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1.
《International Journal of Hydrogen Energy》2022,47(6):3550-3555
Electrocatalytic nitrogen reduction reaction (ENRR) offers a carbon-neutral process to fix nitrogen into ammonia, but its feasibility depends on the development of highly efficient electrocatalysts. Herein, we report that Fe ion grafted on MoO3 nanorods synthesized by an impregnation technique can efficiently enhance the electron harvesting ability and the selectivity of H+ during the NRR process in neutral electrolyte. In 0.1 M Na2SO4 solution, the electrocatalyst exhibited a remarkable NRR activity with an NH3 yield of 9.66 μg h?1 mg?1cat and a Faradaic efficiency (FE) of 13.1%, far outperforming the ungrafted MnO3. Density functional theory calculations revealed that the Fe sites are major activation centers along the alternating pathway. 相似文献
2.
Ida-Marie Andersson Björn Bergenståhl Marcela Alexander Marie Paulsson Maria Glantz 《International Journal of Food Science & Technology》2021,56(1):480-492
During whey powder production, the feed is subjected to several heat treatments which can cause lactosylation of proteins. In this study, lactosylation of whey proteins was evaluated in spray-dried powders before and after storage by varying the native protein fraction as well as the serum protein/lactose ratio in the powders. The lactosylation of native α-lactalbumin and β-lactoglobulin in the powders before storage was not affected to a large extent by the protein denaturation or if the feed had been heat treated in a high or low lactose environment. After storage (relative humidity of 23.5%, 30 °C, 25 days), the kinetic of lactosylation tended to increase with increasing native protein fraction and bulk protein content in the powders. An explanation could be that proteins dissolved in the lactose glassy structure might have a lower reactivity, while proteins present in the protein glassy structure with dissolved lactose may display higher lactosylation reactivity. 相似文献
3.
Chitosan (CHT) is a non-toxic and inexpensive compound obtained by deacetylation of chitin, the main component of the exoskeleton of arthropods as well as of the cell walls of many fungi. In agriculture CHT is used to control numerous diseases on various horticultural commodities but, although different mechanisms have been proposed, the exact mode of action of CHT is still unknown. In sycamore (Acer pseudoplatanus L.) cultured cells, CHT induces a set of defense/stress responses that includes production of H2O2 and nitric oxide (NO). We investigated the possible signaling role of these reactive molecules in some CHT-induced responses by means of inhibitors of production and/or scavengers. The results show that both reactive nitrogen and oxygen species are not only a mere symptom of stress conditions but are involved in the responses induced by CHT in sycamore cells. In particular, NO appears to be involved in a cell death form induced by CHT that shows apoptotic features like DNA fragmentation, increase in caspase-3-like activity and release of cytochrome c from the mitochondrion. On the contrary, reactive oxygen species (ROS) appear involved in a cell death form induced by CHT that does not show these apoptotic features but presents increase in lipid peroxidation. 相似文献
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5.
介绍了尿素装置中3起液位仪表失真案例,分析了故障现象和设备工况,确定失真原因,采取了相应的处理措施,解决了仪表故障。 相似文献
6.
Joshua C. Price Simon J. Levett Valentin Radu David A. Simpson Aina Mogas Barcons Christopher F. Adams Melissa L. Mather 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(22)
Fluorescent nanodiamonds (fNDs) containing nitrogen vacancy (NV) centers are promising candidates for quantum sensing in biological environments. This work describes the fabrication and implementation of electrospun poly lactic‐co‐glycolic acid (PLGA) nanofibers embedded with fNDs for optical quantum sensing in an environment, which recapitulates the nanoscale architecture and topography of the cell niche. A protocol that produces uniformly dispersed fNDs within electrospun nanofibers is demonstrated and the resulting fibers are characterized using fluorescent microscopy and scanning electron microscopy (SEM). Optically detected magnetic resonance (ODMR) and longitudinal spin relaxometry results for fNDs and embedded fNDs are compared. A new approach for fast detection of time varying magnetic fields external to the fND embedded nanofibers is demonstrated. ODMR spectra are successfully acquired from a culture of live differentiated neural stem cells functioning as a connected neural network grown on fND embedded nanofibers. This work advances the current state of the art in quantum sensing by providing a versatile sensing platform that can be tailored to produce physiological‐like cell niches to replicate biologically relevant growth environments and fast measurement protocols for the detection of co‐ordinated endogenous signals from clinically relevant populations of electrically active neuronal circuits. 相似文献
7.
Siqi Yu Qin Wang Jianwei Wang Yong Xiang Xiaobin Niu Tingshuai Li 《International Journal of Hydrogen Energy》2021,46(27):14331-14337
Artificial nitrogen fixation is emerging as a promising approach for synthesis of ammonia at mild conditions. Inspired by biological nitrogen fixation based on bacteria containing iron, zinc doped Fe2O3 nanoparticles are proposed as an efficient and earth abundant electrocatalyst for converting N2 to NH3. In neutral media, it achieves a maximum Faradaic efficiency (FE) of 10.4% and a large NH3 yield rate of 15.1 μg h?1 mg?1cat. at ?0.5 V vs. reversible hydrogen electrode. This catalyst also exhibits excellent selectivity and stability. Theoretical calculations suggest the reaction follows the associative enzymatic mechanism and it has a barrier of as low as 0.68 eV. 相似文献
8.
含氮化合物对NiW体系催化剂芳烃加氢性能的影响 总被引:2,自引:0,他引:2
以γ-Al2O3、B改性的γ-Al2O3、F改性的γ-Al2O3、SiO2-Al2O3为载体制备Ni、W含量相同的四种催化剂,通过程序升温还原表征考察活性金属与不同载体的相互作用。利用氮含量不同、四氢萘含量相同的四种原料考察含氮化合物对同种NiW体系催化剂四氢萘加氢的影响以及对活性金属与载体相互作用不同的催化剂四氢萘加氢的影响。结果表明,以γ-Al2O3或SiO2-Al2O3载体制备的催化剂的金属组分与载体相互作用较强,B或F改性的γ-Al2O3能显著削弱活性金属与载体的相互作用;含氮化合物对四氢萘加氢具有强烈的抑制作用,使四氢萘加氢反应的表观活化能增加;在实验研究的四种催化剂中,金属组分与载体相互作用较弱的催化剂受含氮化合物的抑制较强。 相似文献
9.
10.
无机阻燃剂高聚合度聚磷酸铵的研制 总被引:9,自引:3,他引:6
以五氧化二磷、磷酸铵盐、尿素为原料、氨气为保护气,制备了高聚合度聚磷酸铵无机阻燃剂。考察了五氧化二磷、磷酸铵盐、尿素的用量和反应温度对聚磷酸铵平均聚合度的影响。采用端基滴定法测定了聚磷酸铵的聚合度,并用X射线衍射(XRD)法表征了聚磷酸铵的晶体结构,同时测定了聚磷酸铵的粒度和溶解度。实验结果表明,制备聚磷酸铵的最佳反应条件为:n(磷酸氢二铵)∶n(五氧化二磷)∶n(尿素)=1∶1∶0.3,反应温度280~300℃,反应时间40m in,热处理温度250~280℃,热处理时间110m in。在此条件下制备的聚磷酸铵的平均聚合度大于600,平均粒径直径小于50μm,在水中的溶解度小于0.4g;XRD表征结果表明,所合成的物质为Ⅱ型聚磷酸铵。 相似文献