全文获取类型
收费全文 | 4192篇 |
免费 | 533篇 |
国内免费 | 279篇 |
专业分类
电工技术 | 439篇 |
综合类 | 168篇 |
化学工业 | 898篇 |
金属工艺 | 787篇 |
机械仪表 | 48篇 |
建筑科学 | 62篇 |
矿业工程 | 192篇 |
能源动力 | 423篇 |
轻工业 | 17篇 |
水利工程 | 7篇 |
石油天然气 | 96篇 |
武器工业 | 12篇 |
无线电 | 353篇 |
一般工业技术 | 682篇 |
冶金工业 | 738篇 |
原子能技术 | 43篇 |
自动化技术 | 39篇 |
出版年
2024年 | 21篇 |
2023年 | 73篇 |
2022年 | 141篇 |
2021年 | 184篇 |
2020年 | 228篇 |
2019年 | 164篇 |
2018年 | 143篇 |
2017年 | 170篇 |
2016年 | 168篇 |
2015年 | 147篇 |
2014年 | 230篇 |
2013年 | 204篇 |
2012年 | 287篇 |
2011年 | 350篇 |
2010年 | 228篇 |
2009年 | 213篇 |
2008年 | 209篇 |
2007年 | 328篇 |
2006年 | 278篇 |
2005年 | 231篇 |
2004年 | 202篇 |
2003年 | 169篇 |
2002年 | 142篇 |
2001年 | 107篇 |
2000年 | 106篇 |
1999年 | 79篇 |
1998年 | 40篇 |
1997年 | 38篇 |
1996年 | 35篇 |
1995年 | 23篇 |
1994年 | 20篇 |
1993年 | 8篇 |
1992年 | 11篇 |
1991年 | 6篇 |
1990年 | 9篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1951年 | 4篇 |
排序方式: 共有5004条查询结果,搜索用时 4 毫秒
1.
Shaofeng Wang Jianwei Xu Yuejin Tong Lin Wang Chaobin He 《Polymer International》2005,54(9):1268-1274
A novel cholesterol‐imprinted polymer (CMIP‐H) was prepared by a hybrid method of covalent imprinting and non‐covalent imprinting. This approach involves the copolymerization of a template‐containing monomer, cholesteryl 2‐hydroxyethyl methacrylate carbonate, and a cross‐linker, followed by hydrolysis to afford a flexible guest‐binding site accompanied with the easy and efficient removal of a ‘sacrificial spacer’. The effect of solvent on the binding capacity of CMIP‐H towards cholesterol was studied, indicating that a good binding capacity towards cholesterol could be achieved in a less‐polar solvent. The binding experiments of CMIP‐H towards a series of structural analogues of cholesterol, including cholesterol acetate, progesterone and stigmasterol, were carried out in hexane. The results showed that CMIP‐H almost did not bind cholesterol acetate at all because the hydrogen‐bonding site is blocked. It exhibited a similar binding towards both cholesterol and stigmasterol, but much higher binding towards progesterone. Copyright © 2005 Society of Chemical Industry 相似文献
2.
3.
叙述了从铅阳极泥回收金银后的渣料中综合回收有价金属的生产实践。根据渣料性质,将火法和湿法工艺相互结合,使渣料中的锑、铋、金、银、铅、铜得以较彻底的分离和回收。 相似文献
4.
Lanthanum doped nickel and YSZ composite anode (LaNi–YSZ) exhibited a greatly reduced polarization resistance and high performance for electrochemical oxidation of hydrogen and methane, which resulted from a fine anode structure with a high dispersion of nickel catalyst and a high catalytic activity towards methane. 相似文献
5.
胜利油田污水储罐腐蚀防护方法评价 总被引:1,自引:0,他引:1
对胜利油田纯粱采油厂A3钢制生产污水(水温约60℃)储罐使用寿命过低的原因进行了实验考察。水质分析数据表明氯离子浓度高(45-48gm)是污水腐蚀性强的主要因素。A3钢在60℃污水中的腐蚀速率,由极化曲线数据计算的值大大高于失重法测定值,敞开系统中失重法测定值又高于密闭系统中测定值,挂片上出现蚀孔,说明储罐中A3钢发生了氧存在下氟离子引起的局部腐蚀(孔蚀)。元素分析结果表明.储罐阴极保护所用的牺牲阳极铝材含铁等元素量超标。牺牲阳极密封不良,在实验污水中7天后电流效率仅为2.92%,失去阴极保护能力。处于实验污水环境中的有涂层保护的A3钢.14天后出现腐蚀极化电流,表明涂层已失去完整性。要提高该采油厂及胜利油田其他采油厂污水储罐的使用寿命,必须改用合格的牺牲阳极和保护涂层材料。图3表2参7。 相似文献
6.
Anodic oxidation of mecoprop herbicide at lead dioxide 总被引:1,自引:0,他引:1
The electrochemical oxidation of an aqueous solution containing mecoprop (2-(2-methyl-4-chlorophenoxy)propionic acid) has
been studied at PbO2 anodes by cyclic voltammetry and bulk electrolysis. The influence of current density, hydrodynamic conditions, temperature
and pH on the degradation rate and current efficiency is reported. The results obtained show that the use of PbO2 leads to total mineralization of mecoprop due to the production of oxidant hydroxyl radical electrogenerated from water discharge.
The current efficiency for the electro-oxidation of mecoprop is enhanced by low current density, high recycle flow-rates and
high temperature. In contrast, the pH effect was not significant. It has also been observed that mecoprop decay kinetics follows
a pseudo-first-order reaction and the rate constant increases with rising current density. 相似文献
7.
Iron(III) oxide tablets were electrolytically reduced to iron in molten sodium hydroxide at 530 °C and recovered to produce
iron with 2 wt.% oxygen suitable for re-melting. The cell was operated at 1.7 V and an inert nickel anode was used. The thermodynamics
and mechanism of the process was also investigated. By controlling the activity of sodium oxide in the melt, the cell could
be operated below the decomposition voltage of the electrolyte with the net sequence of events being the ionization of oxygen,
its subsequent transport to the anode and discharge leaving behind iron at the cathode. A reduction time of 1 h was achieved
for a 1 g oxide tablet (close to the theoretical reduction time predicted by Faraday’s laws) at a current density of 520 mA cm−2 with iron phase yields of ∼90 wt.%. The energy consumption was 2.8 kWh kg−1. 相似文献
8.
从铅阳极泥中回收铋的火法工艺实践 总被引:4,自引:2,他引:2
主要论述了从铅阳极泥中回收铋的全火法工艺流程改造与实践,并取得了预期的效果。 相似文献
9.
10.
含RE铝阳极中析出相的电化学行为研究 总被引:7,自引:2,他引:5
用电子探针和能谱分析技术,观察了Al-5Zn-0.05In-0.1Sn-1Mg-0.3RE阳极中主要析出相的成分,并熔炼了析出相合金.电位测量和腐蚀后铝阳极表面的电子探针面扫描分析表明:富Sn相为阳极相,富Fe相、富RE相为阴极相;Fe相是铝阳极自腐蚀微电池中的主要阴极相,温度对析出相的电化学行为有影响. 相似文献