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排序方式: 共有791条查询结果,搜索用时 15 毫秒
1.
Fatemeh Norouzi Jobie Mojtaba Ranjbar Akbar Hajizadeh Moghaddam Mahmoud Kiani 《Advanced Powder Technology》2021,32(6):2043-2052
For the first time in this study, Zinc oxide nanoparticles were biosynthesized by the eco-friendly and cost-effective procedure using Amygdalus scoparia stem bark extract then used as antibacterial, antifungal, anticancer, and anti-diabetic agents. The characterization techniques confirmed the biosynthesis, crystalline nature, structure, size, elemental composition of ZnO NPs and bioactive compounds that exist in A. scoparia extract accounting for Zn2+ ion reduction, capping and stabilization of ZnO NPs. The ZnO NPs displayed remarkable inhibitory activity against E. coli, E. aerigenes, S. aureus, P. oryzae, F. thapsinum, and F. semitectum compared to antibiotic standards. The ZnO NPs showed significant inhibitory effects on cancer cell lines, while it had no toxic effect on Vero normal cell line. The ZnO NPs (30 mg/kg)-treated diabetic rats showed significantly higher levels of insulin and lower AST, ALT and blood glucose compared with the STZ induced diabetic group and other treated groups (P < 0.05). The ZnO NPs- and extract-treated rats showed significantly higher levels of IR, GluT2, and GCK expression and lower TNFα expression compared with the STZ induced diabetic rats. Our findings showed that ZnO NPs represented an outstanding performance for biological applications. 相似文献
2.
《Advanced Powder Technology》2022,33(8):103637
With excellent micromixing characteristic of rotating packed bed (RPB), many nanoparticles with small average size, narrower distribution and good morphology had been successfully and continuously prepared. To reveal complex crystal process, an empirical model were developed to simulate nano-ZnO by considering mass changed, population balance equation, growth rate G, nucleation rate B, drop sizes Di, and resident time t. The predicted particle sizes were shown good agreement with experimental data with error of ±10%. Therefore, it was further adopted to predict the effects of rotating speed, liquid flow rate and reactant concentration on the mean particle size. To look more deeply insight in this process, their contribution ratios were further analyzed. The proposed empirical models were of great helpful to obtain suitable operation conditions for preparing much better properties of nanoparticles with fewer experiments. It was also beneficial to produce other nanoparticles in RPB. 相似文献
3.
Precipitation of calcium deficient hydroxyapatite nanoparticles in an environmentally benign manner by using only dilute solutions of calcium hydroxide and phosphoric acid without pH adjustment and addition of other chemicals, and water, being the only by-product was investigated by using continuous flow Vortex Reactor (VR) and Semi-Batch Reactor (SBR). The effect of hydrodynamics by changing the Reynolds number of the jets providing residence times of 8.4 ms to 4.37 s for VR, and by changing the stirrer speed between 100 rpm (Re = 2656) and 1000 rpm (Re = 26560) for SBR, on the particle size, particle size distribution, and morphology of the particles was investigated for both systems. It has been shown that it is possible to produce pure phase hydroxyapatite nanoparticles in the desired morphology by changing production system, without resorting to additives. While VR produced rod-like particles with the crystallite size around 4 nm, SBR produced spherical particles with the crystallite size of around 5 nm. 相似文献
4.
In this study, a new surfactant-solvent system was described for the preparation of periodic stripe patterns of zeolite A on solid substrates. The evaporation induced self-assembly of zeolite A particles was due to the stick-slip dynamics of the three-phase contact line of the colloid solutions in acetone containing 10% (v/v) poly(dimethylsiloxane) (PDMS) fluid (2 cst.). In order to investigate the possible effects of particle size and the particle concentration on the stick-slip dynamics, three types of zeolite A samples with different particle sizes (zeolite A-I: 250-500 nm, zeolite A-II: 100-250 nm and zeolite A-III: 0-100 nm) were utilized to prepare 0.007-0.06% (w/v) colloidal dispersions. Zeolite A micropatterns were self-assembled on the surface of glass, high density polyethylene (HDPE) and poly(tetrafluoroethylene) (PTFE) substrates, which were placed vertically inside the colloid solutions and held against the wall of the cylindrical vial during the evaporation of acetone. The stripe patterns of zeolite A particles were analyzed with field emission scanning electron microscope (FE-SEM) and optical microscope. The widths of microstripes and the distance between the stripes were found as 2-20 μm and 40-60 μm respectively depending on the particle concentration. By using the stick-slip dynamics of colloids, the linear micropatterns of zeolite A nanocrystals were prepared with low cost and low energy. 相似文献
5.
This paper presents a device proposal based on a junction between an absorbing semiconductor nanorod structure and another window semiconductor layer for solar cell application. The possibility of band gap tuning by varying the diameter of the nanorods along the length, higher absorption coefficient at nanodimensions, the presence of a strong electrical field at the nanorod-window semiconductor nanojunctions and the carrier confinement in lateral direction are expected to result in enhanced absorption and collection efficiency in the proposed device. Process steps, feasibility, technological tasks needed for the realization of the proposed structure and the novelty of the present structure in comparison to the already reported nanostructured solar cells are also discussed. 相似文献
6.
《中国稀土学报(英文版)》2022,40(1):57-62
High surface area mixed oxide 8.7% NiO-CeO2 nanoparticles (122 m2/g; 6–7 nm) were prepared using a reversed microemulsion method, and were tested for dry methane reforming (DRM). The catalytic activity of these nanoparticles remains stable under the severe conditions of DRM (700 °C), and they show better carbon resistance than conventional NiO-CeO2 catalysts prepared without control of the size. The activity and selectivity of nanoparticles and reference catalyst are similar, but nanoparticles reduce the accumulation of carbon by 63% during the DRM tests, which is a key feature for this reaction. XPS and H2-TPR suggest that the improved carbon resistance of the nanoparticles is due to the better interaction and cooperation between NiO and CeO2 mixed phases. In nanoparticles, the participation of cerium cations in the redox processes taking place during DRM stabilizes cationic species of nickel. On the contrary, the catalyst prepared without control of the size suffers segregation of Ni during DRM reaction, and segregated Ni explains the higher catalytic formation of carbon. 相似文献
7.
8.
Min-Jae Yoon Yoan-Sang Bae Sang-Ha Son Jae-Wook Lee Chang-Ha Lee 《Korean Journal of Chemical Engineering》2007,24(5):877-880
Luminescent yttrium aluminum garnet (YAG, Y3Al5O12) nanoparticles doped with Eu (10 at%) were synthesized in batch-type and continuous-type supercritical water (SCW) reactors.
In the case of the continuous-type SCW method, the particles of YAG: Eu phosphors were much smaller and demonstrated a uniform
spherical-like shape. Inversely, in the case of the batch-type SCW method, a needle-like or elliptical-like shape was formed
because a finite amount of time was required to reach SCW conditions from ambient conditions. However, the emission intensity
of YAG: Eu phosphors synthesized by using the batch-type SCW method was stronger. Therefore, it is concluded that the continuous-type
SCW method is superior to the batch-type SCW method from the viewpoint of the particle size and shape, but the luminescence
property of phosphors in the continuous-type SCW method needs to be improved. In addition, a calcination process slightly
improved the luminescence intensities of YAG: Eu phosphors generated by using either the batch-type or continuous-type SCW
methods. 相似文献
9.
Manganese ferrite nanoparticles synthesized through a nanocasting route as a highly active Fenton catalyst 总被引:2,自引:0,他引:2
Teresa Valds-Solís Patricia Valle-Vign Sonia lvarez Gregorio Marbn Antonio B. Fuertes 《Catalysis communications》2007,8(12):2037-2042
Spinel ferrite MnFe2O4 nanoparticles were synthesized by means of a nanocasting technique using a low-cost mesoporous silica gel as a hard template. The magnetic nanoparticles, of <10 nm diameter and with a surface area of around 100 m2/g, were tested as a heterogeneous Fenton catalyst for the decomposition of hydrogen peroxide under neutral and basic conditions. This catalyst shows a much higher activity than previous heterogeneous catalysts reported in the literature, which is mainly ascribed to its small particle size. Furthermore, the magnetic catalyst can be easily separated from the reaction medium by means of an external magnetic field. The effects of residual silica and the purity of the catalyst (hematite formation) on catalytic activity have been studied and correlated. The results obtained show this catalyst to be a suitable candidate for the removal of pollutants in wastewaters by means of the Fenton heterogeneous reaction. 相似文献
10.
This paper documents a study of an Au nano-dot array that was fabricated by electron beam lithography on a glass wafer. The patterns that had features of 100nm dots in diameter with a 2-mum pitch comprised a total area of 200x200mum(2). The dot-shaped Cr underlayer was open to the air after developing Poly(methyl methacrylate) (PMMA). When dipped into the Cr etchant, the exposed Cr layer was eliminated from the glass wafer in a short period of time. In order to ultimately fabricate the Ti/Au dot arrays, Ti and Au were deposited onto the arrays with a thickness of 2 and 40nm, respectively. The lift-off procedure was carried out in the Cr etchant using sonication in order to completely remove the residual Cr/PMMA layer. The fabricated Au nano-dot array was then immersed in an Ag enhancing solution and then into an ethanol solution containing (N-(6-(Biotinamido)hexyl)-3'-(2'-pyridyldithio)-propionamide (Biotin-HPDP). The substrate was analyzed using a correlated atomic force microscopy (AFM) and confocal Raman spectroscopy. Through this procedure, position-dependent surface-enhanced Raman spectroscopy (SERS) signals could be obtained. 相似文献