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排序方式: 共有383条查询结果,搜索用时 31 毫秒
1.
Covalent triazine frameworks (CTFs) have been recently employed for visible light-driven photocatalysis due to their unique optical and electronic properties. However, the usually highly hydrophobic nature of CTFs, which originates from their overall aromatic backbone, leads to limitations of CTFs for applications in aqueous media. In this study, we aim to extend the range of the application media of CTFs and design hybrid material of a CTF and mesoporous silica (SBA-15) for efficient photocatalysis in aqueous medium. A thiophene-containing CTF was directly synthesized in mesopores of SBA-15. Due to the high surface area and the added hydrophilic properties by silica, the hybrid material demonstrated excellent adsorption of organic molecules in water. This leads not only to high photocatalytic performance of the hybrid material for the degradation of organic dyes in water, but also for efficient photocatalysis in solvent-free and solid state. Furthermore, the reusability, stability and easy recovery of the hybrid material offers promising metal-free heterogeneous photocatalyst for broader applications in different reaction media. 相似文献
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三嗪类化合物的合成及其产酸性能研究 总被引:8,自引:1,他引:7
合成了一系列的三嗪类光生酸剂1a-1e,确定了它们的结构,并对1e在乙腈溶剂中365和405nm光下的曝光分解产酸性能进行了初步的定量研究.结果表明,在测定浓度范围内分解量子产率和产酸量子产率基本上都不随浓度的变化而变化,在405nm光下比在365nm光下有更高的分解和产酸量子效率.有关这类化合物的光生酸性能与曝光波长的关系正在进一步研究中. 相似文献
4.
利用田间试验方法研究保护剂长残效除草剂解毒效应。不同保护剂对豆磺隆解毒效应有差异,作保灵解毒效应最明显,但在除草剂高残留量时解毒作用下降。作保灵对三种长残效除草剂都具有明显的解毒作用,作物的出苗率可恢复80%~100%。解毒效应顺序为油莱>白菜>甜菜。 相似文献
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M. A. Foster L. G. Kleine J. Moore 《Journal of the American Oil Chemists' Society》1993,70(12):1239-1240
Direct-seeding guayule (Parthenium argentatum Gray) in west Texas has been successful; however, seedlings grow slowly and are extremely susceptible to weed competition.
An effective preplant or preemergence herbicide is necessary for establishment. The objective of this study was to examine
the effects of preemergence herbicides on guayule stand establishment by direct seeding. Experiments were initiated on a Dalby
clay in 1991 and 1992 at the Texas Agricultural Experiment Station Guayule Research Site near Fort Stockton, Texas. Conditioned
guayule seed (Mexican Bulk) was planted 10 mm deep on raised beds with a Gaspardo SV255 pneumatic planter at 100 seeds/m.
The following herbicides were applied immediately after planting: dimethyl 2,3,5,6-tetrachloro-1,4-benzenedicarboxylate (DCPA)
[4.5, 9.0, 11.0 kg ai/ha (hectare)], pendimethalin [N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzenamine] (0.3, 0.6, 1.1 kg/ha) and prodiamine [N3,N3-Di-n-propyl-2,4-dinitro-6-(trifluoromethyl)-m-phenylenediamine] (0.3, 0.6, 1.1 kg/ha). Herbicides were applied in a 0.5-m band on each bed by using a CO2-powered backpack sprayer with a single-nozzle boom delivering 300 L/ha at 172 kPa pressure. The lowest rates of all herbicides
did not significantly reduce guayule stand density in 1991 when compared to the control. DCPA at 9.0 kg/ha was adequately
selective in both studies. Guayule stand reduction varied from only 2% with DCPA at 4.5 kg/ha in 1991, to 71% with 1.1 kg/ha
of pendimethalin in 1992. DCPA (4.5 and 9.0 kg/ha) would be recommended for preemergence weed control, depending on soil type,
when direct seeding guayule. Based on row spacing recommendations for transplants, at least three established seedlings/m
would be required for an acceptable guayule stand. Seeding rate could be reduced and still allow for effective preemergence
weed control. 相似文献
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Electrochemical destruction of chlorophenoxy herbicides by anodic oxidation and electro-Fenton using a boron-doped diamond electrode 总被引:1,自引:0,他引:1
Enric Brillas Birame Boye José Antonio Garrido Conchita Arias Christos Comninellis 《Electrochimica acta》2004,49(25):4487-4496
The degradation of herbicides 4-chlorophenoxyacetic acid (4-CPA), 4-chloro-2-methylphenoxyacetic acid (MCPA), 2,4-dichlorophenoxyacetic acid (2,4-D) and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) in aqueous medium of pH 3.0 has been comparatively studied by anodic oxidation and electro-Fenton using a boron-doped diamond (BDD) anode. All solutions are totally mineralized by electro-Fenton, even at low current, being the process more efficient with 1 mM Fe2+ as catalyst. This is due to the production of large amounts of oxidant hydroxyl radical (OH) on the BDD surface by water oxidation and from Fenton’s reaction between added Fe2+ and H2O2 electrogenerated at the O2-diffusion cathode. The herbicide solutions are also completely depolluted by anodic oxidation. Although a quicker degradation is found at the first stages of electro-Fenton, similar times are required for achieving overall mineralization in both methods. The decay kinetics of all herbicides always follows a pseudo first-order reaction. Reversed-phase chromatography allows detecting 4-chlorophenol, 4-chloro-o-cresol, 2,4-dichlorophenol and 2,4,5-trichlorophenol as primary aromatic intermediates of 4-CPA, MCPA, 2,4-D and 2,4,5-T, respectively. Dechlorination of these products gives Cl−, which is slowly oxidized on BDD. Ion-exclusion chromatography reveals the presence of persistent oxalic acid in electro-Fenton by formation of Fe3+-oxalato complexes, which are slowly destroyed by OH adsorbed on BDD. In anodic oxidation, oxalic acid is mineralized practically at the same rate as generated. 相似文献
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选取酰胺类、磺酰脲类、硫代氨基甲酸酯类、杂环类、脲类、苯氧羧酸类等常用化学除草剂,以超常规剂量用移液和喷雾两种方式对抛栽和直播籼、粳稻进行药剂试验。研究结果明确了各种除草剂对水稻的药害症状;籼粳稻对各药剂的敏感差异;以及清水冲洗、搁田、施肥等措施对某些除草剂品种造成的水稻药害的缓解作用。 相似文献