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排序方式: 共有91条查询结果,搜索用时 93 毫秒
1.
Characterisation of two biomass fuels (pelletised Miscanthus Giganteus and wood) was performed using thermogravimetric analysis with measurement of products by means of Fourier transform infrared spectroscopy (TG-FTIR). Three heating rate profiles were applied (10, 30 and 100 °C/min), with a final temperature of 900 °C. HCN and HNCO were found to be the major N-products, while the NH3 fraction was detected to a minor extent. Kinetic parameters were obtained from the TG-FTIR results using a model based on parallel first-order reactions with a Gaussian distribution of activation energies. On the basis of the above kinetic analysis and product yields, input files for the functional group-devolatilisation, vaporisation, cross-linking biomass-pyrolysis model were prepared. The fit of model parameters to TG-FTIR product-evolution data was found to be generally good, but the model-predicted yields for some species did not fit experimental data at all heating rates. Further improvements in the model are needed to resolve above difficulty. 相似文献
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利用热重-红外联用(TG-FTIR)分析了Adaro煤与棕榈空果串(EFB)在富氧混烧工况下的特性.热重分析仪记录样品在加热过程中的质量损失,而FTIR则分析其释放的气体产物.对在18%O_2/82%CO_2,Air(21%O_2/79%N_2),21%O_2/79%CO_2,30%O_2/70%CO_24种工况下Adaro coal+30%EFB样品进行燃烧.热重分析表明,与O_2/N_2工况相比,O_2/CO_2条件下CO_2气体对燃烧有抑制作用,且空气工况下与30%O_2/70%CO_2的燃烧特性相当.FTIR分析释放的气体主要是CO_2,CO,H_2O. 相似文献
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Mannose was selected as a model compound of hemicellulose and its thermal behavior over zeolites has been investigated using a TG-FTIR analyzer. There was an initial study of the chemical structure of mannose and a characterization of the catalysts. All three catalysts, HZSM-5, H-β and USY, had a significant influence on the dehydration, cracking and deoxygenation reactions during the pyrolysis of mannose. The dehydration reaction in the initial stage was enhanced, resulting in two separate water release processes, while the char formation was suppressed. USY had the best effect on dehydration, and HZSM-5 obtained the highest deoxygenation efficiency. The presence of HZSM-5 and H-β catalyzed the formation of water and CO2, while suppressing the formation of oxygenated compounds and char residues. 相似文献
5.
Ming Sun Dan Zhang Minghui Huang Jing Chen Xing Tang Chao He 《Petroleum Science and Technology》2017,35(7):674-680
This study focuses on the effects of the tetrahydrofuran-soluble fraction of direct coal liquefaction residue as a modifier to modify asphalt with formaldehyde. The properties and carbonization behavior of matrix asphalt and the modified asphalts were studied. The results indicate that the ductility properties of modified asphalts have been effectively improved. The morphology of modified asphalts without the addition of formaldehyde is a set of uniform distribution point, and it is converted from linear distribution to clustered distribution observed in fluorescence microscope images with the increase of the adding amount of formaldehyde. 相似文献
6.
运用热重-傅立叶红外光谱联用技术(TG-FTIR),以麦秸为对象,探讨催化与非催化条件下生物质的加压热解特性,分析研究热解压力、温度、催化剂种类对生物质热解主要析出产物的影响。通过热重TG和DTG曲线,获得相关热解特性参数及动力学参数,结果表明添加NiO和CaO的加压催化热解均促进麦秸热解反应进行,降低表观活化能,其中NiO对提高热解析出产率作用更显著。通过红外光谱对热解产物的分析表明,提高热解压力以及加入适当的催化剂NiO和CaO均有利于增加CO和CH_4的生成。而且热解压力增加提高了NiO和CaO的催化作用,其中添加NiO时,在800℃以上具有更好的催化作用,且提高压力更有利于促进CH_4的生成;而添加CaO时,提高热解压力有利于减少CO_2的生成。 相似文献
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生物质催化热解的TG-FTIR研究 总被引:2,自引:0,他引:2
借助综合热分析仪和傅立叶红外联用技术(TG-FTIR),考察了HUSY、REY和HZSM-53种分子筛以及重油催化裂化催化剂MLC和馏分油催化裂解催化剂CIP对生物质催化热解的活性和选择性。研究结果表明,分子筛对生物质热解产物的脱氧活性顺序为:REY≈HUSY>HZSM-5,生成高辛烷值烃类的选择性顺序为:REY>HUSY≈HZSM-5;MLC催化剂和CIP催化剂都表现出较高的选择活性,前者的脱氧活性略高于后者;择形分子筛HZSM-5的引入对调整催化剂酸强度、提高催化转化选择性和抑制焦炭生成产生一定作用。 相似文献
9.
利用TG-FTIR对生物质、煤及其混合物的燃烧过程及燃烧产物进行分析,研究了生物质添加比例、升温速率、氧气浓度对燃烧过程的影响。结果表明,生物质的加入可以有效改善样品的燃烧性能,提高样品的燃尽性能。提高生物质添加比例,可以降低燃烧气态产物中CO与CO2的比例,提高燃料利用率。提高升温速率和氧气浓度,可以提高生物质与煤混合物的燃烧速度,缩短燃烧时间,改善生物质与煤混合物的燃烧性能,有利于燃烧反应的进行;同时,燃烧气态产物中CO所占比例逐渐减小,CO2所占比例逐渐增大,提高了燃料的燃尽率。 相似文献
10.
Michelina Catauro Elisabetta Tranquillo Alessandro Dell’Era Riccardo Tuffi Stefano Vecchio Ciprioti 《Ceramics International》2019,45(2):2771-2778
The thermal behavior of pure ZrO2 and four ZrO2-based organic-inorganic hybrids (OIHs) containing increasing amount (6, 12, 24 and 50?wt%) of poly(ε-caprolactone) (PCL) (named Z, ZP6, ZP12, ZP24 and ZP50 respectively) has been studied by simultaneous thermogravimetry (TG) and differential scanning calorimetry (DSC). The FTIR analysis of the gas mixture evolved at defined temperatures from the samples submitted to the TG experiments identified the mechanism of each thermally activated process. The obtained results suggest that the inorganic matrix of the OIHs prepared by this method exerts a stabilizing effect on the polymer, in particular for poor-PCL hybrid materials. In fact, the different thermal behavior of the ZP50 sample suggests that the polymer is not entirely bonded to the -OH groups of the zirconia matrix due to their saturation. For this reason a part of PCL is not affected by the stabilizing effect of the matrix and is subjected to thermal degradation. Finally, by observing their thermal behavior it was possible to select the most suitable temperatures for thermal pretreatment: 400, 600 and 1000?°C. The structural analysis by X-ray diffraction (XRD) revealed that at 400?°C the materials are amorphous, while at 600?°C they are mostly tetragonal, and the content of the tetragonal phase decreases with increasing the amount of PCL in the OIHs. All the materials treated at 1000?°C are monoclinic, but their crystallinity decreases with increasing the PCL content. 相似文献