全文获取类型
收费全文 | 573篇 |
免费 | 78篇 |
国内免费 | 5篇 |
专业分类
综合类 | 18篇 |
化学工业 | 266篇 |
金属工艺 | 1篇 |
机械仪表 | 12篇 |
建筑科学 | 3篇 |
能源动力 | 9篇 |
轻工业 | 321篇 |
水利工程 | 2篇 |
石油天然气 | 4篇 |
武器工业 | 1篇 |
无线电 | 6篇 |
一般工业技术 | 7篇 |
原子能技术 | 2篇 |
自动化技术 | 4篇 |
出版年
2024年 | 4篇 |
2023年 | 16篇 |
2022年 | 17篇 |
2021年 | 30篇 |
2020年 | 17篇 |
2019年 | 21篇 |
2018年 | 19篇 |
2017年 | 20篇 |
2016年 | 19篇 |
2015年 | 26篇 |
2014年 | 17篇 |
2013年 | 30篇 |
2012年 | 30篇 |
2011年 | 25篇 |
2010年 | 25篇 |
2009年 | 13篇 |
2008年 | 17篇 |
2007年 | 41篇 |
2006年 | 27篇 |
2005年 | 13篇 |
2004年 | 26篇 |
2003年 | 26篇 |
2002年 | 26篇 |
2001年 | 15篇 |
2000年 | 14篇 |
1999年 | 23篇 |
1998年 | 18篇 |
1997年 | 17篇 |
1996年 | 12篇 |
1995年 | 7篇 |
1994年 | 10篇 |
1993年 | 7篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1988年 | 3篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有656条查询结果,搜索用时 375 毫秒
1.
王俏 《精细石油化工进展》2003,4(2):41-43
研究了以植物纤维向日葵壳为原料,采用水解-氧化-水解法制取草酸(乙二酸)的新工艺。与用同类原料,其他方法制草酸相比,本工艺在提高产率,降低生产成本以及易于业化方面有很大突破。在H2SO4质量分数为70%,原料浸泡时间3h以上,m(HNO3):m(向日葵壳)=方面有很大突破,在H2SO4质量分数为70%,原料浸泡时间3h以上,m(HNO3):m(向日葵壳)=2.1:1.0;氧化-水解反应时间5h,反应温度65-70℃的条件下,草酸二水合物收率可达78.5%。 相似文献
2.
Effects of extraction pH, temperature, and time on yield and quality of pectin from sunflower heads (Interstate cultivar) were investigated. The low-methoxyl pectin was extracted, using 0.75% sodium hexametaphosphate at pH 3, 4, and 5 and at 75, 85, and 95°for 20, 40, and 60 min, respectively. Yield, molecular mass, and firmness of jellies of the pectins were determined. Three-way statistical analysis on yield, molecular mass and gel firmness showed strong interactions among pH, temperature and time. Highest yields were obtained at pH 5, 95°for 20 min and pH 4, 85°for 40 min. Pectin extracted for 40 min at pH 3 and 4 and at 85°and 75°C, respectively, had the highest molecular mass. Gel firmness of sunflower pectin prepared at pH 5.4 was higher than that of a commercial citrus pectin. 相似文献
3.
Luciana M. Rodriguez María B. Fernández Ethel E. Pérez Guillermo H. Crapiste 《European Journal of Lipid Science and Technology》2021,123(1):2000132
The main goal of this work is to evaluate the extraction of sunflower oil from enzyme-treated collets using ethanol and isopropanol (IPA) as solvents. The sunflower collets are pretreated with the multienzyme complex Viscozyme L prior to solvent extraction by the Soxhlet method. The influence of the moisture content of the collets, pretreatment, processing time, and solvent type on the amount of total extracted material and the oil extraction efficiency is studied. Some quality parameters such as phospholipid content of the oil and chlorogenic acid content of the residual meal are also analyzed. At low moisture content (7%) the solvents exhibit similar oil extraction ability (98–99%), but with increasing moisture the extraction efficiency of ethanol decreases to about 85%, while no significant differences are observed for IPA. The enzymatic treatment increases the extraction efficiency for all times, especially for ethanol. It is observed that IPA is more efficient in the extraction compared to ethanol, and the amount of nonlipid material is reduced by ≈70%. In addition, the oil extracted with IPA have lower phospholipid content and the residual meal presents a higher chlorogenic acid content. Practical Applications:This work would contribute toward the use of green solvents in the extraction of sunflower oil from collets. Ethanol and isopropanol, used as solvents, present attractive advantages, including low toxicity, good operational security, as well as being obtained from a renewable source. The obtained data provide up-to-date information on the use of these alcohols in the extraction of sunflower oil from collets and the influence of operating conditions, such as moisture content, enzymatic pretreatment of the collets, and the extraction time. Information about oil and meal quality is also reported. 相似文献
4.
Paresh Chandra Dutta 《Journal of the American Oil Chemists' Society》1997,74(6):659-666
Hydrogenated rapeseed oil/palm oil blend, sunflower oil and high-oleic sunflower oil, and French fries fried in these oils
were assessed for contents of sterol oxidation products. Different oxidation products of phytosterols (7α- and 7β-hydroxy-sito-and
campesterol, 7-ketosito- and 7-ketocampesterol, 5α,6α-epoxy-sito- and campesterol, 5β,6β-epoxy-sito-and campesterol, dihydroxysitosterol
and dihydroxycampesterol) were identified and quantiated by gas chromatography (GC) and GC-mass spectroscopy. Rapeseed oil/palm
oil blend contained 41 ppm total sterol oxides before frying operations. After two days of frying, this level was increased
to 60 ppm. Sunflower oil and high-oleic sunflower oil had 40 and 46 ppm sterol oxides, respectively, before frying operations.
After two days of frying operations, these levels increased to 57 and 56 ppm, respectively. In addition to campesterol and
sitosterol oxidation products, small amounts of 7α- and 7β-hydroxystigmasterol were detected in the oil samples. Total sterol
oxides in the lipids of French fries fried at 200°C in rapeseed oil/palm oil blend, sunflower oil, and high-oleic sunflower
oil were 32, 37, and 54 ppm, respectively. The levels of total oxidized sterols, calculated per g sample, ranged from 2.4
to 4.0 ppm. In addition to the content of phytosterol oxides, full scan mass spectra of several oxidation products of stigmasterol
are reported for the first time.
Part of these results were presented at the 86th Annual Meeting of the AOCS, May 7–11, 1995, San Antonio, TX. 相似文献
5.
D. Wiesenborn Z. Zbikowski H. Nguyen 《Journal of the American Oil Chemists' Society》1995,72(2):183-188
Extract of purple sunflower hulls is a potential red food colorant; however, suitable process conditions must still be identified.
Selected process variables were studied using bench-scale units to prepare, clarify, concentrate and spray dry extracts. Concentration
by evaporation at 32°C and addition of maltodextrin to 15% (wt/dry wt) prior to drying largely eliminated pigment degradation
during those steps. Relative to water extracts, extracts prepared with 5 to 15% ethanol in water generally yielded more pigment
with similar levels of degradation and loss during subsequent processing. Use of 5% ethanol/2% citric acid reduced yield by
about half relative to water, but gave a powder with a lower degradation index and wetting time. Percentage recovery of pigment
during concentration and drying was not greatly affected by solvent type or extraction temperature. 相似文献
6.
Francis W. Maloba Michael L. Rooney Paul Wormell Minh Nguyen 《Journal of the American Oil Chemists' Society》1996,73(2):181-185
The oxidative stability of sunflower oil (SFO) was measured during storage at 23 and 37°C in the presence of a novel oxygen-scavenging
film that contained polyfuryloxirane (PFO). Commercially refined and deodorized SFO was stored in a lighted room in sealed
transparent packages containing either PFO film or an antioxidant, 0.02% butylated hydroxytoluene (BHT). Oxidative stability
was evaluated by determination of peroxide values and gas-chromatographic measurement of headspace hexanal. SFO stored in
the presence of the oxygen-scavenging film was more stable than oil stored without the film, or than film stored with 0.02%
BHT. The PFO film scavenges oxygen through energy-transfer sensitization of singlet oxygen. The film is doped with eosin and
the naturally-occurring dye, curcumin, which absorb over a wide range of visible wavelengths. Curcumin transfers its absorbed
energy to eosin, which sensitizes the production of singlet oxygen. The singlet oxygen is scavenged by PFO. The use of two
dyes increases the efficiency of the sensitization process, reducing the illumination time and intensity required for effective
oxygen scavenging. 相似文献
7.
Yinzhong Guo Vijay M. Mannari Pulin Patel John L. Massingill 《Journal of Coatings Technology and Research》2006,3(4):327-331
A series of soybean oil phosphate ester polyols (SOPEP) was prepared by reaction of fully epoxidized soybean oil with phosphoric
acid and simultanoeous hydrolysis in the presence of a polar solvent. The polyols were characterized by determination of acid
value, oxirane number, hydroxyl value, molecular weight (GPC), and FTIR spectra. These polyols with varying amounts of acid
phosphate groups could be self-emulsified to form aqueous dispersions after neutralization with organic base. These aqueous
dispersion showed varying degrees of stability and their appearance ranged from opaque dispersions to translucent to clear
solutions. Waterborne coating compositions were prepared using these aqueous dispersions as principal components and their
thermally cured film properties were studied. it was found that by careful selection and formulation, SOPEPs can be successfully
used for low-VOC waterborne coating formulations. SOPEPs with 3.5% phosphate ester content showed visibly superior corrosion
resistance properties. 相似文献
8.
G.?Perretti E.?Finotti S.?Adamuccio R.?Della Sera L.?MontanariEmail author 《Journal of the American Oil Chemists' Society》2004,81(12):1119-1123
The aim of the present study was to highlight the main differences between seed oils produced from conventionally cultivated
crops and organically cultivated ones and processed using mild extraction procedures. The composition and the nutritional
and health aspects of both types of sunflower seed oils were compared and were analytically tested to determine the macroscopic
differences in proximate composition, the main differences in the minor components, the main quality parameters, the in vitro antioxidant activity, and the presence of trans-ethylene steroisomers in FA. No significant trends were found in the oil samples for TAG and FA composition, but remarkable
differences were found in the composition of minor components and in the main chemical and analytical quality properties.
The organically grown samples had a higher total antioxidant activity compared with the conventional samples. Trans FA were found only in the conventional oils. 相似文献
9.
Pascale Sabin Bouchra Benjelloun-Mlayah Michel Delmas 《Journal of the American Oil Chemists' Society》1997,74(5):481-489
Two sets of alkyd resins of variable oil lengths with the required properties for offset printing ink formulations, modified
by sunflower and rapeseed oil, were synthetized according to the “monoglyceride” process. The influence of the acyl composition
of the modifying vegetable oil and of the oil content on alkyds’ properties was determined by detailed chemical and rheological
characterization. Molecular structure, size, and molecule size distribution appeared to be linked to these two factors. A
comparative study with two usual linseed oil-modified alkyds led to determination of the more appropriate alkyds for applications
in offset varnishes. 相似文献
10.