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排序方式: 共有690条查询结果,搜索用时 15 毫秒
1.
The oxidation behavior of a Cu60Hf25Ti15 bulk metallic glass was studied over the temperature range of 375–520 °C in dry air. The oxidation kinetics of the amorphous
alloy generally followed the parabolic law at all temperatures, with an oxidation rate increasing with temperature. The oxidation
rates of the amorphous alloy were much higher than those of polycrystalline pure-Cu, implying that the additions of Hf and
Ti accelerated the oxidation reaction. The composition of the scales formed on the amorphous alloy was strongly temperature-dependent,
since they consisted mostly of Cu4O3 and CuO with minor amounts of HfO2 at T ≤ 450 °C, while mostly CuO with minor amounts of HfO2 and Cu2TiO3 were detected at higher temperatures. In addition, nanocrystalline Cu51Hf14 and Cu3Ti2 phases were detected on the substrate after oxidation at T ≥ 450 °C, indicating the occurrence of phase transformation. 相似文献
2.
Using TiO2 as carrier, CuO/TiO2 catalysts with different CuO loading were prepared by the impregnation method. The catalytic activities in NO+CO reaction
were examined with a micro-reactor gas chromatography reaction system and the methods of TPR, XPS and NO-TPD. It was found
that the catalytic activities were affected by pretreatment atmosphere, i.e. H2 atmosphere > reduction–reoxidation > 10%CO/He > reaction gas (fresh sample). NO decomposition was better by low-valence Cu
species than by high-valence Cu species, i.e. Cu0>Cu+>Cu2+. The XPS results indicated that Cu species on CuO/TiO2 were Cu0, Cu+, normal Cu2+(Cu2+(I)) and chain-structured Cu2+(Cu2+(II)) as –Cu–O–Ti–O–. The activities of Cu2+(II) were much higher than that of Cu2+(I), but both species were very unstable in the reaction atmosphere and easily reduced by CO, which accounted for the variable
activities of fresh catalysts with increasing reaction temperature. In NO+CO reaction, the redox process was a cycle of Cu+–Cu2+(I) at low reaction temperature but was a cycle of Cu0–Cu+ at high reaction temperature. As shown by NO-TPD, high catalytic activities could be attributed to the following factors,
e.g. oxygen caves on the catalyst’s surface after pretreatment with H2 and reduction–reoxidation, formation of Cu0 after pretreatment with H2, and increment of Cu species dispersion and formation of Cu2+(II) after pretreatment with reduction–reoxidation. 相似文献
3.
以氢氧化铜为前驱体,在超声和微波作用下制备纳米氧化铜。借助透射电镜(TEM)、X射线衍射(XRD)、粒度分析等手段,研究了超声、分散剂、微波等制备条件的影响。结果表明:采用该法可以制备粒径小(15nm)、分散良好的纳米氧化铜粉体;超声可使前驱体Cu(OH)2转变为CuO,并粉碎颗粒间形成的团聚;分散剂通过表面修饰抑制颗粒的团聚;微波加热促进了前驱体的转化,并抑制颗粒的长大。 相似文献
4.
研究了不同水热(180℃)碱性条件下(糖)醇对Cu2 的还原,通过控制不同水热条件及添加不同种类和质量的(糖)醇,借助XRD和SEM分析,得到了不同的产物及产物形貌.当不加任何(糖)醇时,产物为CuO,其形貌随c(OH-)/c(Cu2 )增大而由薄带和球形颗粒向薄片转变;当在不同c(OH-)/c(Cu2 )中添加同量的D-Sorbitol,c(OH-)/c(Cu2 )=2时产物主要为Cu2O,具有多种形貌,c(OH-)/c(Cu2 )=4和6时产物都为金属Cu,但c(OH)/c(Cu2 )=4时产物形貌有线状、棒状及立方六角状,c(OH-)/c(Cu2 )=6时产物主要为颗粒状;当保持c(OH-)/c(Cu2 )=4而添加不同质量的D-Sorbitol时,产物也都为金属Cu,形貌上有较大差异;当保持c(OH-)/c(Cu2 )=4而添加等摩尔数的不同(糖)醇D-Sorbitol,Mannitol,Xylitol时,产物还都是金属Cu,形貌随(糖)醇不同而发生显著变化.研究结果表明,水热(180℃)条件下,c(OH-)/c(Cu2 )值可以决定产物形貌,(糖)醇的加入不仅可以与Cu2 或其配合物发生氧化还原反应,而且其加入的质量和种类可以决定产物的形貌. 相似文献
5.
To study the influence of steam on the solid state reaction between MeO (Me = Ni, Co, Cu or Fe) and Al2O3, MeO/-Al2O3 and MeO/-Al2O3 model catalysts were kept in either N2/20% O2 or N2/O2/30% H2O at 500–1000°C. The samples were subsequently analyzed with RBS and FTIR. Surprisingly, nickel, cobalt and copper volatilized when MeO/-Al2O3 or MeAl2U4/-Al2O3 samples were annealed in the presence of 0.3 atm steam at 1000°C. Especially copper was found to volatilize very rapidly in the presence of steam, even at a temperature as low as 800°C. FTIR spectra of steam-treated NiO/-Al2O3 samples showed the incorporation of hydroxyl groups in the nickel oxide layer. This observation and an excellent agreement with thermochemical calculations support our conclusion that the volatile species are metal hydroxides. The solid state reaction of MeO with-Al2O3 was found to proceed at a much higher rate in the presence of 0.3 atm steam at 500–800°C, presumably as a result of an enhanced surface mobility of Me and Al ions along the grain boundaries and the surfaces of the internal pores of the-Al2O3 support, when steam is present. 相似文献
6.
在超细催化剂CuO/ZnO/SiO_2上CO_2加氢合成甲醇的优化研究 总被引:2,自引:0,他引:2
本文考察了焙烧温度、还原温度、反应温度、反应压力和体积空速对用于CO2加氢反应的超细CuO/ZnO/SiO2催化剂性能和产物分布的影响,确定了催化剂的合适焙烧温度、还原温度,并对CO2加氢反应条件进行了优化 相似文献
7.
Youngha Kim Sungkwan Kim Young-Ah Jeon Yunseok Kim Hanjong Paik Yangsoo Kim Sang-Chul Han Young-Hee Han Nyeon-Ho Jeong Tae-Hyun Sung Jong-In Hong Kwangsoo No 《Journal of Electroceramics》2006,17(2-4):1063-1067
YBa2Cu3Ox (Y123) superconducting films were fabricated on Cu substrates using a simple screen-printing method, from Cu-free powders
(Y2O3 and BaCO3). In the process, CuO, which causes superconducting properties of Y123 films to deteriorate, was formed on the film surface.
By varying the atomic ratio of Y to Ba (Y:Ba = 1:1∼1:4), the ratio needed to prevent CuO formation was found for the film
surface that had been heat-treated at 980∘C for 17 s. The film, with the ratio of Y to Ba (Y:Ba = 1:1), is reheat-treated at 930∘C for 9 min 30 s to form a superconducting Y123 phase. It was possible to prevent CuO formation by controlling the ratio of
Cu-free powders in the mixture and to fabricate YBCO superconductors on Cu substrates using a two-step heat-treatment. 相似文献
8.
CuO/CeO2 catalysts were prepared by a coprecipitation method and tested for CO removal from reformed fuels via selective oxidation. The influence of the calcination temperature on the chemical compositions and catalytic performance of CuO/CeO2 catalysts were studied. It was found that CuO/CeO2 catalysts exhibit excellent CO oxidation activity and selectivity, and the complete removal of CO is attained when the catalysts are calcined at appropriate temperatures. XRD, TPR and XPS results indicate that CuO/CeO2 catalysts exhibit higher catalytic performance in CO selective oxidation due to the strong interaction between copper oxide and cerium dioxide, which promotes the dispersion and hydrogen reduction activity of copper. 相似文献
9.
采用磁控溅射, 通过氧氩比的调制在玻璃衬底上沉积了单斜结构的CuO薄膜, 并重点研究了氧氩比对薄膜微结构及光学吸收边的影响。研究表明随着氧氩比的增加, 薄膜逐渐从多相向单相转变, 薄膜表面逐渐趋于光滑和平整, CuO<-111>择优取向逐渐减弱。晶轴上的晶格畸变结果显示氧氩比对晶轴 a, b和 c的影响不尽相同。a, b轴上呈现的压应力均先明显增大然后变得稳定, 而 c轴上则呈现了压应力向拉应力的转变。氧氩比对晶格常数的影响反应了 a, b和 c轴上晶粒生长的各向异性。CuO薄膜为直接带隙半导体, 其1.9 e V附近的光学吸收边随着氧氩比的增加而略微蓝移, 吸收边的蓝移归结于晶粒的量子尺寸效应。 相似文献
10.
《Advanced Powder Technology》2021,32(8):3063-3074
The objective of the present numerical study is to investigate the heat transfer enhancement, entropy generation, and thermal performance of turbulent nanofluids inside double-pipe heat exchangers equipped with novel perforated cylindrical turbulators. Effects of inflow velocity, CuO nanoparticles volume fraction and perforated index are evaluated on the Nusselt number, friction loss, thermal performance factor (η), and viscous irreversibilities of the double-pipe heat exchangers. The newly proposed perforated turbulators with CuO nanopowder with ϕ = 1.5% provide the thermal performance of η = 1.931, which is considerably higher than the other previous studies. The results show that raising PI reduces the turbulent kinetic energy, especially in outer regions of the cylindrical turbulator. The jet formation near the walls and the perforations is the primary physical reason for this. The viscous entropy generation is increased up to 153.0% by increasing the Re number from 6,000 to 17,000 for PI = 8% and DR = 0.7. Thermal boundary layer disruption is the primary physical reason for heat transfer enhancement. 相似文献