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301.
Loose-abrasive machining with cerium oxide (ceria) slurry is traditionally employed for finishing glass. However, the use of slurries can have a detrimental impact on the environment. Fixed-abrasive machining has received attention as an alternative technology; however, conventional fixed-abrasive tools are inefficient. In this study, spiral-structured pads with fixed-abrasive layers and abrasive holding layers are introduced to increase the quality and efficiency of fixed-abrasive tools. The finishing experiments revealed a much higher finishing efficiency and good surface quality compared to those obtained in conventional polishing with ceria slurry. 相似文献
302.
303.
Kohjiro Hara Yasuhiro Tachibana Yasuyo Ohga Akira Shinpo Sadaharu Suga Kazuhiro Sayama Hideki Sugihara Hironori Arakawa 《Solar Energy Materials & Solar Cells》2003,77(1):89-103
We have developed dye-sensitized nanocrystalline TiO2 solar cells (DSSCs) based on novel coumarin-dye photosensitizers. The absorption spectra of these novel dyes are red-shifted remarkably in the visible region relative to the spectrum of C343, a conventional coumarin dye. Introduction of a methine unit (–CH=CH–) connecting the cyano (–CN) and carboxyl (–COOH) groups into the coumarin framework expanded the π-conjugation in the dye and thus resulted in a wide absorption in the visible region. These novel dyes performed as efficient photosensitizers for DSSCs. A DSSC based on 2-cyano-5-(1,1,6,6-tetramethyl-10-oxo-2,3,5,6-tetrahydro-1H,4H,10H-11-oxa-3a-aza-benzo[de]anthracen-9-yl)-penta-2,4-dienoic acid (NKX-2311), produced a 6.0% solar energy-to-electricity conversion efficiency (η), the highest performance among DSSCs based on organic-dye photosensitizers, under AM 1.5 irradiation (100 mW cm–2) with a short-circuit current density (Jsc) of 14.0 mA cm–2, an open-circuit voltage (Voc) of 0.60 V, and a fill factor of 0.71. Our results suggests that the structure of NKX-2311 whose carboxyl group is directly connected to the –CH=CH– unit, is advantageous for effective electron injection from the dye into the conduction band of TiO2. In addition, the cyano group, owing to its strong electron-withdrawing ability, might play an important role in electron injection in addition to a red shift in the absorption region. On a long-term stability test under continuous irradiation with white light (80 mW cm–2), stable performance was attained with a solar cell based on the NKX-2311 dye with a turnover number of 2.6×107 per one molecule. 相似文献
304.
Different types of novel xanthates containing a vinyl ether moiety, S-benzyl O-2-(vinyloxy)ethyl carbonodithioate (Xanthate 1) and S-1-(ethoxycarbonyl)ethyl O-2-(vinyloxy)ethyl carbonodithioate (Xanthate 2) were synthesized. In particular, the Xanthate 2 enabled to design polyvinyl alcohol (PVA) stereoblock copolymer via the combination of living cationic vinyl polymerization and RAFT/MADIX polymerization. For cationic polymerization of isobutyl vinyl ether (IBVE) and tert-butyl vinyl ether (TBVE), the polymerizations were conducted under Xanthate 1-HCl adduct/SnCl4 and Xanthate 1 or 2-CF3COOH adduct/EtAlCl2 initiating system in the presence of ethyl acetate. Both systems proceeded in living polymerization fashion because the calculated Mn of both poly(IBVE) and poly(TBVE) matches with the Mn polymerized assuming that one polymer chain is formed per one molecule of the Xanthate 1 or 2. The resulting poly(TBVE) had a high number average α-end functionality as determined by MALDI-TOF-MS spectrometry. Xanthate 2 is more efficient for the following RAFT/MADIX polymerization of vinyl acetate (VAc). The RAFT/MADIX polymerization of vinyl acetate (VAc) using azobis(isobutyronitrile) (AIBN) at 60 °C was conducted using either poly(IBVE) or poly(TBVE) macro-CTA. The poly(TBVE) macro-CTAs synthesized from the Xanthate 2 were able to polymerize VAc smoothly via RAFT/MADIX polymerization, to prepare well-defined diblock copolymer, poly(TBVE)-b-poly(VAc). The resulting block copolymer was then hydrolyzed using KOH in methanol and followed by acid hydrolysis using HBr gas bubbling. The resulting polymer is inherently stereoblock like copolymer, isotactic rich PVA-b-atactic PVA (iPVA-b-aPVA). From the DSC measurement, the iPVA-b-aPVA has one glass transition at 69.5 °C and two melting points according to iPVA and aPVA at 237.9 and 198.1 °C, respectively. Thus, it can be suggested that the obtained PVA has two different geometries by the combination of living cationic polymerization and RAFT/MADIX polymerization. 相似文献
305.
Tomohiko Tagashira Tominari Choshi Satoshi Hibino Jun Kamishikiryou Narumi Sugihara 《Journal of food science》2012,77(10):H208-H215
Abstract: The cellular accumulation of individual catechins was measured as an index of intestinal absorption to clarify the interactions among catechins. The cellular accumulation of (?)‐epicatechin (EC) increased in the presence of other catechins. The ability of gallate catechin such as (?)‐epigallocatechin gallate (EGCG) and (?)‐epicatechin gallate (ECG) to increase the cellular accumulation of EC was greater than that of nongallate catechins. Gallic acid octyl ester (GAO) also increased the cellular accumulation of EC by 426% as compared with that in untreated cells. Conversely, the cellular accumulation of ECG was not influenced by other catechins, but it increased by 54% in the presence of GAO. Experiments using GAO derivatives indicated that the gallate moiety required the presence of a catechol group and a neighboring carbonyl group, whereas the pyrogallol moiety, without a neighboring carbonyl group, required 3 hydroxyl groups to increase the cellular accumulation of EC. Furthermore, gallate esters required long carbon chains to increase the same. The experiment using EGCG, GAO, or their derivatives indicated that the ability of gallate or pyrogallol moiety to increase the cellular accumulation of EC was restricted by their hydrophobicity. These results suggest that the co‐administration of foods containing functional materials such as gallate or pyrogallol moieties, increases the intestinal absorption of catechin. Practical Application: The cellular accumulation of (?)‐epicatechin increased by the gallate or pyrogallol moiety in catechin structure. The interaction among catechins appeared to affect intestinal absorption of catechin. The bioavailability of catechin may be improved by co‐administration of functional foods. 相似文献
306.
Sugihara F Inoue N Kuwamori M Taniguchi M 《Journal of Bioscience and Bioengineering》2012,113(2):202-203
Plasma levels of prolyl-hydroxyproline (Pro-Hyp) and hydroxyprolyl-glycine (Hyp-Gly) in healthy volunteers (n=5) after ingestion of collagen hydrolysate were estimated by liquid chromatography-tandem mass spectrometry. The ratio of Hyp-Gly to Pro-Hyp was distributed in the range of 0.063-0.221. This is a first report for quantification of food-derived Hyp-Gly in human plasma. 相似文献
307.
H. Kitano M. Murakami Y. Kawata C. Egami O. Sugihara N. Okamoto M. Tsuchimori† & O. Watanabe† 《Journal of microscopy》2001,202(1):162-171
We have developed a non-optically probing near-field microscope with illumination of total internal reflection. Because the illumination light does not pass through the specimens, it is possible to observe thick specimens or highly absorptive materials. It reduces the background noise because the decay length of the evanescent wave is a few hundred nanometres. We found that although in the total internal reflection illumination system the light passed through the photosensitive film and illuminated the specimen, it did not affect the photosensitive film severely and did not limit the resolution. The imaging properties of reflection illumination and transmission illumination are analysed using a finite-differential time domain method. 相似文献
308.
Yomi Watanabe Yuji Shimada Akio Sugihara Hideo Noda Hideki Fukuda Yoshio Tominaga 《Journal of the American Oil Chemists' Society》2000,77(4):355-360
Candida antarctica lipase is inactivated in a mixture of vegetable oil and more than 1∶2 molar equivalent of methanol against the total fatty
acids. We have revealed that the inactivation was eliminated by three successive additions of 1∶3 molar equivalent of methanol
and have developed a three-step methanolysis by which over 95% of the oil triacylglycerols (TAG) were converted to their corresponding
methyl esters (ME). In this study, the lipase was not inactivated even though 2∶3 molar equivalent of methanol was present
in a mixture of acylglycerols (AG) and 33% ME (AG/ME33). This finding led to a two-step methanolysis of the oil TAG: The first-step
was conducted at 30°C for 12 h with shaking in a mixture of the oil, 1∶3 molar equivalent of methanol, and 4% immobilized
lipase; the second-step reaction was done for 24 h after adding 2∶3 molar equivalent of methanol (36 h in total). The two-step
methanolysis achieved more than 95% of conversion. When two-step reaction was repeated by transferring the immobilized lipase
to a fresh substrate mixture, the enzyme could be used 70 cycles (105 d) without any decrease in the conversion. From the
viewpoint of the industrial production of biodiesel fuel production, the two-step reaction was conducted using a reactor with
impeller. However, the enzyme carrier was easily destroyed, and the lipase could be used only several times. Thus, we attempted
flow reaction using a column packed with immobilized Candida lipase. Because the lipase packed in the column was drastically inactivated by feeding a mixture of AG/ME33 and 2∶3 molar
equivalent of methanol, three-step flow reaction was performed using three columns packed with 3.0 g immobilized lipase. A
mixture of vegetable oil and 1∶3 molar equivalent of methanol was fed into the first column at a constant flow rate of 6.0
mL/h. The eluate and 1∶3 molar equivalent of methanol were mixed and then fed into the second column at the same flow rate.
The final step reaction was done by feeding a mixture of eluate from the second column and 1∶3 molar equivalent of methanol
at the same flow rate. The ME content in the final-step eluate reached 93%, and the lipase could be used for 100 d without
any decrease in the conversion. 相似文献
309.
This paper presents a theoretical consideration on the possibility of subsynchronous resonance (SSR) in longitudinal power systems. Shunt capacitors are used for reactive power compensation in our country, but series capacitors are not used in general. The possibility of SSR is therefore small. However, if power transmission increases, and accordingly, if shunt compensation increases in amount, there is no guarantee that SSR will never occur. First, we investigate network impedance viewed from a generator. Its resonance frequencies become lower with increasing transmission power. One of them gets subsynchronous if the power exceeds a certain value. In this area, there is some possibility of SSR, which is confirmed with the damping property of the generator. The admittance matrix of the load buses is singular at the resonance frequencies. Their number is equal to the dimension of the matrix. The frequencies are common to all generators but not limited to one particular generator. One of them becomes equal to 60 Hz as we increase transmission power. We regard this power as a limit for SSR. However, steady‐state stability limit is lower than this limit, and steady operation is not possible at the limit. Therefore, it is impossible to enter the area of SSR. Thus, we conclude that SSR does not occur in shunt compensated systems. However, this property is easily lost if some series compensation is introduced. © 1999 Scripta Technica, Electr Eng Jpn, 130(3): 30–38, 2000 相似文献
310.
Hirofumi Akagi Kenji Takahashi Toshiaki Kobayashi Hiroaki Sugihara Takaaki Kai 《Electrical Engineering in Japan》2000,133(1):31-42
Over the last five to ten years, significant progress has been made in high‐power semiconductor devices and in their practical applications to power systems. This comes not only from sophisticated semiconductor technology but also from the demand for a higher degree of frequency and voltage stability, and for greater reliability in power systems. This paper deals with an adjustable speed rotary condenser capable of not only reactive power control but also active power control based on a flywheel effect of the rotor. The behavior of a power system consisting of the adjustable speed rotary condenser, a synchronous generator, and a transmission line is subjected to a set of nonlinear differential equations. The set of nonlinear equations can be linearized by limiting attention to small perturbations around a reference state, thus leading to the so‐called Heffron–Phillips model of the power system. The Heffron–Phillips model derived is effective in analyzing effects of the adjustable speed rotary condenser on power system stabilization. The validity of the analysis is confirmed by computer simulation based on EMTDC. Finally, it is discussed how well power system stabilization is achieved by the rotary condenser. As a result, the rotary condenser has the function of decoupling reactive power control from active power control, thus producing a good effect on power system stabilization which would not be achieved by a conventional inverter‐based static var compensator. © 2000 Scripta Technica, Electr Eng Jpn, 133(1): 31–42, 2000 相似文献