井下乳化/水热催化裂解复合降黏开采稠油技术研究

实验考察了胜利孤东稠油井下催化水热裂解和乳化/催化水热裂解降黏效果。所用催化剂为水溶性铁镍钒体系,Fe3+∶Ni2+∶VO4+=5∶1∶1,100 g稠油与30 g 0.5%催化剂水溶液在240℃反应24小时。原始黏度(50℃)11.0和8.36 Pa.s的两种稠油裂解并静置除水后,黏度降低76.2%和75.6%,室温放置60天后降黏率下降小于3个百分点,气相色谱显示裂解后轻组分明显增加,红外光谱显示稠油组分发生脱羧反应且芳环数减少。讨论了稠油催化水热裂解反应机理。所用化学助剂JN-A在油水中均可溶,耐温达250℃,耐矿化度达50 g/L,其水溶液以30∶100的质量比与稠油混合时形成低黏度的O/W乳状液。当水相含1.0%JN-A和0.5%催化剂时,两种稠油水热裂解后的反应混合物为O/W乳状液,黏度仅为319和309 mPa.s,静置除水后的稠油降黏率增加到86.5%和87.3%,其中的轻组分含量进一步增加。该井下乳化/催化水热裂解复合降黏法成功地用于孤东两口蒸汽吞吐井,稠油井作业后初期采出的原油黏度由~9 Pa.s降低到1 Pa.s左右,随采油时间延长而逐渐升高,约50天后超过4Pa.s。图2表6参5。     

蒸汽减压站自控系统的巧设计

蒸汽是石油化工装置中最重要的物料。随着石油化工工业的迅猛发展 ,蒸汽在其中扮演着越来越重要的多重角色。因此 ,对蒸汽系统的平稳控制 ,对石油化工生产装置平稳、高效地运行是至关重要的。传统的蒸汽减压站自控系统基建投资大 ,紧急情况下靠人工手动操作稳定蒸汽压力系统 ,往往造成生产的波动或大面积的停车。针对传统蒸汽减压站自控系统的弱点 ,提出蒸汽减压站自控系统的优化设计方案 ,该方案得以在大型生产装置成功应用。新方案不但节省了大量的基建投资 ,而且取得了良好的生产效益     

Drying Kinetics of a Porous Spherical Particle and the Inversion Temperature

A model is presented for drying of a single porous particle with superheated steam and humid air. Experimental data for spherical porous ceramic particle reported in the literature were used for the validation of the model. An inversion temperature at which the evaporation rates within superheated steam and humid air are equal was predicted. The effect of thermophysical properties of the particle (permeability 10^-14 - 10^-17 m², diameter 3 × 10^-3 - 10 × 10^-3 m) and operating variables (gas mass flux 0.26 - 0.78 kg m^-2 s^-1, drying agent temperature 120-200°C) is tested. The inversion temperature is shown to be affected by the thermophysical properties of the porous particle and of the drying agent.     

宾馆酒店蒸汽冷凝水回收问题剖析

分析了宾馆酒店进行冷凝水回收所遇到的各种问题，提出了应对策略和解决方法，介绍了取得的应用效果。     

Life Calculations for Header – PGV-1000 Steam Generator Connector Weld Joints under NPP Service Conditions

The procedure for calculating the life of header – steam generator connector weld joints is proposed. It allows for running out the material plasticity reserve upon static cyclic elastoplastic loading as well as operating conditions, local stress concentrations, and residual stresses after welding.     

Connecting the second exhaust-heat boiler to the operating first one under the conditions of flow circuits of combined-cycle plants with two gas-turbine units and one steam turbine

Problems arising with connecting the second exhaust-heat boiler to the first exhaust-heat boiler under load in the case of flow circuits of combined-cycle plants of type PGU-450 are considered. Similar problems exist for two-boiler single-turbine units of type PGU-325 and for two-boiler single-turbine units of traditional steampower plants with an output of 200–300 MW upon connection of the second furnace of a two-furnace boiler to the operating first furnace. Analysis of the temperature-induced stressed state and of the cyclic strength of thick-walled elements of the steam-water conduit of PGU-450 and of two-furnace boilers of two-boiler single-turbine units with an output of 200–300 MW (the check valve, the inlet header of the water economizer) is used for determining the steam temperature differences in the high-pressure conduits to the steam turbine and the order of connection of the second exhaust-heat boiler to the operating fist one. Modes of enabling a two-boiler single-turbine unit of a combined-cycle plant, which are most “rigid” from the standpoint of thermal strength, are determined. __________ Translated from élektricheskie Stantsii, No. 2, February 2006, pp. 11–17.     

Geochemical characteristics of the Yufuin outflow plume, Beppu hydrothermal system, Japan

Thermal water at Yufuin (Kyushu Island, Japan) is tapped through about 820 shallow wells and used mainly for hot-spring bathing purposes. Chemical and isotopic data for fluids from wells and fumaroles in Yufuin and Beppu indicate that the thermal activity at Yufuin represents a dilute, westward-flowing hydrothermal outflow plume from the Beppu hydrothermal system. Two other (eastward-flowing) outflow plumes have long been recognized at Beppu, but the Yufuin outflow plume is first recognized here. The Yufuin outflow plume is apparently a mixture of two end-member fluids: (1) deep high-temperature (250–300°C) fluid from the Beppu system having high chloride concentration (1400–1600 mg/L) and a δ¹⁸O value near −6.0%, and (2) meteoric water having low chloride concentration (≤7 mg/L) and a δ¹⁸O value near −9.2%.A permeable conduit for the vertical and lateral transport of deep fluid from the Beppu system is provided by the Yufuin Fault zone, which extends westward from the southern flank of Mt. Tsurumi volcano to the town of Yufuin. Stable isotope ratios and chloride concentrations for shallow groundwaters near the eastern end of the fault, at an elevation near 700 m, are consistent with those required for the low-chloride meteoric end-member of the Yufuin thermal waters. Recharge of this meteoric water, as well as mixing with the Beppu deep fluid, may occur along the Yufuin Fault. Enthalpy-chloride relations indicate additional conductive heating of the Yufuin waters, in the amount of 350–500 kJ/kg beyond that which can be accounted for by mixing between Beppu deep fluid and meteoric water. This could be a result of conductive heating with convection to a depth of 1–2 km. Estimates of the magnitude of the heat source for the Beppu hydrothermal system should take into account the heat being discharged at Yufuin.     

Reactivity of steam in exhaust gas catalysis III. Steam and oxygen/steam conversions of propane on a Pd/Al2O3 catalyst

A 1% Pd catalyst (38% dispersion) was prepared by impregnating a γ-alumina with palladium acetylacetonate dissolved in acetone. The behaviour of this catalyst in oxidation and steam reforming (SR) of propane was investigated. Temperature-programmed reactions of C₃H₈ with O₂ or with O₂ + H₂O were carried out with different stoichiometric ratios S(S =[O₂]/5[C₃H₈]). The conversion profiles of C₃H₈ for the reaction carried out in substoichiometry of O₂ (S < 1) showed two discrete domains of conversion: oxidation at temperatures below 350°C and SR at temperatures above 350°C. The presence of steam in the inlet gases is not necessary for SR to occur: there is sufficient water produced in the oxidation to form H₂ and carbon oxides by this reaction. Contrary to what was observed with Pt, an apparent deactivation between 310 and 385°C could be observed with Pd in oxidation. This is due to a reduction of PdO_x into Pd⁰, which is much less active than the oxide in propane oxidation. Steam added to the reactants inhibits oxidation while it prevents the reduction of PdO_x into Pd⁰. Compared to Pt and to Rh, Pd has a higher thermal resistance: no deactivation occurred after treatment up to 700°C and limited deactivation after treatment up to 900°C, provided that the catalyst is maintained in an oxygen-rich atmosphere during the cooling.     

原料扩重的中压加氢改质装置投产

介绍燕山石化公司为扩大1Mt／a中压加氢改质装置的原料来源，改用大庆减二线油和重油催化裂化柴油组成的混合料开工投产的经验以及装置初期的运行条件。中压加氢改质技术可以生产优质柴油和蒸汽裂解制乙烯的原料，还可增产喷气燃料。     

蒸汽发生器二次侧清洁度的视频检查

立式平管板Ｕ形管束的压水堆核电站蒸汽发生器安装至瞬变工况期间，管板上表面的铁基金属残余物的堆积和外来物的存在，以及商业运行后管板、传热管、管子支撑板等的低流速区域里沉积物的堆积要求进行蒸汽发生器的清洁度检查。介绍了蒸汽发生器二次侧清洁度的视频检查技术。该技术适用于蒸汽发生器安装至瞬变工况和投入商业运行后可能发生污染的各阶段的清洁度检查。