Excellent destabilization effect and ideal desorption temperature in the hydride Mg2FeH6 substituted with yttrium; a first principles study

We investigated some properties of the hydride Mg₂FeH₆ substituted with yttrium by a first principles calculation. Some experimental results showed that 4d transition metal, yttrium serves as a good catalyst for magnesium based hydrogen storage alloys, but there are a few theoretical studies about magnesium based hydrides substituted with it. Mg₂FeH₆ is regarded as a cheaper material than pure MgH₂, while it is crystalized into Fm3m structure (space group 225). Although it has high hydrogen storage capacity, many investigations have not been devoted to it due to its extremely high thermodynamic stability. The yttrium substituted Mg₂FeH₆ exhibits very low energy of formation, and its desorption temperature, 75 °C is very suitable for practical hydrogen storage applications. Our results showed that Mg₂FeH₆ is destabilized effectively by yttrium substitution and introducing vacancy defects has additive effect to the improvement of dehydrogenation performance.     

Modeling the effect of deep traps on the capacitance–voltage characteristics of p-type Si-doped GaAs Schottky diodes grown on high index GaAs substrates

Numerical simulation, using SILVACO-TCAD, is carried out to explain experimentally observed effects of different types of deep levels on the capacitance–voltage characteristics of p-type Si-doped GaAs Schottky diodes grown on high index GaAs substrates. Two diodes were grown on (311)A and (211)A oriented GaAs substrates using Molecular Beam Epitaxy (MBE). Although, deep levels were observed in both structures, the measured capacitance–voltage characteristics show a negative differential capacitance (NDC) for the (311)A diodes, while the (211)A devices display a usual behaviour. The NDC is related to the nature and spatial distribution of the deep levels, which are characterized by the Deep Level Transient Spectroscopy (DLTS) technique. In the (311)A structure only majority deep levels (hole traps) were observed while both majority and minority deep levels were present in the (211)A diodes. The simulation, which calculates the capacitance–voltage characteristics in the absence and presence of different types of deep levels, agrees well with the experimentally observed behaviour.     

High areal capacitance of FeOOH-carbon nanotube negative electrodes for asymmetric supercapacitors

The relatively low capacitance of negative electrodes, as compared to the capacitance of advanced positive electrodes, poses a serious problem, since this limits the development of asymmetric supercapacitor (SC) devices with a large voltage window and enhanced power-energy characteristics. We fabricate negative SC electrodes with a high capacitance that match the capacitance of advanced positive electrodes at similar active mass loadings, as high as 37?mg?cm^?2. Cyclic voltammetry, impedance spectroscopy, galvanostatic charge-discharge data and the power-energy characteristics of the asymmetric SC device exhibit good electrochemical performance for a voltage window of 1.6?V. Our approach involves the development and application of particle extraction through liquid-liquid interface (PELLI) methods, new extraction mechanisms and efficient extractors to synthesize α-FeOOH and β-FeOOH electrode materials. The use of PELLI allows agglomerate-free processing of powders, which facilitates their efficient mixing with multiwalled carbon nanotubes (MWCNT) and allows improved electrolyte access to the particle surface. Experiments to determine the properties of FeOOH-MWCNT composites provided insight into the influence of the electrode material and the structure of extractor molecules on the composite properties. The highest capacitance of 5.86?F?cm^?2 for negative electrodes and low impedance were achieved using α-FeOOH-MWCNT composites and a 16-phosphonohexadecanoic acid (PHDA) extractor. This extractor allows adsorption on particles, not only at the liquid-liquid interface, but also in the bulk aqueous phase and can potentially be used as a capping agent for particle synthesis and as an extractor in the PELLI method.     

阴离子表面活性剂测定方法的探讨

本文对“阴离子表面活性剂的测定方法”进行探讨,优化了显色剂、萃取剂的用量及萃取频率等分析条件,有效地降低了方法的检出浓度,提高了分析精度及准确度,节约大量试剂。本法最低检出浓度的0.019mL/L。     

Differentiating anxiety and depression in older adults with generalized anxiety disorder.

To examine affect and cognition in differentiating anxiety and depression, 83 older participants with generalized anxiety disorder completed the Cognitive Checklist (CCL) and the Positive and Negative Affect Schedule (PANAS). A 3-factor solution was found for the PANAS: positive affect (PA), anxiety and anger (Negative Affect 1 [NA-1]), and guilt and shame (Negative Affect 2 [NA-2]). A 2-factor structure was noted for the CCL. Correlations with anxiety and depression measures suggested that the CCL Depression (CCL-D) subscale showed stronger correlations with depression, whereas the CCL Anxiety subscale did not uniquely correlate with anxiety. The NA-1 subscale correlated positively with measures of depression and anxiety, whereas the PA subscale showed negative correlations. Hierarchical regression suggested that the CCL-D subscale was a significant predictor of self-reported depression. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

关于缩短大电流开关二极管反向恢复时间的研究

通过长期的工作实践，阐述了适当条件下的金扩散对缩短反向恢复时间，提高二极管2CK28开关速度，满足了反向恢复时间，改善了二极管的反向特性。     

Origin of the negative wake behind a bubble rising in non-Newtonian fluids

The present work aims at understanding the behavior of individual bubbles in non-Newtonian fluids. By means of a Particle Image Velocimetry (PIV) device, the complete flow field around either a single non-spherical bubble rising in polyacrylamide (PAAm) solutions or a solid sphere settling down in the same fluids shows for the first time the similar coexistence of three distinct zones: a central downward flow behind the bubble or the sphere (negative wake), a conical upward flow surrounding the negative wake zone, and an upward flow zone in front of the bubble or the sphere. This excludes then the possible influence of the interface deformation on the negative wake. A theoretical lattice Boltzmann scheme coupled to a sixth-order Maxwell model was developed for computing the complex flow field around a solid sphere. The good agreement with the experimental measurements provides evidence that the physical mechanism responsible for the negative wake in such fluids could be related to the fluid's viscoelastic properties.     

Very low surface recombination velocities on p-type silicon wafers passivated with a dielectric with fixed negative charge

Surface recombination velocities as low as 10 cm/s have been obtained by treated atomic layer deposition (ALD) of Al₂O₃ layers on p-type CZ silicon wafers. Low surface recombination is achieved by means of field induced surface passivation due to a high density of negative charges stored at the interface. In comparison to a diffused back surface field, an external field source allows for higher band bending, that is, a better performance. While this process yields state of the art results, it is not suited for large-scale production. Preliminary results on an industrially viable, alternative process based on a pseudo-binary system containing Al₂O₃ are presented, too. With this process, surface recombination velocities of 500–1000 cm/s have been attained on mc-Si wafers.     

Electrocopolymerization of aniline and ortho-phenylenediamine via facile negative shift of polyaniline redox peaks

Oxidative electropolymerization of aniline (Ani) in phosphoric acid (H₃PO₄) on composite 2B pencil graphite was accomplished using selected inorganic salts as supporting electrolytes. These salts determined the degree of conductivity of polyaniline (PAni) formed. The conductivity was in the order of CaCl₂ > KCl > ZnCl₂ > ZnSO₄ > Ca₃(PO₄)₂. The three pairs of redox peaks in the voltammogram of PAni formed in the presence of 0.06 M Ca₃(PO₄)₂ and 0.2 M ZnSO₄ have shifted 300 mV to the negative potential. The shifting of peaks is strongly influenced by type of anions' presence in the salts. However, the nature of the available cations had no significant effect. The negative shifts of redox peaks were exploited to facilitate the electrocopolymerization of Ani and ortho-phenylenediamine (oPD). The formation of the poly(Ani-co-oPD) was confirmed by the FTIR spectra.     

变频器在链条炉系统中的应用

本文介绍了链条炉的定义，链条炉应用变频调速的意义，链条炉控制系统的原理，锅炉采用变频调速控制的优点，变频调速的控制方法和逻辑，链条炉采用变频调速装置的节能分析。