双排桩门架—锚杆新型组合支护体系的应用研究

本文分析了双排桩门架支护结构的受力机理。针对工程实际进行变形分析,提出增设锚杆形成锚杆———双排桩门架式组合支护体系的方法,并与监测数据对比、验证。     

毗邻铁路大动脉排架式厂房拆除爆破

文章介绍了运煤车间爆破拆除工程的设计、施工经过及防后座的措施，对于复杂爆破环境的建筑物拆除有一定参考意义。     

The Cooperative Molecular Field Effect

Two‐dimensional arrangements of molecules can show remarkable cooperative electronic effects. Such effects can serve to achieve direct electronic sensing of chemical and physical processes via electrostatic effects, i.e., without transfer of charge or matter between the locus of sensing and that of detection.     

Deep‐UV Photochemistry and Patterning of (Aminoethylaminomethyl)phenethylsiloxane Self‐Assembled Monolayers

The 193 nm photochemistry of (aminoethylaminomethyl)phenethylsiloxane (PEDA) self‐assembled monolayers (SAMs) under ambient conditions is described. The primary photodegradation pathways at low exposure doses (< 100 mJ cm^–2) are benzylic C–N bond cleavage (ca. 68 %), with oxidation of the benzyl C to the aldehyde, and Si–C bond cleavage (ca. 32 %). Amine‐containing photoproducts released from the SAM during exposure remain physisorbed on the surface, where they undergo secondary photolysis leading to their complete degradation and removal after ca. 1200 mJ cm^–2. NaCl(aq) post‐exposure rinsing removes the physisorbed materials, showing that degradation of the original PEDA species (leaving Si–OH) is substantially complete after ca. 450 mJ cm^–2. Consequently, patterned, rinsed PEDA SAMs function as efficient templates for fabrication of high‐resolution, negative‐tone, electroless metal and DNA features with good selectivity at low dose (i.e., ca. 400 mJ cm^–2) via materials grafting to the intact amines remaining in the unirradiated PEDA SAM regions.     

硫醇自组装膜的电化学研究进展

综述了在金电极上硫醇自组装膜的电化学表征方法，性质和应用，介绍了自组装膜上的电子传递机理，并进行了简要的展望。     

基于多工位组合机床的数字化研究

针对组合机床的运动特点,采用多台SDPLC单轴控制系统实现对转台式多工位组合机床的数字化控制,应用系统提供的PLC程序及STEP程序完成组合机床的逻辑控制及加工运动,通过对控制系统通讯功能的开发,利用ADP软件依据人机通讯地址所需求的转换关系,在触摸屏上完成满足用户需求的人机界面设计.     

配钢纤维RPC永久柱模的RC框架抗震性能试验

目的为推广永久性建筑模板的工程应用,探讨钢纤维活性粉末混凝土（RPC）永久柱模对框架结构抗震性能的改善.方法通过对一榀配钢纤维RPC永久柱模的装配整体式钢筋混凝土框架在水平低周反复荷载作用下的拟静力试验,并基于该型框架结构的破坏特征、滞回耗能、变形及延性等性能,分析永久柱模对框架结构抗震性能的影响.结果试件具有显著的＂强柱弱梁＂破坏特征,滞回环面积较大,正、反向延性系数分别达4.44与6,具有较好的变形能力,极限点等效黏滞阻尼系数达0.21,耗能能力较强.永久柱模对核心混凝土有一定的紧箍作用,约束核心柱的横向变形.结论配钢纤维RPC的钢筋混凝土框架结构抗震性能良好,永久柱模的配置提高了框架的抗震能力,这种柱模具有良好的应用前景.     

循环伏安法研究银表面自组装膜的致密性

在Ag电极表面制备了3-巯基丙基三甲氧基硅烷(MPS)自组装单分子膜,通过循环伏安曲线(CV)、接触角等方法对修饰电极的电化学性能、组装膜的致密性等进行了研究.结果表明:修饰后电极的CV曲线峰电流减小、还原峰位发生负移及峰电位差增大,说明MPS已经在Ag电极表面成膜,对电子传输具有明显的抑制作用.膜的致密性受组装液浓度及组装时间的影响,当MPS的浓度为0.1 mmol/L、组装时间为6 h时,抑制电化学反应的效果较好,组装膜成膜状况较为理想.对不同水解时间接触角的分析表明,水解时间不同,MPS尾基的水解自聚度不同,延长水解时间能提高组装膜的致密度.     

Trimetallic PtCoFe Alloy Monolayer Superlattices as Bifunctional Oxygen‐Reduction and Ethanol‐Oxidation Electrocatalysts

A synthesis strategy for the preparation of trimetallic PtCoFe alloy nanoparticle superlattices is reported. Trimetallic PtCoFe alloy monolayer array of nanoparticle superlattices with a large density of high index facets and platinum‐rich surface are successfully prepared by coreduction of metal precursors in formamide solvent. The concentration of cetyl trimethyl ammonium bromide plays a vital role for the formation of a monolayer array of nanoparticle superlattices, while the size of nanoparticles is determined by NaI. The prepared monolayer array of nanoparticle superlattices is the superior catalyst for oxygen reduction reaction as well as for ethanol oxidation owing to their specific structural and compositional characteristics.