T-ZnOw/TLCP抗静电复合材料的制备与性能研究

以热致液晶高分子(TLCP)为基体,四针状氧化锌晶须(T-ZnOw)为导电填料,用单螺杆挤出机制备抗静电性T-ZnOw/TLCP复合材料,分别探讨了偶联剂对T-ZnOw的影响;T-ZnOw用量对T-ZnOw/TLCP复合材料表面电阻率、热变形温度、力学性能的影响。结果表明,T-ZnOw经过偶联剂改性后,随着其用量的增加,复合材料表面电阻率显著下降,热变形温度、拉伸强度、冲击强度均呈现先增大后减小的趋势。     

T-ZnOw/树脂基复合材料逾渗行为的模拟与研究

从T-ZnOw空间结构出发,建立新型T-ZnOw/树脂基复合材料三维点阵模型,并利用Monte Carlo方法对系统逾渗导通行为进行了模拟,获得点阵逾渗阈值为23.2％。结合实际计算并获得了T-ZnOw的临界掺入比例,与文献报道的结果基本吻合。计算表明临界掺入比例主要取决于T-ZnOw长径比,且与晶须尺寸及复合材料的制备工艺有关。对T-ZnOw复合材料吸波机理进行了探讨,发现电导损耗和界面极化效应引发T-ZnOw针状晶体尖端放电现象可能是入射电磁波能量耗散的主要途径。     

Simulation and research of percolation phenomenon in T-ZnOw resin matrix composite

A novel three-dimensional lattice model of tetrapod-like zinc oxide whisker (T-ZnOw) resin matrix composite with a coordination number of 12 is constructed based on the special structure of T-ZnOw; the percolation phenomenon of the system is simulated by the Monte Carlo method,and the percolation threshold is obtained at 23.2%.The critical mixing ratio of T-ZnOw is calculated by considering the practical factors,and the result basically agrees with the reported one.Theoretical calculation shows that the critical mixing ratio mainly depends on the L/D ratio of T-ZnOw,and is also related to the size of T-ZnOw as well as the preparation method of the composite.The microwave absorbing mechanism of T-ZnOw composite is discussed,and conductivity loss and point discharge caused by the polarization effect are regarded to be two important means of energy dissipation.     

四针状氧化锌晶须制备方法及其在复合材料中的应用

四针状氧化锌晶须 (T -ZnOw)是晶须家族中目前发现的唯一具有规整三维空间结构的四针状晶须。由于其独特的空间四针状结构 ,以及特有的半导体、压电、吸波等特性 ,除了用作复合材料的增强体外 ,该晶须还可作为结构材料、功能材料等 ,在国防、电子、化工、交通等领域发挥巨大的作用。本文简述了四针状氧化锌晶须的结构、特性、制备方法 ,以及作为填充剂在复合材料方面的应用     

硫化亚铜/四针状氧化锌晶须异质结的多元醇法制备及光催化性能(英文)

以聚乙烯吡咯烷酮(PVP)为表面活性剂,通过多元醇法制备 Cu2S/T-ZnOw异质结复合材料,利用 XRD、FESEM、EDS、XPS 和 FTIR 测试方法对样品进行表征,通过测定甲基橙溶液的光降解率来评价样品的光催化活性。结果表明,在紫外光照射下,Cu2S/T-ZnOw纳米复合材料的光催化性能优于纯氧化锌晶须的。当 PVP 的浓度为 3.0 g/L 时,样品的光催化活性最高,在紫外光照射 120 min 后,甲基橙的降解率为 97%。经过 4 个周期的光催化实验后,Cu2S/T-ZnOw 催化剂的光催化活性并没有明显下降,说明该样品具有优异的光稳定性。此外,讨论了Cu2S/T-ZnOw 纳米复合材料的光催化机理。     

共沉淀法制备T-ZnOw/Fe_3O_4复合物的研究

以四针状氧化锌晶须(T-ZnOw)为基体,采用共沉淀法,制备了T-ZnOw/Fe3O4复合物.通过扫描电子显微镜(SEM)、X射线衍射仪(XRD)对复合物形貌和结构进行分析和表征,确定了制备T-ZnOw/Fe3O4复合物的最佳工艺条件.在该条件下制备的复合物由ZnO和Fe3O4晶体组成,且形貌完整,Fe3O4颗粒平均粒径在19.99nm左右.     

模压成型制备T-ZnOW/PS复合材料

采用具有分形结构特征的四针状氧化锌晶须(T-ZnOw)为填料,通过溶液共混与模压成型相结合的方法制备T-ZnOw/聚苯乙烯(PS)复合材料,对复合材料的力学性能、热性能等进行测试,并用扫描电镜分析复合材料冲击断口形貌.结果表明,T-ZnOw能有效改善复合材料的冲击强度、拉伸弹性模量、热变形温度等,即复合材料的刚性和韧性同时得到改善.断口形貌分析表明,T-ZnOw诱导基体产生银纹是复合材料韧性提高的主要原因.     

Preparation of Ag nanoparticles coated tetrapod-like ZnO whisker photocatalysts using photoreduction

Ag/tetrapod-like ZnO whisker (T-ZnOw) photocatalysts with different Ag loadings were synthesized by photoreduction of Ag⁺ on the surface of T-ZnOw. The chemical composition, morphology and photocatalytic properties of Ag/T-ZnOw photocatalysts were characterized and studied in detail. It is found that metal Ag can exist either as nanoparticles or as agglomerates through varying the Ag/ZnO molar ratio (MR). In photodegradation of methyl orange, enhanced degradation rates are achieved by all Ag/T-ZnOw photocatalysts due to increased separation efficiency of photogenerated electron and hole pairs. Specifically, the photocatalytic activities of Ag/T-ZnOw photocatalysts increase with increasing Ag/ZnO MR from 2.4 to 12%. However, further increasing the Ag/ZnO MR to 14.4% induces the formation of more agglomerates, which can act as recombination centers of photogenerated electron and hole pairs, leading to decreased photocatalytic activity of the photocatalyst.     

Study on properties of tetrapod-like zinc oxide whisker/silicone rubber foam composites

In this paper, the microcellular silicone rubber foams, strengthened with tetrapod-like Zinc Oxide whisker（T-ZnOw） are prepared. Through further characterization, it can be seen that the average cell diameter size of the filled with T-ZnOw is reduced. The distribution uniformity of microcellulars is improved obviously with increasing T-ZnOw filler. The reason that introduction of T-ZnOw can greatly enhance mechanical properties of the microcellular silicone rubber foams is its good interfacial adhesion with the matrix contributes. It is also found that the reducing effects of T-ZnOw on the compressive stress relaxation ratio of microcellular silicone rubber foams, and the improvement is obvious with increasing T-ZnOw filler.     

电磁改性T-ZnOw的制备及性能研究

采用化学沉积法制备了电磁改性T-ZnOw样品,用XRD,SEM和EDX对样品进行表征。结果表明:样品存在六方晶系纤锌矿结构ZnO和立方晶系Fe两相,四针结构保持完整,晶须表层沉积了球形颗粒,颗粒粒径约为0.5μm,铁元素和锌元素的质量分数分别为63%,37%;电磁改性T-ZnOw磁饱和强度达到85.66emu/g,电阻率降低到6.9Ω.cm。