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排序方式: 共有207条查询结果,搜索用时 328 毫秒
1.
铁锈渣对氧气生产的危害 总被引:2,自引:0,他引:2
介绍铁锈、铁锈渣对氧气生产的危害 ,分析一起因铁锈、铁锈渣引起的氧压机着火而殃及氧气囊燃烧的事故 ,针对分析的原因提出预防措施。 相似文献
2.
Taxonomy for protective ability of rust layer using its composition formed on weathering steel bridge 总被引:2,自引:0,他引:2
For a quantitative evaluation of the protectiveness of a rust layer formed on a weathering steel bridge, the relationship between the corrosion rate of the bridge and the composition of the rust layers formed on the girders was first investigated. These corrosion rates were clearly classified by the protective ability index (PAI) of α/γ∗ and (β + s)/γ∗, where α, γ∗, β and s are the mass ratio of crystalline α-FeOOH, the total of γ-FeOOH, β-FeOOH and the spinel-type iron oxide (mainly Fe3O4), β-FeOOH and spinel-type iron oxide, analyzed by XRD, respectively. The inequality of the former index α/γ∗ > 1 expressed the protectiveness criterion of the rust layer, while that of the latter index, (β + s)/γ∗< 0.5 or > 0.5, classified the corrosion rate of the non-protective rust layer. The PAI is useful for a quantitative evaluation of the protectiveness of a rust layer formed on a weathering steel bridge and is an important item for the corrosion assessment of the bridge. 相似文献
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4.
The effects of water pollution on the immersion corrosion of mild and low alloy steels 总被引:1,自引:0,他引:1
R.E. Melchers 《Corrosion Science》2007,49(8):3149-3167
The short-term immersion corrosion of mild and low alloy steels in seawaters is known to be proportional to the concentration of dissolved oxygen (DO) in the bulk water. Longer-term corrosion is a function of the activity of sulphate-reducing bacteria and is influenced by the concentration of nutrients in the bulk water. These influences are examined in more detail for the corrosion of steels in the brackish waters of the River Thames and for several immersion corrosion sites on the Eastern Australian seaboard and in the North Sea. The published data sources were supplemented with plausible assumptions about environmental conditions. New interpretations of the data are provided based on the previously published model for immersion corrosion. For waters with negligible salinity and sulphate levels early corrosion loss was shown to depend on the dissolved oxygen content of the waters, and later corrosion loss was a direct function of nitrogenous nutrient (pollution) levels. This also applies to longer-term corrosion. 相似文献
5.
Indoor weight loss of steel, chloride, sulphur compounds and dust deposition rate were determined in six storehouses having different characteristics. Relative humidity and temperature were determined in three storehouses. A model for indoor corrosion of steel depending on time of exposure and deposition of dust, sulphur compounds and chlorides is proposed. Dust deposition plays an important role indoors. The position of the sample has also a significant influence on corrosion. Indoor corrosion aggressivity in Cuban storehouses ranges in classification IC3 and IC4 according to the new ISO proposal of indoor aggressivity.A report about the presence of localized corrosion indoors (filiform like) using a special designed sample is made. 相似文献
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Atmospheric corrosion of steel proceeds under thin electrolyte film formed by rain and dew condensation followed by wet and dry cycles. It is said that rust layer formed on steel as a result of atmospheric corrosion strongly affects the corrosion behavior of steel. The effect of environmental corrosiveness on the formation process and structure of the rust layer is, however, not clear to date. In this study, in situ observation of the rusting process of a carbon steel covered with a thin film of Na2SO4 or NaCl solution was performed under a wet/dry repeating condition by X-ray diffraction spectroscopy with white X-rays obtained from synchrotron radiation. The present in situ experiments successfully detected initial process of the rust formation. In the early cycles, the rust constituents were not well crystallized yet, but the presence of Fe(OH)2 and Fe(OH)3 was confirmed. In the subsequent cycles, two different solutions resulted in difference in preferential phase of the rust constituents. α-FeOOH was preferentially formed in the case of the Na2SO4 solution film, whereas β-FeOOH appeared only under the NaCl solution film. 相似文献
8.
本文对0Cr13-SA-387Gr11Cl复合板复层产生锈迹、裂纹的原因进行了分析探讨,并提出了预防措施。 相似文献
9.
To clarify the role of phosphate in the formation of corrosion products, the transformation of GRI(Cl−) with the addition of phosphate was characterized through XRD, TEM, and solution analysis. Electrochemical analysis showed that the transformation of GRI(Cl−) was delayed and the size of the final products, i.e., γ-FeOOH was reduced in the phosphate added case. X-ray absorption spectroscopy indicated that the neighboring Fe–Fe coordination number of FeO6 octahedral unit in γ-FeOOH was decreased. These effects of phosphate are attributed to its adsorption on GRI(Cl−) and nucleated γ-FeOOH that prevented particle growth during oxidation process. 相似文献
10.
Role of zinc compounds on the formation, morphology, and adsorption characteristics of β-FeOOH rusts
To simulate the corrosion of galvanized steel in marine zone, β-FeOOH was prepared by aging the FeCl3 solutions containing ZnCl2 and zinc rusts such as ZnO and zinc hydroxychloride (Zn5(OH)8Cl2·H2O:ZHC). Adding ZnCl2, ZnO, and ZHC inhibited the crystallization and particle growth of β-FeOOH and the inhibitory effect was in order of ZHC ≈ ZnO > ZnCl2. The adsorption of H2O and CO2 was suppressed by adding ZnCl2, ZnO, and ZHC. These results imply that the rust formed on galvanized steel in marine environment is more compact, amorphous, and hydrophobic in nature which may lead to improve the corrosion resistance. 相似文献