全文获取类型
收费全文 | 21658篇 |
免费 | 2098篇 |
国内免费 | 728篇 |
专业分类
电工技术 | 479篇 |
综合类 | 1108篇 |
化学工业 | 5202篇 |
金属工艺 | 1355篇 |
机械仪表 | 554篇 |
建筑科学 | 920篇 |
矿业工程 | 422篇 |
能源动力 | 258篇 |
轻工业 | 10040篇 |
水利工程 | 192篇 |
石油天然气 | 991篇 |
武器工业 | 217篇 |
无线电 | 606篇 |
一般工业技术 | 1158篇 |
冶金工业 | 492篇 |
原子能技术 | 75篇 |
自动化技术 | 415篇 |
出版年
2024年 | 232篇 |
2023年 | 444篇 |
2022年 | 945篇 |
2021年 | 1015篇 |
2020年 | 1064篇 |
2019年 | 949篇 |
2018年 | 895篇 |
2017年 | 950篇 |
2016年 | 934篇 |
2015年 | 922篇 |
2014年 | 1087篇 |
2013年 | 1199篇 |
2012年 | 1556篇 |
2011年 | 1528篇 |
2010年 | 1070篇 |
2009年 | 1012篇 |
2008年 | 887篇 |
2007年 | 1114篇 |
2006年 | 1087篇 |
2005年 | 970篇 |
2004年 | 773篇 |
2003年 | 665篇 |
2002年 | 552篇 |
2001年 | 493篇 |
2000年 | 442篇 |
1999年 | 327篇 |
1998年 | 263篇 |
1997年 | 236篇 |
1996年 | 169篇 |
1995年 | 149篇 |
1994年 | 118篇 |
1993年 | 81篇 |
1992年 | 94篇 |
1991年 | 53篇 |
1990年 | 45篇 |
1989年 | 44篇 |
1988年 | 20篇 |
1987年 | 12篇 |
1986年 | 11篇 |
1985年 | 10篇 |
1984年 | 8篇 |
1983年 | 10篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1980年 | 10篇 |
1979年 | 7篇 |
1978年 | 3篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
《Food Control》2015
In this work a multicommuted flow system employing copper–4,4′- dipyridyl coordination compound as the solid-phase reagent for the spectrophotometric determination of reducing sugar was developed. The coordination compound was synthesized through a reaction of the 4,4′-dipyridyl and copper (II) nitrate, under hydrothermal conditions. The complex was characterized by infrared spectroscopy (FTIR), power X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometer (EDS) and thermogravimetric analysis (TGA). Based on the characterization, a multicommuted spectrophotometric procedure for the determination of reducing sugar using copper (II) complex as solid reagent is proposed. The proposed method was based on the redox reaction between a monosaccharide, such as fructose and glucose (reducing sugar) and Cu(II). This reaction, mediated in an alkaline medium, produces a yellow compound that can be determined by absorption electronic spectroscopy (λABS = 420 nm). Under optimum experimental conditions, a linear response ranging from 1.0 to 20.0 g L−1 (R = 0.9978 and n = 5), a detection (3σ criterion) and quantification (10σ criterion) limit estimated at 0.23 and 0.75 g L−1, respectively, a standard deviation relative of 4.7% (n = 7), for a reference solution of 10.0 g L−1 reducing sugar, and a sampling rate of 75 determinations per hour were achieved. The proposed system was applied to the determination of reducing sugars in coconut water and juices. The analysis of ten samples and the application of the t-test to the results found, and those obtained using reference procedures (AOAC), provided no significant differences at a 95% confidence level. This system enabled the analysis of reducing sugar with ease and simplicity, providing a significant economy of the solid reagent (600 μg per determination) and reducing effluent generation. 相似文献
2.
Purification,structural data and biological properties of polysaccharide from Prunus amygdalus gum 下载免费PDF全文
Fatma Bouaziz Mohamed Koubaa Claire Boisset Helbert Fatma Kallel Dorra Driss Imen Kacem Raoudha Ghorbel Semia Ellouz Chaabouni 《International Journal of Food Science & Technology》2015,50(3):578-584
This work demonstrates the efficiency of almond gum polysaccharides (AGPs) as bioactive compounds. AGPs were first extracted using H2O2, in the presence of NaOH, at different times and temperatures. The optimal extraction conditions were 4% H2O2 and 2 N NaOH, for 7 h at 50 °C, leading to an extraction yield of 58.2% (w/w). After a purification step, the retained AGPs were characterised using high‐performance liquid chromatography showing a molecular weight of 99.3 kDa. The monosaccharide composition of AGPs were assessed using gas chromatography–mass spectrometry. AGPs were found to be a complex heteropolysaccharide with a repeating unit mainly composed of galactose, arabinose, xylose, mannose, rhamnose, and glucuronic acid with the respective ratios: 45:26:7:10:1:11. The acidic nature of the polysaccharide is due to the presence of glucuronic acid. Total antioxidant activity, free radical‐scavenging activity and reducing power assay of AGPs were investigated. The obtained results showed high antioxidant activities of AGPs. Furthermore, beyond 60 mg mL?1, AGPs exhibited bacterial growth inhibition for five pathogenic strains: Escherichia coli, Staphylococcus aureus, Enterococcus feacalis, Pseudomonas aeruginosa and Salmonella typhimurium. 相似文献
3.
对CFG桩质量缺陷的探讨 总被引:2,自引:2,他引:0
根据具体工程的概况及水文地质条件,分析了CFG桩在地下水位出现大面积缩颈现象和复合地基载荷试验达不到设计要求的原因,并介绍了地基补强措施,以满足工程质量的要求。 相似文献
4.
5.
G Garrote J
M Cruz H Domínguez J
C Paraj 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(4):392-398
Non‐isothermal processing of lignocellulosic materials in aqueous media (autohydrolysis reaction) under mild conditions leads to solutions containing valuable chemicals (oligosaccharides, sugars and acetic acid) and other, undesired, compounds (belonging to the extractive and acid‐soluble lignin fractions) which have to be removed in further purification treatments. Liquors obtained by non‐isothermal autohydrolysis of Eucalyptus globulus wood and corncobs under a variety of operational conditions were extracted with ethyl acetate in order to remove non‐saccharide components, and the suitability of the fraction dissolved in the organic phase was assayed for possible utilisation as an antioxidant. The yield and antioxidant activity of ethyl acetate extracts (measured by the α,α‐diphenyl‐β‐picrylhydrazyl (DPPH) radical scavenging capacity) showed a strong dependence on the autohydrolysis conditions. The antioxidant activity of extracts obtained under selected operational conditions compared well with synthetic antioxidants. © 2003 Society of Chemical Industry 相似文献
6.
研究了用固体润滑石墨、碳化硅、二硫化钼等填料改性的聚苯硫醚 (PPS)涂层的耐磨性能。实验结果表明 ,聚苯硫醚复合涂层具有优良的耐磨性 ;加入适量 ( 3 0 % )的石墨、碳化硅等固体润滑剂 (石墨 :碳化硅 =2∶3 ) ,可以有效提高涂层的耐磨性能 ,而二硫化钼和三氧化二铬的减摩效果更佳 相似文献
7.
综述了近年来超分子主体化合物在分析化学领域的应用研究与进展。分别以冠醚、环糊精、杯芳烃、卟啉4类超分子为主体功能化合物的研究进行了详细的评述,并对这几类主体化合物在分析化学中的应用研究进行了展望。 相似文献
8.
9.
10.
以聚醚为基础油辅以抗磨剂、抗氧剂、防锈剂等多种添加剂研制而成的KGW聚醚合成工业齿轮油具有优异的黏温性能和低温性能,优异的极压抗磨性,极优的减摩性能,可满足高负荷、强冲击等苛刻条件下各类齿轮传动装置的润滑要求。该系列产品达到国外同类油品质量水平。 相似文献