单分散六边形扁平溴碘化银微晶的结构与性能的研究

应用可控双注仪制备了一系列碘含量相同而碘在微晶中分布不同的单分散六边形扁平溴碘化银乳剂。用扫描电镜（ＳＴＥＭ）与Ｘ－射线能谱仪（ＥＤＳ）对单个微晶进行了微区分析，并用介电损耗，微波光导等方法研究了此类乳剂微晶的结构与性能的关系。结果表明：严格控制微晶成核、成熟、生长三个阶段的条件，可制得含六边形颗粒９２％以上的扁平溴碘化银乳剂，颗粒大小变化系数小于１２％。此外碘在微晶中的分布明显影响微晶的电性质和     

单分散高振实密度球形微米银粉的工艺研究

为了改善银粉颗粒的表面光滑度和均匀性,以硫酸亚铁铵为还原剂、AgNO3为原料和吐温65(TW65)为表面活性剂,通过液相还原法制备单分散球形微米银粉。研究了还原剂浓度、反应温度、表面活性剂用量等对银粉粒度分布的影响,并探讨了银粉的形成机制。研究确定较优工艺条件为反应温度为室温,还原剂与AgNO3的摩尔比为6∶1,TW65与AgNO3的质量比为5%。在较优工艺条件下制备出了粒度均匀单分散球形银粉,平均粒径为1.18μm左右,松装密度为2.4g/cm3,振实密度为4.9g/cm3,回收率达99.56%,基本达到了太阳能电池用银粉要求。     

用水氯镁石制备单分散六角片状氢氧化镁

用水氯镁石为原料,氢氧化钠为沉淀剂,常压下合成氢氧化镁,在不加入任何改性剂的条件下,对反应后的料浆进行水热处理,并用扫描电镜（SEM）、X射线衍射仪（XRD）和激光粒度仪表征所得产品的形貌、结构及粒度分布,主要考察了水热反应时间和水热反应温度对氢氧化镁产品的影响.结果表明：在120℃水热4h条件下的过滤速率是未经水热条...     

Optical performances of mono‐dispersed spherical YAG:Ce3+ nano‐phosphor achieved by one‐pot synthesis

Mono‐dispersed spherical YAG:Ce³⁺ nano‐phosphors were successfully synthesized by a one‐pot glycol‐thermal process using aluminum isopropoxide, yttrium, and cerium acetate hydrates as the precursor, (1,4)‐butanediol as the solvent, ethidenediamine as the additive agent that can both control the morphology and improve the optical performances of the as‐achieved products. The as‐prepared YAG:Ce³⁺ nano‐phosphors displayed mono‐dispersed spheres of about 150 nm and an improved optical performance with a quantum yield (QY) of 41% and good photostability, indicating that they have a considerable potential to be applied in solid‐state lighting or used as coatings in other optical electronic devices.     

单分散铕掺杂氧化钇空心微球的荧光性能研究

以单分散三聚氰胺-甲醛微球为模板,通过煅烧除去模板,制备出粒径均一的铕掺杂氧化钇空心微球荧光材料. 利用扫描电子显微镜、透射电子显微镜、傅立叶变换红外光谱仪、X射线衍射仪、荧光分度计对氧化物空心微球荧光材料进行表征. 结果表明:成功地制备了铕掺杂氧化钇单分散空心微球,铕元素掺杂进入氧化钇晶体后对氧化钇晶型没有影响,随着铕元素含量的增加,晶格常数逐渐增大. 铕掺杂氧化钇空心球在613 nm处均表现出强烈的发射峰,当铕元素掺杂量为原分子数x=5%时,荧光强度最强;随着铕元素含量的增多,电荷迁移带红移,表明铕-氧键共价性逐渐减弱、离子性逐渐增强.     

CMC稳定的Ni/Fe双金属催化体系的制备及对PCB77原位脱氯降解

以羧甲基纤维素钠(CMC)作为稳定剂,优化了制备条件,在反应温度25℃,m(CMC)/m(Fe)=5以及m(Ni)/m(Fe) =0.03的条件下成功制备了CMC-Ni/Fe纳米双金属颗粒.用制得的CMC-Ni/Fe纳米双金属颗粒于30℃下降解5 mg/L的PCB77溶液48 h,当双金属颗粒用量为3 g/L时,有高达94％的PCB77被降解,而没有加入CMC的Ni/Fe双金属体系只有71％的PCB77被降解.CMC-Ni/Fe纳米双金属颗粒经XRD检测,表现出明显的单质铁特征峰,且无铁氧化物特征峰,表明制备所得的纳米颗粒中的铁单质没有被氧化.经粒度分析仪的检测,CMC-Ni-Fe双金属纳米颗粒平均粒径在23.94 nm,明显小于没有加CMC的Ni/Fe双金属颗粒粒径(100 nm).     

准单分散阳8离子型聚甲基苯乙烯胶乳粒子的制备

采用偶氮对2－脒基丙烷盐酸盐（V－50）为引发剂通过无乳化剂乳液聚合方法制备尺寸均一的阳离子聚甲基苯乙烯（PMS）胶乳粒子。详细讨论聚合条件,如引发剂浓度、单体浓度、离子强度、搅拌速度对聚合速率、粒子尺寸及分布的影响。最终获得制备单分散无乳化剂阳离子型聚甲基苯乙烯乳粒子的方法。     

High-gravity-assisted synthesis of aqueous nanodispersions of organic fluorescent dyes for counterfeit labeling

Organic fluorescent dyes have attracted wide interest because of their high photoluminescence quantum efficiencies. However, there are several application limitations arising from their hydrophobicity, poor dispersity and large particle sizes. These problems can be improved by preparing nanoparticles with a small size. Herein, we present a continuous approach to efficiently prepare an aqueous nanodispersion of water-insoluble organic fluorescent dye Nile red (NR) with monodispersed and uniform nanoparticles (35 nm) by high-gravity antisolvent precipitation in a rotating packed bed (RPB). In contrast, NR nanodispersions prepared using a traditional batch stirred tank (ST) had a broad size distribution (20–150 nm). Due to its small size effect and good dispersity in water, the RPB nanodispersion displayed significantly increased saturation solubility and much stronger fluorescent intensity compared to raw NR, and was obviously superior to the ST counterpart. Furthermore, NR nanodispersions were mixed with ink to draw fluorescent patterns on paper for counterfeit labeling.     

单分散Ni球制备及Ni／NiO的磁性研究

使用微波辅助Poly方法制备了直径范围在100nm～180nm单分散的Ni球，用磁力显微镜（MFM）测其磁结构。进一步对Ni球表面氧化获得了高度球化的NicoreNiOshell结构，采用XRD，TEM，XPS和EDAX对其进行了测量分析，并用VSM和SQUID进一步讨论了铁磁／反铁磁的界面耦合效应。同时，估算了磁性交换偏置耦合场与颗粒尺寸的关系。     

均分散胶体的研究——Ⅶ草酸氧钛锶均分散颗粒的制备条件与工艺

研究了草酸氧钛锶均分散胶体的形成条件,对影响颗粒形貌的因素进行了探讨,找出了形成均分散胶体的条件范围并优选出较佳制备条件。对于这种均分散胶体的工业化生产工艺进行了模拟。