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1.
Peng Li Haibin Jiang Ariel Barr Zhichu Ren Rui Gao Hua Wang Weiwei Fan Meifang Zhu Guiyin Xu Ju Li 《Advanced functional materials》2021,31(51):2105845
Mercury, lead, and cadmium are among the most toxic and carcinogenic heavy metal ions (HMIs), posing serious threats to the sustainability of aquatic ecosystems and public health. There is an urgent need to remove these ions from water by a cheap but green process. Traditional methods have insufficient removal efficiency and reusability. Structurally robust, large surface-area adsorbents functionalized with high-selectivity affinity to HMIs are attractive filter materials. Here, an adsorbent prepared by vulcanization of polyacrylonitrile (PAN), a nitrogen-rich polymer, is reported, giving rise to PAN-S nanoparticles with cyclic π-conjugated backbone and electronic conductivity. PAN-S can be coated on ultra-robust melamine (ML) foam by simple dipping and drying. In agreement with hard/soft acid/base theory, N- and S-containing soft Lewis bases have strong binding to Hg2+, Pb2+, Cu2+, and Cd2+, with extraordinary capture efficiency and performance stability. Furthermore, the used filters, when collected and electrochemically biased in a recycling bath, can release the HMIs into the bath and electrodeposit on the counter-electrode as metallic Hg0, Pb0, Cu0, and Cd0, and the PAN-S@ML filter can then be reused at least 6 times as new. The electronically conductive PAN-S@ML filter can be fabricated cheaply and holds promise for scale-up applications. 相似文献
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《能源学会志》2020,93(4):1449-1459
Oil shortage and awareness of environment pollution leads to the extensive use of biodegradable starch-based materials against synthetic plastics. The accumulated wastes of these plastics takes more time for natural recycling and the process is complex. Therefore the best option of recycling would be to convert these polymers into a source of energy by pyrolysis. So to understand the pyrolytic behaviour, kinetics of such waste plastics is studied by using thermogravimetric analysis at different heating rates of 10 °C, 20 °C, 40 °C, 60 °C, 80 °C and 100 °C in nitrogen atmosphere followed by characterization of the pyrolysis products. The kinetic parameters are obtained for two major stages of decomposition in two different temperature ranges 250–620 °C and 620–855 °C by iso-conversional methods such as Friedman, Coats-Redfern, FWO and Kissinger methods. The regression coefficient data (>0.9) of kinetic plots obtained for different methods best fits to the kinetic equation. Empirical formula of the compound is determined by ultimate analysis is CH2.214S0.0018O0.6910. Proximate analysis gives the idea of volatile component which is74.33%. The range of average value of activation energy is 120.7013 kJ/mol to 140.7707 kJ/mol for the biodegradable plastic plate with different conversion (0.1–0.6) and (0.1–0.3) respectively at two different temperatures. The pyrolysis products obtained using a semi-batch reactor are characterized to know their composition and other properties. 相似文献
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随着公路系统的新陈代谢,大量废弃物给城市的资源与环境协调发展带来了巨大压力,以沥青路面再生技术为路径的公路废弃物资源化符合循环经济的理念,是我国公路建设迈向生态文明的必然选择。通过 ANP-SWOT 对上海公路废弃物资源化发展战略进行实证分析,发现当前形势下其优势和机遇较为明显,确定以 SO 策略为核心的推广战略为最佳选择,并提出一系列配套发展策略,为推动上海公路废弃物资源化提供参考。 相似文献
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多功能杀菌剂的合成及其性能研究 总被引:7,自引:1,他引:6
在现有季铵盐类杀菌灭藻剂上增加一个脂键,连接一个有机酸基团,合成一种兼具阻垢缓蚀功能的新型工业水处理用杀菌灭藻剂(多功能杀菌剂),经一系列评价实验表明:新型杀菌剂是较理想的杀菌剂,在较低浓度下,对硫酸盐还原菌(SRB)及腐生菌(TGB)均有很好的杀灭效果,优于1227杀菌剂,同时还具有较好的缓蚀阻垢效果。 相似文献
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通过氟塑料-石墨板式换热器在化纤生产中高温强腐蚀换热工况中的实际应用,并与常规换热器的使用情况的对比分析,阐述了这种新型换热设备的特点。 相似文献
8.
A critical review of the current status of tungsten resources, of state-of-the-art processing technology and of product development
in India vis-a-vis the world scenario is presented. An attempt has been made to identify technology gap areas requiring attention. 相似文献
9.
This study, which is based on responses from over 300 individuals in England and Wales, explores how a willingness to use a water-recycling system of specific configuration varies against a number of factors which are linked to system design, system scale, system context, and water-conservation behaviour. Findings show that there is broad willingness to accept in-house water recycling provided that public health is not compromised. 相似文献
10.
利用废旧塑料生产阻燃建筑装饰材料探讨 总被引:4,自引:0,他引:4
本文介绍了一种综合利用废旧热塑性塑料和锯末粉通过加入阻燃剂改性 ,生产防火阻燃型建筑装饰材料的方法。所生产的产品 ,其阻燃性能均达到国家标准 (GB5464 - 85)中规定的不燃性材料的要求。 相似文献