Preparation of a Near-Infrared Ray Absorption Film from N-Phenylthiocarbamoyl Chitosan Derivative

We recently observed that the decanoylation of N-phenylthiocarbamoyl chitosan (2) with a mixture of decanoic anhydride and pyridine at 60 °C for 24 h afforded N,N-(decanoyl)phenythiocarbamoyl-/2-isothiocynato chitosan decanoate (3b) rather than the expected product N,N-(decanoyl)phenylthiocarbamoyl chitosan decanoate (3a). This result suggested that some of the N,N-(decanoyl)phenylthiocarmbamoyl groups had been converted to isothiocyanate groups during the decanoylation process. The subsequent reaction of compound 3b with aniline gave N,N-(decanoyl)phenylthiocarbamoyl/N-phenylthiocarbamoyl chitosan decanoate (4) in high yield. A solution of compound 4 in CHCl₃ was then added to a solution of copper decanoate (5) in the same solvent, and the resulting mixture was cast onto a glass plate to give a cast film. The film was annealed at 200 °C in an oven to give a greenish film, which showed good near-infrared absorption characteristic in the range of 800–2200 nm.     

Display reflectance: Basics,measurement, and rating

Abstract— In this paper, methods and instruments for measurement and evaluation of reflection characteristics are reviewed as needed for research and development of electronic displays and for material and surface modeling with ray‐tracing and rendering software packages. Contrast under ambient illumination and recognizability under daylight illumination are prime development targets in the electronic‐display field, while computation and synthesis of realistic scenes and objects are pushing the need for physical data in computer graphics applications. Three categories of instruments are available for detailed reflection analysis. They are based on (1) gonioscopic (mechanical) and conoscopic (optical) directional scanning, (2) imaging approaches, and (3) on arrangements with variable source or receiver aperture. The capabilities, advantages, and limitations of these methods are introduced and discussed in order to facilitate appropriate selection of methods and instruments. For illustration purposes we present typical results obtained from commercial electronic display screens. A basis for continued widespread implementation and standardization of reflection metrology as required for objective rating and comparison of electronic‐display screen performance under ambient illumination is provided.     

纸张背衬不同衬底时的光反射率的研究

从理论上研究了纸张背衬不同衬底的光反射率，得出下列表达式：Ｒｂ＝Ｒｏ＋（Ｒ∞－Ｒｏ）×（１／Ｒ∞－Ｒｏ）／（１／Ｂ－Ｒｏ）（Ｂ为衬底的光反射率），该式简单实用且物理意义明确。利用上述公式，可将Ｔａｐｐｉ标准列出的Ｔａｐｐｉ不透明度Ｃ０．８９的换算公式简化，并可从理论上定性地讨论纸张不透明度与印刷透印性的关系。     

Recovering spectral data from natural scenes with an RGB digital camera and colored filters

Many spectral‐recovery methods using RGB digital cameras assume the underlying smoothness of illuminant and reflectance spectra, and apply low‐dimensional linear models. The aim of the present work was to test whether a direct‐mapping method could be used instead of a linear‐models approach to recover spectral radiances and reflectances from natural scenes with an RGB digital camera and colored filters. In computer simulations, a conventional RGB digital camera with up to three colored filters was used to image scenes drawn from a hyperspectral image database. Three measures were used to evaluate recovery with the direct‐mapping method: goodness‐of‐fit, root‐mean‐square error, and a color‐difference metric. It was found that with two and three filters both spectral radiances and reflectances could be recovered sufficiently accurately for many practical applications. With little increase in computational complexity, an RGB camera and a few colored filters can provide significantly better recovery of natural scenes than an RGB camera alone. © 2007 Wiley Periodicals, Inc. Col Res Appl, 32, 352–360, 2007     

煤岩配煤在湘钢焦化厂的应用

论述了湘钢目前利用煤岩学数据指标判定进厂煤质情况,指导煤场分堆,优化配煤结构.同时在保证焦炭质量稳定的前提下,配入少量低灰的气煤,有效地提高了焦炭质量.     

量子阱红外探测器能带结构的计算

利用电子波在阱与垒的界面上的反射及干涉效应，计算了量子阱红外探测器(QWIP)的能带结构，并对其适用性进行了分析和讨论。通过与K-P模型比较发现，本方法对计算较宽势阱(阱宽大于4nm)的量子阱结构的电子态适合。在垒宽和阱宽不变条件下，用两种方法计算得到的AlGaAs／GaAs量子阱材料中Al组分x与吸收峰值波长λp的关系曲线基本相同。结果说明，在较宽的范围内，本方法对QWIP能带结构的计算是适用且简便的。     

镜质体反射率与砂岩孔隙度关系的研究与应用

利用有关孔隙度和有机质热成熟度的理论公式研究了二者之间的内在联系 ,建立起Ro与砂岩孔隙度之间的关系模型。用该模型对济阳坳陷沾化凹陷渤南洼陷沙河街组四段上亚段烃源层有机质的成熟度进行了估算 ,指出该烃源层有机质已达到成熟     

Use of pyrogenic silicas for petroleum oil polar fraction characterisation. Fourier transform infrared spectroscopy and microelectrophoresis studies

In the power transformer, the presence of polar or charged species in the insulating oil can cause failure and electric discharges. Solid substrates such as silica can be used to extract the polar species and to refine the oil in order to prevent future failure in the power transformer. However, the use of silica for petroleum oil separation and refining will depend on the silica characteristics such as surface charge, surface composition, specific surface area and particle size.Various pyrogenic silicas having various specific surface areas (49-200 m² g⁻¹) and particle sizes (207-500 nm) were used to extract the polar fractions from the neat transformer insulating oils (a new, NO, and used, UO2, oils). The oil covered silica samples were investigated by diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy in the range 4000-600 cm⁻¹. The bare silica surfaces present two main hydroxyl components, a sharper peak at 3745 cm⁻¹, I₃₇₄₅, due to isolated silanols and a second broad, which spreads over 3745-3000 cm⁻¹, I_3745-3000, due to H-bonded silanols. The relative intensities of the two components, I₃₇₄₅/I_3745-3000, varied for the bare and the oil covered silicas depending on the solid surface characteristics. The adsorption of the NO polar fraction onto silica leads to strong reduction in intensity of the sharper peak in favour of the broad one. However, the adsorption of the UO2 polar fraction onto silica leads in all cases to the decrease in the intensity of the both silica OH components. Further, the UO2 adsorption on the silica leads to the apparition of a broad peak at low frequency in the region 3250-3300 cm⁻¹ which, is due to the associated phenolic groups of UO2 oil polar fraction. The analysis of the DRIFT spectra for various samples indicates that the oil polar fraction resembles to asphaltenes compounds.The microelectrophoresis method used to investigate the surface charge at the water/oil polar fraction covered silica interface, indicates negatively charged particles. Further, the negative charge increased with the pH, as resulting from the increase of the ionisation and/or the amount of the oil polar carboxylic and phenolic groups. The oil polar fraction, i.e. the asphaltene components, in contact with both the silica surface and water at high pH values rearrange, due to their amphiphilic character.Finally, the use of the silica substrates seems to be suited to extract and analyse polar species present in petroleum oil. A correlation is found between the nature of the oil, its functionalities, and the magnitude of its zeta potential value at the water/oil covered silica interface.     

非接触式半导体少子寿命测试方法——微波反射法

介绍了一种非接触式用于测量少子寿命的微波反射法，并与通常的光电导衰退法进行了比较。     

Formation of GaAsP interface layers monitored by reflectance anisotropy spectroscopy

Reflectance anisotropy spectroscopy (RAS) has been used to study As-by-P exchange during metalorganic vapor phase epitaxy. The study focuses on the processes occurring during switching from GaAs to GaInP, especially the effect of purging PH₃ over a GaAs surface. GaAsP/GaAs superlattices of different periodicity were grown and the P-content was determined by high-resolution x-ray diffraction and correlated to the RAS spectra. From the temperature dependence of the P-content, an activation energy of 0.56 eV was estimated for the incorporation mechanism. In addition to the insights into the processes at mixed group-V heterointerfaces, our study demonstrates the reproducibility of RAS transients that thus can be used for process monitoring.