全文获取类型
收费全文 | 134篇 |
免费 | 2篇 |
国内免费 | 2篇 |
专业分类
综合类 | 1篇 |
化学工业 | 111篇 |
金属工艺 | 5篇 |
矿业工程 | 2篇 |
一般工业技术 | 14篇 |
冶金工业 | 4篇 |
自动化技术 | 1篇 |
出版年
2023年 | 8篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 4篇 |
2019年 | 1篇 |
2018年 | 4篇 |
2017年 | 6篇 |
2016年 | 3篇 |
2015年 | 1篇 |
2014年 | 3篇 |
2013年 | 3篇 |
2012年 | 2篇 |
2011年 | 10篇 |
2010年 | 3篇 |
2009年 | 6篇 |
2008年 | 3篇 |
2007年 | 12篇 |
2006年 | 5篇 |
2005年 | 7篇 |
2004年 | 18篇 |
2003年 | 10篇 |
2002年 | 11篇 |
2001年 | 7篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1993年 | 1篇 |
1991年 | 1篇 |
排序方式: 共有138条查询结果,搜索用时 0 毫秒
1.
Chao M. Huang Dong Zhu Xu Yuren Waltraud M. Kriven Chao Y. Yuh 《Materials Science and Engineering: A》1996,220(1-2)
A composite of O′SiAlON (Si2-xAlxN2-xO1+x, with x 0.14) reinforced with 20 vol.% SiC monofilaments was fabricated by hot-pressing, at 1600°C, for 2 h under 34 MPa pressure. The mechanical and interfacial properties of the composites, as-fabricated as well as post-oxidized, were, investigated. The composite exhibited a significant improvement in ultimate flexure strength (640 MPa) and work of fracture (42 kJ m−2) compared with that (350 MPa and 1.8 kJ m−2, respectively) of the monolithic material. These mechanical properties were slightly increased after the composite was heat treated for 24 h in air at 1200 and 1300°C. However, the composite exhibited a significant degradation in ultimate strength, while the work of fracture (WOF) remained unchanged after exposure in air at temperatures beyond 1400°C. The as-fabricated composite revealed a low interfacial shear strength (6.2 MPa) and a frictional sliding stress (3.2 MPa). After the composite was oxidized at elevated temperatures, the interfacial bonding and sliding stresses were reduced to noticeable extents, resulting from the degradation of the carbon coating layer of the SiC monofilaments. 相似文献
2.
Hans-Joachim Kleebe Giuseppe Pezzotti 《Journal of the American Ceramic Society》2002,85(12):3049-3053
The grain-boundary structure of a model SiAlON polycrystal with nominal composition Si5 AlON7 was characterized by transmission electron microscopy (TEM) both in an equilibrium (as-processed) state at room temperature and after quenching from elevated temperature. In addition, low-frequency (1–13 Hz) internal friction data were recorded as a function of temperature, showing a pronounced grain-boundary sliding peak positioned at 1030°C. High-resolution transmission electron microscopy (HRTEM) of the equilibrated low-temperature microstructure revealed residual glass only at multigrain junctions, but no amorphous intergranular films were observed. The detection of clean interfaces in the as-processed sample contradicts the internal friction data, which instead suggests the presence of a low-viscosity grain boundary phase, sliding at elevated temperatures. Therefore, a thin section of the as-sintered material was heated to 1380°C and rapidly quenched. HRTEM analysis of this sample showed, apart from residual glass pockets, wetted grain boundaries, which is in line with the internal friction experiment. This wetting-dewetting phenomenon observed in z = 1 SiAlON is expected to have a strong impact not only on high-temperature engineering ceramics but also on geological, temperature-activated processes such as volcanic eruptions. 相似文献
3.
Mark I. Jones Hideki Hyuga Kiyoshi Hirao Yukihiko Yamauchi 《Journal of the American Ceramic Society》2004,87(4):714-716
Novel Lu-α-SiAlON ceramics were produced by hot pressing mixtures of Si3 N4 , Lu2 O3 , AlN, and Al2 O3 at 1950°C for 2 h in a nitrogen atmosphere. The resultant SiAlON was fully dense and possessed a uniform, equiaxed microstructure with a grain size of ∼1 μm, which resulted in a high hardness of >19 GPa. In addition to high hardness, the sample showed very high optical transparency in the visible light region, with >70% transmission at higher wavelengths. This high transparency was attributed to the uniform, dense microstructure and lack of residual grain-boundary phase. 相似文献
4.
5.
通过碳还原氮化反应,从工业废料粉煤灰制备氮化陶瓷类材料.采用氮/氧分析仪测定产物氮含量,评价氮化反应程度;以BET氮气吸附法测定比表面积,分析粉体活性;以扫描电镜分析样品表面形貌;以热重分析仪测定碳含量,X射线能谱仪估计元素组成.比较机械混合法、超声法和高能球磨法3种碳加入方式.结果表明,粉煤灰自身含碳的还原活性处于机械混合法和高能球磨混合法之间,高能球磨法对提高反应混合物活性最有效,所得产物结晶氮含量最高,质量分数可由0.3 %提高到23.1%. 相似文献
6.
7.
Mikinori Hotta Junichi HojoKatsutoshi Komeya Junichi TatamiTakeshi Meguro Hirohisa MasudaKenji Morinaga Yi-Bing Cheng 《Materials Letters》2011,65(1):116-118
Ca-α SiAlON powders were prepared by carbothermal reduction-nitridation of CaO-Al2O3-SiO2 glasses at 1450 °C for 2 h in nitrogen. The content of Ca-α SiAlON phase was 65-81% in the products, and the other phases were AlN and β-SiAlON. The products contained hollow spheres with the size of around 5 μm in diameter. The particle morphology was almost identical to that of Ca-α SiAlON prepared from CaCO3-Al2O3-SiO2 powder mixtures. 相似文献
8.
Rong-Jun Xie Mamoru Mitomo Kyota Uheda Fang-Fang Xu Yoshio Akimune 《Journal of the American Ceramic Society》2002,85(5):1229-1234
Rare-earth-doped oxynitride or nitride compounds have been reported to be luminescent and may then serve as new phosphors with good thermal and chemical stabilities. In this work, we report the photoluminescence (PL) spectra of europium-, terbium-, and praseodymium-doped Ca-α-SiAlON ceramics. The highly dense ceramics were prepared by hot pressing at 1750°C for 1 h under 20 MPa in a nitrogen atmosphere. Europium-doped Ca-α-SiAlON displayed a single broad emission band peaking at λ= 550–590 nm depending on the europium concentration. The emission bands in the spectra of europium-doped Ca-α-SiAlONs were assigned to the allowed transition of Eu2+ from the lowest crystal field component of 4 f 6 5 d to 8 S7/2 (4 f 7 ) ground-state level. The emission spectra of terbium- and praseodymium-doped Ca-α-SiAlON ceramics both consisted of several sharp lines, which were attributed to the 5 D4 →7 F j ( j = 3, 4, 5, 6) transitions of Tb3+ and 3 P0 →3 H j ( j = 3, 4, 5) transitions of Pr3+ , respectively. In particular, the terbium-doped α-SiAlON ceramics showed a strong green emission among these phosphors. 相似文献
9.
Hilmi YurdakulServet Turan 《Ceramics International》2011,37(5):1501-1505
Outstanding properties for SiAlON ceramics can be obtained by tailoring the microstructure through α-SiAlON and β-SiAlON phase content as well as a type of secondary phases. It is so far well known that while some of the elements could be accommodated in α-SiAlON structure, β-SiAlON does not easily accommodate different elements in its structure. In this work, SiAlON ceramics were produced by using β-Si3N4 starting powder containing small amount of iron and chromium and the possible incorporation of iron and chromium into β-SiAlON structure was investigated by using analytical transmission electron microscopy (TEM) techniques. As a result of analytical TEM analysis, it is found that transition metals (Cr and Fe) can enter into the β-SiAlON crystal structure. 相似文献
10.
《Ceramics International》2016,42(10):11924-11929
The incorporation of Fe and Cr atoms into β-Si5AlON7 and the effects on the mechanical properties of β-Si5AlON7 were theoretically studied at the GGA-PBE/USP level of theory. The incorporation of Fe and Cr atoms shows remarkable site preferences in β-Si5AlON7. The binding energies between the incorporated Fe/Cr atoms and the parent β-Si5AlON7 are ~5.0 eV, indicating both Fe@β-Si5AlON7 and Cr@β-Si5AlON7 are thermodynamically stable. Fe incorporation at the A, B and G sites induces remarkable increase in the shear modulus and Young's modulus; all other Fe/Cr incorporated β-Si5AlON7 structures exhibit lowered shear modulus and Young's modulus than the parent β-Si5AlON7. Except CrG@β-Si5AlON7, the Poisson's ratio of β-Si5AlON7 decreases in all cases of Fe and Cr incorporation. 相似文献