以上。