Topology optimization of fluid problems using genetic algorithm assisted by the Kriging model

A non‐gradient‐based approach for topology optimization using a genetic algorithm is proposed in this paper. The genetic algorithm used in this paper is assisted by the Kriging surrogate model to reduce computational cost required for function evaluation. To validate the non‐gradient‐based topology optimization method in flow problems, this research focuses on two single‐objective optimization problems, where the objective functions are to minimize pressure loss and to maximize heat transfer of flow channels, and one multi‐objective optimization problem, which combines earlier two single‐objective optimization problems. The shape of flow channels is represented by the level set function. The pressure loss and the heat transfer performance of the channels are evaluated by the Building‐Cube Method code, which is a Cartesian‐mesh CFD solver. The proposed method resulted in an agreement with previous study in the single‐objective problems in its topology and achieved global exploration of non‐dominated solutions in the multi‐objective problems. © 2016 The Authors International Journal for Numerical Methods in Engineering Published by John Wiley & Sons Ltd     

Soft-X-ray emission spectroscopy based on TEM-Toward a total electronic structure analysis

The construction and basic performances of wavelength-dispersive soft-X-ray emission spectroscopy (SXES) devices attached to a transmission electron microscope were presented. An energy resolution of 0.23 eV was obtained at the aluminum L-emission energy. A Cu L-emission spectrum obtained showed four L-emission lines of Lalpha, Lbeta, Ll and Leta. Angle-resolved measurements of boron K-emission spectra of hexagonal-BN (h-BN) were presented. It clearly showed anisotropic emission intensity of the transition from pi-bonding state to 1s core hole. B K-emission spectra of h- and cubic-BNs showed a difference in energy positions of sigma-bonding peaks. An electron energy-loss spectrum of B K-edge and a B K-emission spectrum of cubic-BN were compared with a result of a LDA band calculation. It showed that high symmetry points in the band diagram appeared as peak and/or shoulder structures in those spectra. Interband transitions appeared in the imaginary part of the dielectric function of cubic-BN experimentally obtained were assigned in the band diagram. These results demonstrated a method to analyze the entire electronic structure of materials in the nanoscale using high energy-resolution spectroscopy methods based on transmission electron microscopy.     

Fluorometric analysis on physicochemical properties of phosphatidylcholine-based W/O microemulsion involved with enzymatic reactivity in phospholipid hydrolysis

Interfacial tension and fluorometric analysis were employed for the investigation of the interfacial local fluidity and the hydrophobicity of the micro water pool in the PC-based water-in-oil (W/O) microemulsion. These microenvironment properties strongly influenced the phospholipase A₂ reactivity for phospholipid hydrolysis in the W/O microemulsion. The organic phase was prepared by mixing of isooctane as a main solvent and 1-butanol as a co-solvent. The critical micelle concentration (CMC) was dramatically decayed from 9mM to 0.025mM by the increasing of the 1-butanol content. The local interfacial fluidity of the micro water pool was measured by using fluorescence polarity indicated by 1,6-Diphenyl-1,3,5-hexatriene-4′-trimethylammonium tosylate (TMA-DPH) and Coumarin 343 (C343). It was apparently increased with increasing the molar ratio of additive 1-butanol. In contrast, the hydrophobicity of the water pool measured by C343 was almost constant throughout the molar ratio of additive 1-butanol. Additive alcohol influenced the micro fluidity and enhanced reactivity of phospholipase A₂ in lipid hydrolysis. This work was presented at 13 ^th YABEC symposium held at Seoul, Korea, October 20–22, 2007.     

Specific surface area of aggregate and its relation to concrete drying shrinkage

This paper deals with the influence of aggregate properties on the shrinkage of concrete during drying. The drying shrinkage strains of concretes with various types of aggregates were measured and their influences on the fundamental properties of the different types of aggregates were investigated. Furthermore, the specific surface areas (SSAs) of aggregates were obtained by the BET method using both nitrogen (N₂) and water vapour (H₂O). The SSAs determined by using H₂O exhibited higher values than those by using N₂. The drying shrinkage strains of concretes increased with the H₂O SSAs of the aggregates used. Our results suggest that the SSA determined by using H₂O is an effective index for evaluating the influence of the aggregate type on the drying shrinkage of concrete.     

pH-Responsive Self-Assembly of Designer Aromatic Peptide Amphiphiles and Enzymatic Post-Modification of Assembled Structures

Supramolecular fibrous materials in biological systems play important structural and functional roles, and therefore, there is a growing interest in synthetic materials that mimic such fibrils, especially those bearing enzymatic reactivity. In this study, we investigated the self-assembly and enzymatic post-modification of short aromatic peptide amphiphiles (PAs), Fmoc-L_nQG (n = 2 or 3), which contain an LQG recognition unit for microbial transglutaminase (MTG). These aromatic PAs self-assemble into fibrous structures via π-π stacking interactions between the Fmoc groups and hydrogen bonds between the peptides. The intermolecular interactions and morphologies of the assemblies were influenced by the solution pH because of the change in the ionization states of the C-terminal carboxy group of the peptides. Moreover, MTG-catalyzed post-modification of a small fluorescent molecule bearing an amine group also showed pH dependency, where the enzymatic reaction rate was increased at higher pH, which may be because of the higher nucleophilicity of the amine group and the electrostatic interaction between MTG and the self-assembled Fmoc-L_nQG. Finally, the accumulation of the fluorescent molecule on these assembled materials was directly observed by confocal fluorescence images. Our study provides a method to accumulate functional molecules on supramolecular structures enzymatically with the morphology control.     

Atmospheric-dispersion database system that can immediately provide calculation results for various source term and meteorological conditions

ABSTRACT

We have estimated source term and analyzed processes of atmospheric dispersion against atmospheric discharge of radioactive materials due to the Fukushima Daiichi Nuclear Power Station (FDNPS) accident by atmospheric-dispersion calculation using the Worldwide version of System for Environmental Emergency Dose Information (WSPEEDI). On the basis of this experience, we developed an atmospheric-dispersion calculation method that can respond to various needs for dispersion prediction in a nuclear emergency and provide useful information for emergency-response planning. By this method, if a release point, such as a nuclear facility, is known, it is possible to immediately obtain the prediction results by applying provided source term (released radionuclides, release rate, and release period) to the database of dispersion-calculation results prepared in advance without specifying source term. With this function, it is easy to compare results by applying many kinds of source term with monitoring data, and to find out the optimum source term. By preparing a database by this calculation with past long-term meteorological data, we can immediately get dispersion-calculation results for various source term and meteorological conditions. This database is useful for pre-accident planning, such as optimization of a monitoring plan and understanding of events to be supposed in considering emergency countermeasures.     

The effect of the structural order of isotactic polypropylene containing magnetically aligned nickel particles on its electrical resistivity

The effect of the high order structure of an isotactic polypropylene (PP) composite on the resistivity of composites containing magnetically aligned Ni particles was studied. Only a small amount of particles needed to be added for the composite material to become conducting after heating while in a magnetic field. The Ni columns formed on applying the field were distorted by the formation of large PP spherulites. Changes to the crystallization process due to the addition of a nucleating agent gave rise to changes in the columnar structure, resulting in large changes in the resistivity of the composite material. Controlling the high order structure of the polymer matrix including its morphology is very important in order to be able to control the magnetically aligned Ni structure.     

Quantum Set Theory Extending the Standard Probabilistic Interpretation of Quantum Theory

The notion of equality between two observables will play many important roles in foundations of quantum theory. However, the standard probabilistic interpretation based on the conventional Born formula does not give the probability of equality between two arbitrary observables, since the Born formula gives the probability distribution only for a commuting family of observables. In this paper, quantum set theory developed by Takeuti and the present author is used to systematically extend the standard probabilistic interpretation of quantum theory to define the probability of equality between two arbitrary observables in an arbitrary state. We apply this new interpretation to quantum measurement theory, and establish a logical basis for the difference between simultaneous measurability and simultaneous determinateness.