全文获取类型
收费全文 | 226篇 |
免费 | 30篇 |
国内免费 | 21篇 |
专业分类
电工技术 | 3篇 |
综合类 | 11篇 |
化学工业 | 46篇 |
金属工艺 | 18篇 |
机械仪表 | 3篇 |
建筑科学 | 1篇 |
矿业工程 | 1篇 |
轻工业 | 1篇 |
武器工业 | 1篇 |
无线电 | 53篇 |
一般工业技术 | 127篇 |
冶金工业 | 9篇 |
原子能技术 | 1篇 |
自动化技术 | 2篇 |
出版年
2024年 | 1篇 |
2023年 | 12篇 |
2022年 | 5篇 |
2021年 | 9篇 |
2020年 | 12篇 |
2019年 | 12篇 |
2018年 | 7篇 |
2017年 | 19篇 |
2016年 | 13篇 |
2015年 | 8篇 |
2014年 | 21篇 |
2013年 | 14篇 |
2012年 | 11篇 |
2011年 | 14篇 |
2010年 | 16篇 |
2009年 | 9篇 |
2008年 | 11篇 |
2007年 | 14篇 |
2006年 | 7篇 |
2005年 | 10篇 |
2004年 | 8篇 |
2003年 | 18篇 |
2002年 | 3篇 |
2001年 | 9篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1985年 | 1篇 |
排序方式: 共有277条查询结果,搜索用时 62 毫秒
1.
Electronic structure and ferromagnetism in III–V compound-based diluted magnetic semiconductors (DMS) are investigated based on first-principles calculations by using the Korringa-Kohn-Rostoker method combined with the coherent-potential-approximation. The stability of the ferromagnetic phase in GaN-, GaAs-, GaP-, GaSb-based DMS is investigated systematically. The calculations show that 3d-impurities from the first-half of the transition metal series favor the ferromagnetic state, while impurities from the latter-half of the series exhibit spin-glass behavior. This chemical trend in the magnetism is explained by the double exchange mechanism taking the local symmetry at the impurity gap states into account. Curie temperatures of GaAs- and GaN-based DMS are estimated by using the Heisenberg model in a mean field approximation with the parameters calculated from first-principles. It is suggested that room-temperature ferromagnetism can be realized in these systems. 相似文献
2.
K. P. Lee S. J. Pearton M. E. Overberg C. R. Abernathy R. G. Wilson S. N. G. Chu N. Theodoropolou A. F. Hebard J. M. Zavada 《Journal of Electronic Materials》2002,31(5):411-415
In p-GaN implanted with Mn (3×1016 cm−2 at 250 keV), the material after annealing shows ferromagnetic properties below 250 K. Cross-sectional transmission electron
microscopy (TEM) revealed the presence of platelet structures with hexagonal symmetry. These regions are most likely GaxMn1−xN, which produce the ferromagnetic contribution to the magnetization. In p-GaN implanted with Fe, the material after annealing
showed ferromagnetic properties at temperatures that were dependent on the Fe dose, but were below 200 K in all cases. In
these samples, TEM and diffraction analysis did not reveal any secondary phase formation. The results for the Fe implantation
are similar to those reported for Fe doping during epitaxial growth of GaN. 相似文献
3.
A series of Mn-doped TiO_2 nanowires (NWs) were prepared by hydrothermal method at the mole fraction of Mn changing from 0 to 12.0%. X-ray powder diffraction (XRD) analysis shows that all the samples have pure anatase structure. SEM and TEM studies show that the diameter and the length of the Mn-doped TiO_2 NWs are larger than those of the undoped TiO_2 NWs. Energy dispersive X-ray spectroscopy (EDX) reveals that the samples are composed of Ti, Mn and O. According to magnetization measurements, all samples show ferromagnetic behavior, but only the undopedTiO_2 NWs are completely ferromagnetic with a saturated magnetization about 1.0 mA·m~2/kg. Mn-doped TiO_2 samples exhibit antiferromagnetic and ferromagnetic (AF-FM) behaviors simultaneously. Photoluminescence (PL) spectra demonstrate the existence of MnO_2 sublattice. These observations indicate that an AF-WF crossover is induced by the coexistence of TiO_2 sublattice and MnO_2 sublattice. 相似文献
4.
文章采用基于密度泛函理论的平面波超软赝势法,结合广义梯度近似计算了Cu掺杂AlN的晶格常数、能带结构、电子态密度、铁磁态和反铁磁态的总能量,并通过平均场近似的海森堡模型估算了居里温度Tc。结果表明,Cu掺杂体系的能带结构呈现半金属性,半金属能隙为0.442eV。铁磁性是Cu原子的3d态与其最近邻的N原子的2p态通过p-d杂化作用而稳定的。当两个Cu原子相距最远且自旋平行排列时,体系具有最低的能量,估算出此时的居里温度高于室温,因此Cu掺杂AlN有望作为稀磁半导体材料。 相似文献
5.
Qin Du Wenli Wang Zhiguang Wang Wei Su Zhiyuan Deng Jingen Wu Ming Ma Zhongqiang Hu Ziyao Zhou Ming Liu 《Journal of the American Ceramic Society》2021,104(2):896-902
Perovskite materials with compositions in the vicinity of the steep morphotropic phase boundary (MPB) exhibit various intriguing properties including giant piezoelectricity and large dielectric constant. Aside from composition, the phase configuration of the perovskites is also strongly related to the ambient temperature. Here, we report a giant piezoelectricity of 10 980 pm/V at 93°C in the 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (PMN-PT) single crystals which is more than five times larger than that at room temperature. The enhanced piezoelectricity can be attributed to the instability of the thermally induced tetragonal phase which can be converted to the orthorhombic phase by the external electric field in the <011> oriented single crystal. The transverse piezoelectricity has been investigated by measuring the electric-field-dependent ferromagnetic resonance (FMR) field in the CoFeB/PMN-PT magnetoelectric (ME) heterostructures. The ME coupling coefficient has been increased from 49.3 to 476 Oe cm/kV as temperature increased from 25 to 90°C. The findings reveal that both longitudinal and transverse piezoelectricity in the PMN-PT single crystals can be greatly enhanced by proper setting of ambient temperature, indicating an effective route for the design of strain-mediated tunable devices with ultralow driving voltage. 相似文献
6.
机械合金化Mn90Bi10纳米晶合金的结构和磁性 总被引:2,自引:0,他引:2
研究了Mn90Bi10混合粉末在机械合金化过程中结构和磁性的变化。X射线衍射,DSC分析和饱和磁化强度的测量结果表明:Mn90BI10混合粉末通过合金化可以形成纳米晶合金,而且经过短时间球磨即可迅速细化而达到纳米尺度。机械合金化可以明显提高铋在锰中的固溶度。反铁磁性的Mn元素和抗磁性的Bi元素通过机械合金化可以产生铁磁性。 相似文献
7.
8.
以锌粉、醋酸锌和氢氧化钠为原料,采用水热法制备出了具有结构性缺陷的蒲公英状ZnO。通过X射线衍射仪、扫描电子显微镜、荧光光谱仪和超导量子干涉仪对产物的结构形貌和光学性能及磁学性能进行了表征,并对其生长机理进行了探讨。研究表明,蒲公英状氧化锌为六方纤锌矿结构,由许多顶端为锥尖形的棒自组装而成;其荧光本征发射峰在388nm处,属于激子跃迁发射。在波长450~492nm处所观察到的3个弱蓝光峰是由锌填隙原子中的电子到价带顶的跃迁所致;在波长492~580nm范围内出现的较为宽泛的绿光发射峰根源于电子从导带底到氧错位缺陷能级间的跃迁。蒲公英状ZnO中存在的结构性缺陷使得原本呈现抗磁性的ZnO具有了室温铁磁性,从而可作为一种稀磁半导体应用到自旋电子学领域中。 相似文献
9.
Yi Wang Lei Sun Ling-Gang Kong Jin-Feng Kang Xing Zhang Ru-Qi Han 《Journal of Electroceramics》2006,16(4):389-391
Effects of Co
x
Ti
1−x
O
2−δ on the sinterability and the ferromagnetism properties of Co
2sO
3/TiO
2 (0.0 < x < 0.06) ceramics are investigated in this paper. It is found that the Co-doped Ti
O
2 ceramics transform from paramagnetism to room-temperature ferromagnetism (RTFM) after hydrogenation. With annealing temperatures
at 600∘
C and 1000∘
C, these as-prepared samples present anatase and rutile structures respectively, which are analyzed with X-ray diffraction
(XRD). After hydrogenation, the relation between temperature variations and the magnetic susceptibility for the hydrogenated
samples were measured under zero-field-cooled and field-cooled conditions by using SQUID magnetometer. And the hysteresis
loops are observed. These ferromagnetism resonance data suggest that the observed RTFM is at least partly due to the Cobalt
nano-particles in our hydrogenated samples. 相似文献
10.
S. Ashhab 《Journal of Low Temperature Physics》2005,140(1-2):51-65
We study the thermodynamic phases of a Bose gas of spin-1/2 atoms in the Hartree-Fock approximation. Our main result is that, for repulsive or weakly attractive inter-component interaction strength, the superfluid and ferromagnetic phase transitions occur at the same temperature. For strongly attractive inter-component interaction strength, however, the ferromagnetic phase transition occurs at a higher temperature than the superfluid phase transition. We also find that the presence of a condensate acts as an effective magnetic field that polarizes the normal cloud. We finally comment on the validity of the Hartree-Fock approximation in describing different phenomena in this system. 相似文献