共晶强制性熔化的界面形态

对透明共晶系ＣＢｒ４－８．４ｗｔ－％Ｃ２Ｃ１６生长的典型层片共晶组织强制熔化进行实时实地观测．表明相对于强制生长时的“界面滞后”现象，熔化界面温度高于静止时界面温度，熔化界面比静止界面更靠近热端，称为“界面超前”．随熔化速度增大，“界面超前量”增大；共晶组织分层熔化，出现两个熔化界面，α和β相熔化秩序不同，α，β相分别单独熔化，两熔化界面的相对位置由α，β相成分，熔化速度和共晶相间距等因素决定．     

Controllable synthesis of pure monodispersed zirconia nanopowders with tetragonal phase

Nanopowders of pure zirconia have been synthesized using citric acid (CA)-assisted lamellar liquid crystal template method. The microstructure of the zirconia powder prepared at the different mole ratios of CA to zirconium oxynitrate (ZN) was characterized by FT-IR, X-ray diffraction (XRD), laser particle size analyzer, Raman spectroscopy, and scanning electron microscope (SEM) methods. The phase structure of the sodium dodecyl sulfate (SDS)/C₁₀H₂₁OH/H₂O system before and after adding mixing solution CA and ZN was determined by POM (Polarizing Optical Microscope). The results show that lamellar structure of the SDS/C₁₀H₂₁OH/H₂O system after adding mixing solution CA and ZN is stable. The presence of CA inhibits agglomeration and growth of zirconia particle. The crystallite size of zirconia powders decreases and agglomerates lowly with addition of CA. Fourier transform infrared spectrometry (FI-IR) analyses reveal that the structure of chelating organic complex is maintained in zirconia structure at high-temperature calcination to cause oxygen vacancies which stabilizes the tetragonal phase of zirconia. The zirconia powders remained the single metastable tetragonal phase at the molar ratios of CA to ZN ranging from 1:3 to 5:1. The crystallite size of zirconia with spherical morphology varied from 32.2 to 20.1 nm with the increase of the molar ratio of CA to ZN in the range of 1:3 to 5:1.     

Flattening and solidification of thermally sprayed particles

In this article, molybdenum particles were plasma sprayed on copper, zirconia, and glass substrates. The impact of the molten particles was monitored using a fast two-color optical fiber pyrometer focused on a small spot on the substrate surface. The apparent duration of the flattening process and the cooling speed, both determined from the pyrometer signals, were found to depend on the substrate conditions and to vary with coating thickness. The substrate material and its roughness were also found to influence the texture in the sprayed coatings. Furthermore, a transient thermal flow numerical model was used to compute reliable thermal histories of the impinging particles and the underlying lamellae, the interfacial thermal resistance being determined by comparison of experimental thermograms with computed ones.     

预应变对16MnR钢断裂韧性的影响SCIEI

本文实验发现预应变对16MnR钢的断裂韧性具有显著的影响,断裂过程中裂尖区域材料的组织结构发生了变化,裂纹在二次珠光体组织上扩展。16MnR钢断裂韧性的大小取决于碳原子的扩散及二次珠光体组织生成的难易程度。     

Effects of melt‐extension and annealing on row‐nucleated lamellar crystalline structure of HDPE films

The row‐nucleated lamellar crystalline structure of high‐density polyethylene (HDPE) films was prepared by applying elongation stress to HDPE melt during T‐die cast film extrusion and subsequently annealing the extruded films. This unusual crystalline structure was analyzed in terms of lamellar crystalline orientation, long‐period lamellar spacing, crystallite size, and degree of crystallinity. The contribution of melt‐extension represented by draw‐down‐ratio (DDR) to the overall orientation was found to be most noticeable than other processing variables. Meanwhile, the long‐period lamellar spacing, the crystallite size, and the degree of crystallinity were influenced predominantly by the annealing temperature. Finally, the processing (melt extension and annealing temperature) – structure (lamellar crystalline structure) – property (hard elasticity) relationship of HDPE films was investigated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3326–3333, 2007     

兆瓦级风电球铁件低温冲击韧性的影响因素

为了获得具有良好低温冲击性能的兆瓦级风电球铁铸件,对实际生产中的附铸试件-20℃ V型缺口冲击性能进行了测试,并对其成分、基体组织、石墨球大小及分布情况进行分析,研究了兆瓦级风力发电机组球铁件低温冲击韧性影响因素.结果表明：在低P、S的前提下,通过合理的熔炼工艺控制,终Si量在2.3%时可以使单位面积的石墨球数量增加,石墨球细小,低温冲击值最佳;Mn在0.2%~0.3%之间变化时对低温冲击韧性影响并不明显;基体组织中珠光体在5%以下时,低温冲击值无明显变化,珠光体大于12.5%时,低温冲击值急剧下降.     

硅酸盐富锌（水性）防腐涂料的研究

通过分析比较，找出制备硅酸盐富锌涂料的理想配方。试验检测表明：该涂层具有良好的附着力，较强防腐性能等。是一种很有发展潜力的防腐蚀涂料。     

Effect of vanadium and chromium on the microstructural features of V–Cr–Mn–Ni spheroidal carbide cast irons

The objective of this investigation is to study the influence of vanadium（5.0wt%–10.0wt%） and chromium（0–9.0wt%） on the microstructure and hardness of Cr-V-Mn-Ni white cast irons with spheroidal vanadium carbides. The alloys＇ microstructural features are presented and discussed with regard to the distribution of phase elements. The structural constituents of the alloys are spheroidal VC, proeutectoid cementite, ledeburite eutectic, rosette-shaped carbide eutectic（based on M7C3）, pearlite, martensite, and austenite. Their combinations and area fraction（AF） ratios are reported to be influenced by the alloys＇ chemical composition. Spheroidized VC particles are found to be sites for the nucleation of carbide eutectics. Cr and V are shown to substitute each other in the VC and M7C3 carbides, respectively. Chromium alloying leads to the formation of a eutectic（γ-Fe ＋ М7С3）, preventing the appearance of proeutectoid cementite in the structure. Vanadium and chromium are revealed to increase the total carbide fraction and the amount of austenite in the matrix. Cr is observed to play a key role in controlling the metallic matrix microstructure.     

贝氏体相变特点的研究

研究贝氏体相变的特点，弄清贝氏体相变反应与共析分解的区别极为重要。本文应用QUANTA--400环扫电镜和JEM-2010高分辨电镜观察了多种钢的珠光体和贝氏体组织形貌和亚结构。综合以往的研究资料，从表象到本质上分析了贝氏体相变的特征，阐述了贝氏体相变与共析分解的区别。认为：贝氏体相变具有过渡性特征，贝氏体相变绝非共析分解。有的学者将贝氏体相变说成是共析分解的延续，那是不正确的。从贝氏体的物理本质出发，提出了钢中的珠光体、贝氏体、共析分解、钢中贝氏体相变等重要概念的新定义。     

Si对过共析锰钢力学性能及晶界组织的影响

本文用ＳＥＭ、ＴＥＭ研究了Ｓｉ对过共析锰钢经９５０℃奥氏体化和５６０℃等温处理后的组织及力学性能的影响。结果表明，Ｓｉ提高冲击韧性和延伸率，抑制先共析渗碳体在奥氏体晶界呈连续网状析出，并促进在过共析钢中晶界铁素体的形成，本文重点讨论了含Ｓｉ过共析钢中晶界铁素体的形成机理及其对韧性的影响。