Study of Compatibilized Liquid Crystalline Polymer/Cyclic Olefin Copolymer Blends

The technology to produce compatibilized blends of liquid crystalline polymer and highly amorphous cyclic olefin copolymers through two novel approaches were studied. The first approach was to use silane-functionalized halloysite nanotube as nonspecific compatibilizer and the second method was reactive compatibilization. The study of blends and their resulting microstructure; their thermal, mechanical, and viscoelastic properties were investigated. The kinetic study of blends compatibilized through both routes was performed.     

加工高酸油品加氢反应进料加热炉炉管的选材

论述了加氢装置反应进料加热炉炉管经常出现的晶间腐蚀的形成原因、控制方法以及近年来油品中出现的环烷酸对炉管的腐蚀影响,并结合工程实例,讨论了综合考虑强度和防止这两种腐蚀的炉管选材的问题。     

Eu2+激活的碱土金属铝酸盐磷光体的研究进展

主要概述了Eu^2 激活的碱土金属铝酸盐磷光体的光谱特性，总结了近年来在铝酸盐基质研究以及长余辉机理研究等方面所取得的进展，同时对今后的研究提出了展望。     

膨化硝酸铵晶体特性研究

膨化硝酸铵是一种改性硝酸铵晶体,具有显著自敏化特征,成功应用于各类膨化硝铵炸药及震源药柱中.在膨化剂(表面活性剂)的作用下改善了膨化硝酸铵的物理性能和晶体结构及其特征.本文通过硝酸铵固体表面接触角的测量,算出了膨化硝酸晶体表面能;利用差热分析(DSC)技术给出了膨化剂对硝酸铵晶变的影响;采用x射线衍射分析了膨化硝酸铵晶体的晶格特性.     

聚乙烯醇侧链液晶的结构与液晶性研究

研究了聚乙烯醇侧链液晶主链分子量和液晶基元等结构因素对其液晶性的影响，结果表明随着聚合物的分子量增加，导致复合物清亮点温度下降。但是在液晶主链尚未被液晶基元饱和之前，随着液晶基元相对主链摩尔比的增加，样品形成较为完善的氢键结构。     

Development of co-continuous structure in liquid crystalline polyester

We investigated liquid crystallization of liquid crystalline polyester BB-5 during isothermal annealing by digital high-fidelity microscope and light scattering. A liquid crystalline spherical domain having a radius of micrometers appeared by annealing at around 180 °C. The domain grew dendritically in all directions. Neighboring liquid crystalline regions coalesced and then interconnected. The interconnected structure changed to a co-continuous two-phase structure with increasing ordering of the liquid crystalline phase, and the interface between the liquid crystalline phase and the isotropic phase became smoother over time. Liquid crystallization stopped before volume filling the whole space, and the liquid crystalline phase and isotropic phase coexisted. The liquid crystalline region became narrower with an increase in the temperature of the liquid crystallization. Such structural development is different from the liquid-liquid phase separation via spinodal decomposition, and it may be attributed to the segregation of non-liquid crystallizable low molecular weight molecules from the growth front by fractionation of the molecular weight distribution during the liquid crystallization in terms of the instability of the diffusion-controlled interface.     

Phase transition of LCP fluids confined in nanochannels through MD simulation

Manipulation of molecular orientation alignment in MCTLCPs (main-chain thermotropic liquid crystalline polymers) by pure shear at nano scale has been investigated for the first time using molecular dynamics (MD) simulation. Results indicate that high planar shear induces long-range uniform orientation ordering (liquid crystalline phase) of initially randomly orientated molecules of MCTLCP fluid confined in a nanochannel, which is confirmed by analyzing the orientation order parameter and the snapshots of MCTLCP liquid in a nanochannel under different shear rates. Insights into the origin of the phase transition phenomena are given at molecular level through investigating the thermodynamic density distribution of MCTLCP molecules in the nanochannel, suggesting that the energy shift due to a radical jump of system density affects both the magnitude and the orientation of the molecular ordering. Simulation results also show that there is a critical shear rate for transforming isotropic phase into liquid crystalline phase. The critical shear rate is dependent on the temperature of the MCTLCP system. Findings in this paper may present useful information for processing TLCP molecules at nano scale and the understanding of nanoflow.     

Phase behavior in liquid crystallization for diblock copolymers consisting of rubbery amorphous and side-chain liquid crystalline components

Phase behavior in liquid crystallization was studied for a series of liquid crystalline (LC) diblock copolymers consisting of rubbery amorphous and side-chain liquid crystalline components, poly(n-butyl acrylate) (PBA) and poly[11-(4′-cyanophenyl-4″-phenoxy)undecyl acrylate] (PLC), respectively, using a time-resolved small-angle X-ray scattering (SAXS) techniques, DSC and polarized optical microscopy (POM). The block copolymers used had three kinds of copolymer compositions, 44, 20 and 15 wt% of PLC compositions (BLC44, BLC20 and BLC15, respectively). BLC44 showed a smectic liquid crystalline structure. In the process of liquid crystallization for BLC44, the SAXS peak due to the microphase separation structure existing before liquid crystallization was changed continuously to be at a smaller angular side, and at almost the same time, a new peak appeared at a further smaller angular side and developed. The former peak disappeared with the development of liquid crystallization. The behavior of these SAXS peaks suggests that the microphase separation structure was changed discretely at the transition from isotropic to smectic and that two phases coexist in the early stage of the liquid crystallization. The coexistence of two peaks in the early stage of the liquid crystallization corresponded to the POM observation. In the isotropization process, coexistence of two phases was not observed. For BLC20 exhibiting a cylindrical structure in both isotropic and liquid crystalline states, the liquid crystalline structure was not smectic but probably nematic, and the spacing was changed continuously in liquid crystallization. No liquid crystallization was observed in SAXS, POM and DSC for BLC15. The orientation of smectic layers within lamellar domains was investigated using 2D-SAXS images. The smectic layer was aligned perpendicularly to the lamellar interface.     

Fe73.5Cu1Nb3Si13.5B9非晶合金的晶化动力学

用ＤＴＡ结合ＸＲＤ了Ｆｅ７３．５Ｃｕ１Ｎｂ３Ｓｉ１３．５Ｂ９晶合金的晶化动力学。表明，该事金在５００℃时析出α－Ｆｅ（Ｓｉ）相。晶化初期激活能最小为２４２ｋＪ／ｍｏｌ，它随晶化量的增加，在ＸＣ为０．４－０．８时，呈极大值为５２０ｋＪ／ｍｏｌ。在６２４℃时析出Ｆｅ２Ｂ相。     

美国高能激光技术2005年主要进展

高能激光武器技术在2005年取得了重大进展。介绍了机载兆瓦级化学氧碘激光器的关键试验和束控-火控系统的飞行试验。评论和讨论了高功率固体激光器、光纤激光器、超高效率二极管源和中继镜技术的重大进展。