Cumulant calculations of thermodynamic quantities for the Hubbard and the emery model

The calculations of the first paper suggesting phase separation in the Hubbard model [2] are performed under modern computer facilties for the one and three-band Hubbard model. High-temperature approximations for specific heat and static correlation functions are obtained. The latter show, at these high temperatures, no tendency to phase separate in the same way as in the cited paper because our spin parallel nearest-neighbor charge correlation function is negative for all doping values. The spin antiparallel correlation function has positive and negative values for different doping regimes.Extension of this work to higher levels of iterations and to other correlation functions is in progress.     

电厂热力系统耗差分析系统实现的研究与发展

总结了电厂热力系统耗差分析几种实现方式，回顾了国内在该领域的发展过程。电厂热力系统耗差分析实现方式分别经历了独立的耗差分析系统、基于DCS的耗差分析系统、基于MIS的耗差分析系统。并在不同的分析方式上进行了评价，指出了耗差分析系统的发展方向。     

聚电解质溶液分子热力学模型

<正>链状聚电解质由于是长链大分子又有很高的电荷密度,其溶液即使在极低的浓度下仍具有很强的负偏差,与Debye-Huckel理论预测的结果相去甚远。工程上使用的Manning模型认为聚离子的电荷密度有一临界值,当超过临界值时,反离子即凝聚在聚离子表面使其实际电荷密度降至临界值。Nagvekar等在该模型的基础上引入NRTL方程,以计及短程相互作用的贡献。Manning等的方法虽然有一定的物理意义,但临界值的确定缺乏可靠的根据。     

Estimation of Thermodynamic Properties from Binary Phase Diagram

The general relationship between binary phase diagrams and the thermodynamic properties was system-atically derived without any assumption.A procedure was presented to estimate the thermodynamic proper-ties from the binary phase diagrams.     

带疏水泵加热器出口主凝结水焓的计算方法

以火电厂热力系统热力单元矩阵分析法为基础，提出了一种更为科学有效的带疏水泵加热器出口主凝结水焓分析计算的新方法，应用表明，其结论与常规算法完全一致，图2表1参3。     

Calorimetric determination of the enthalpy change for the binding of methyl orange to poly(vinylpyrrolidone) in aqueous solution

Thermodynamic parameters have been determined for the interaction of methyl orange and poly(vinylpyrrolidone) in aqueous solutions containing tris, tris and hydrochloric acid, or water only. Enthalpy changes were determined by use of a flow microcalorimeter. Free energy changes were calculated from the results of equilbrium dialysis studies. The results are interpreted in terms of the behaviour of poly(vinylpyrrolidone) in these systems. Analysis of data shows that the hydrophobic interactions in the systems are in the order: tris > wateronly > tris-HC1.     

Thermodynamic state of reinforced interpenetrating polymer networks

The free energies of mixing of two networks in the interpenetrating polymer network based on crosslinked polyurethane and poly(ester acrylate) have been determined by the vapour sorption method. It was established that the constituent networks in the IPN are not miscible. The introduction of fillers of different chemical nature increases the compatibility. The thermodynamic affinity of the fillers to the individual networks and IPN was estimated. It was established that when the free energy of interaction of one or both components of the IPN with the filler is negative, reinforcement leads to the formation of a compatible and equilibrium system. For fillers having no affinity to the polymers, compatibilization is observed, which is connected with slowing down of phase separation in the system in the presence of filler.     

The Influence of Medium on Low-Voltage Circuit Breaker Arcs

This paper mainly focuses on the influence of three kinds of media： air, air-10%PA （Nylon） and air-10% POM （polyoxymethylene） on low-voltage circuit breaker arcs. A threedimensional （3-D） model of arc motioa under the effect of external magnetic field is built based on magnetohydrodynamics （MHD） equations. By adopting the commercial computational fluid dynamics （CFD） package based on the control-volume method, the above MHD equations are solved. For the media of air-10%PA and air-10%POM, the distributions of stationary temperature and electrical potential and the transient motion processes are compared with those of air arc. The research shows that both air-10%PA and air -10% POM can cool the arc plasma and the former is more effective. Both of them can increase the stationary voltage as well. Moreover, the presence of the two mixtures can accelerate the arc motion toward the quenching area and ensures the arc quenched in time.     

600MW机组热力系统优化设计探讨

在保证机组运行安全、可靠的前提下，对热力系统进行了优化，合理地减少了备用设备和备用容量，降低系统阻力及工质损失。从而达到了降低能耗和初投资，减少运行成本的目的。