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1.
Poly(l ‐lactic acid) (PLLA) is a biodegradable and biocompatible thermoplastic polyester produced from renewable sources, widely used for biomedical devices, in food packaging and in agriculture. It is a semicrystalline polymer, and as such its properties are strongly affected by the developed semicrystalline morphology. As a function of the crystallization temperature, PLLA can form different crystal modifications, namely α′‐crystals below about 120 °C and α‐crystals at higher temperatures. The α′ modification is therefore of special importance as it may be the preferred polymorph developing at processing‐relevant conditions. It is a metastable modification which typically transforms into the more stable α‐crystals on annealing at elevated temperature. The structure, kinetics of formation and thermodynamics of α′‐ and α‐crystals of PLLA are reviewed in this contribution, together with the effect of α′‐/α‐crystal polymorphism on the properties of PLLA. © 2018 Society of Chemical Industry 相似文献
2.
The smoke suppression of rigid polyurethane foam (RPUF) modified by melamine was investigated based on three sections: the condensed phase, the carbon layer, and the gas phase. In the condensed phase, the results of thermogravimetry, X‐ray photoelectron spectroscopy (XPS) N1S spectrum, and Fourier transform infrared spectroscopy indicated that melamine could suppress the degradation of RPUF by reacting with the aromatic hydrocarbons. It also reduced the smoke generation because the volatilizable aromatic hydrocarbons were the principal smoke precursors in a fire. In the carbon layer, the decrease from 38.50% to 24.76% of the inner layer oxygen content identified by XPS full‐spectrum and C1S spectrum indicated that melamine could prevent oxygen from transferring into the inner foam by the formation of an enhanced surface carbon layer, and the enhanced carbon layer could also block the release of smoke precursors. In the gas phase, the content of total aromatic hydrocarbons declined to 59.12% according to pyrolysis gaseous chromatography mass spectroscopy and indicated that melamine could reduce the smoke precursors. The results of smoke density chamber and cone calorimeter tests revealed that the addition of the melamine could decrease the smoke density of burning RPUF. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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谐波齿轮机构在商业表格印刷机中的应用 总被引:1,自引:1,他引:0
从商业表格印刷机特殊要求出发,以某一具体机型的传动系统为例,提出采用谐波齿轮机构解决纵向套准的问题。并且分析研究了谐波齿轮机构的工作原理及其在商业表格印刷机中的使用。 相似文献
5.
介绍了路面管理系统数据采集技术、数据库管理技术、路面使用性能评价及预测模型、养护决策模型在山西省的推广应用情况,并指出了取得的社会经济效益,阐明了其科学性、适用性和可操作性,证明其推广应用的价值。 相似文献
6.
G. M. Kulikov S. V. Plotnikova 《International journal for numerical methods in engineering》2002,55(10):1167-1183
The precise representation of rigid body motions in the displacement patterns of curved Timoshenko–Mindlin (TM) shell elements is considered. This consideration requires the development of the strain–displacement relationships of the TM shell theory with regard to their consistency with the rigid body motions. For this purpose a refined TM theory of multilayered anisotropic shells is elaborated. The effects of transverse shear deformation and bending‐extension coupling are included. The fundamental unknowns consist of five displacements and eight strains of the face surfaces of the shell, and eight stress resultants. On the basis of this theory the simple and efficient mixed models are developed. The elemental arrays are derived using the Hu–Washizu mixed variational principle. Numerical results are presented to demonstrate the high accuracy and effectiveness of the developed 4‐node shell elements and to compare their performance with other finite elements reported in the literature. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
7.
浅谈门式刚架轻型钢结构厂房中抗风柱的设置 总被引:1,自引:0,他引:1
通过对抗风柱上下端的节点几种形式进行分析比较,提出建议性的节点连续方式。 相似文献
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This study was to compare theoretical calculation and practical measurement structure response of asphalt pavement. Analysis of the pavement layer moduli was determined from a Back-calculation of Falling Weight Deflectometer (FWD) data and the measured stiffness moduli of asphalt layer cores. The pavement response was calculated using a theoretical model and the measured strain response at the bottom different layers. Layered elastic theory was used to back-calculate the layer moduli and three different theory models were used to forward calculate the strain and deflection. The models were: Layered Elastic Theory (LET), the Method of Equivalent Thicknesses (MET) with linear elastic and the Finite Element Method (FEM) where asphalt layer may be viscoelastic. The results showed that the calculation structure response from FEM was consistent with measured results. 相似文献
10.
底部框剪砌体房屋空间弹塑性地震反应分析 总被引:10,自引:3,他引:7
本文提出了底部框剪砌体房屋这类上下混合承重结构体系的空间弹塑性地震反应时程分析方法。针对砌体结构和框架抗震墙结构截然不同的抗震性能,对上部砌体结构采用空间剪扭分析法,而对下部框架抗震墙结构采用空间协同分析法,建立了组合型串联刚片系振动模型。对单向和双向地震波输入结构层位移反应进行了比较。 相似文献