Self-Standing Covalent Organic Framework Membranes for H2/CO2 Separation

Covalent organic frameworks (COFs) are proposed as promising candidates for engineering advanced molecular sieving membranes due to their precise pore sizes, modifiable pore environment, and superior stability. However, COFs are insoluble in common solvents and do not melt at high temperatures, which presents a great challenge for the fabrication of COF-based membranes (COFMs). Herein, for the first time, a new synthetic strategy is reported to prepare continuous and intact self-standing COFMs, including 2D N-COF membrane and 3D COF-300 membrane. Both COFMs show excellent selectivity of H₂/CO₂ mixed gas (13.8 for N-COF membrane and 11 for COF-300 membrane), and especially ultrahigh H₂ permeance (4319 GPU for N-COF membrane and 5160 GPU for COF-300 membrane), which is superior to those of COFMs reported so far. It should be noted that the overall separation performance of self-standing COFMs exceeds the Robeson upper bound. Furthermore, a theoretical study based on Grand Canonical Monte Carlo (GCMC) simulation is performed to explain the excellent separation of H₂/CO₂ through COFMs. Thus, this facile preparation method will provide a broad prospect for the development of self-standing COFMs with highly efficient H₂ purification.     

A multiplicative decomposition of Poiseuille number on rarefaction and roughness by lattice Boltzmann simulation

Poiseuille number of rarefied gas flow in channels with designed roughness is studied and a multiplicative decomposition of Poiseuille number on the effects of rarefaction and roughness is proposed. The numerical methodology is based on the mesoscopic lattice Boltzmann method. In order to eliminate the effect of compressibility, the incompressible lattice Boltzmann model is used and the periodic boundary is imposed on the inlet and outlet of the channel. The combined bounced condition is applied to simulate the velocity slip on the wall boundary. Numerical results reveal the two opposite effects that velocity gradient and friction factor near the wall increase as roughness effect increases; meanwhile, the increments of the rarefaction effect and velocity slip lead to a corresponding decrement of friction factor. An empirical relation of Poiseuille number which contains the two opposite effects and has a better physical meaning is proposed in the form of multiplicative decomposition, and then is validated by available experimental and numerical results.     

基于Ansoft仿真分析的SSN解决方案探讨

利用Ansoft公司的设计仿真工具,结合具体电路对部分电源分配系统进行了优化设计,重点研究了对SSN(同步开关噪声)的抑制。对采用传统的加退偶电容方法提高其高频特性和高阻抗电磁表面(EBG)结构应用到具体电路设计中减小同步开关噪声(SSN)进行了比较,结果证明,采用EBG结构比传统单纯加去耦电容效果更佳。     

辐射限制下有源无源协同跟踪技术

为了提高作战飞机的隐蔽性,提出了一种辐射限制下有源无源传感器目标跟踪与协同管理的方法,给出了基于辐射控制的机载多传感器系统协同跟踪方法.利用跟踪过程中目标残差范数与门限的比较结果,判断雷达开关机,用序贯和IMM(interacting multiple model)联合滤波算法对目标进行跟踪.对利用该方法的机载多传感器目标跟踪性能进行了仿真分析,仿真结果证明了该方法的合理性和有效性.     

论环境陶艺与技术

当代环境陶艺不仅仅表达艺术家自身的情感以及对社会的关注,更多的是在对传统陶瓷技艺的继承与发扬的基础上,赋予陶瓷新的价值。本文从数字技术与印刷技术对环境陶艺的影响;陶艺雕塑成型与安装;可拆卸的陶瓷壁画与装置;室外整体烧成等四方面对环境陶艺的新技术进行了阐述。     

一种快速三角形电源地平面谐振腔模型

针对等腰直角三角形平面模型效率低和精度差的问题,在双频点近似算法的基础上,提出了一种快速的Spice兼容等腰直角三角形平面谐振腔模型.与电感近似的等腰直角三角形平面模型相比,提出的模型使用最少的谐振腔基本模式与单节的高阶修正电路,不仅提高了等腰直角三角形电源地平面的仿真效率,而且改善了模型精度.仿真结果表明,电感近似模型在分类关键因子为2时,最大误差约为10%;提出的模型在分类关键因子为1.3时,最大误差约为1%,其仿真时间仅为电感近似模型的26%,验证了该模型在提高等腰直角三角形电源地平面的仿真效率和改善模型精度上的有效性.     

混凝-活性炭-超滤工艺处理洪水的试验研究

针对洪水的水质特征,研究了混凝、活性炭和超滤膜对洪水中浊度、有机物和细菌等主要污染物的去除效果,确定了混凝-活性炭-超滤组合处理工艺.试验结果表明,该组合工艺稳定、可靠.运行期间对浊度、有机物去除效果较好,对CODMn的去除率为75%,对UV254的去除率为71%,系统出水中未检出大肠杆菌,浊度基本被完全去除,主要水质指标达到国家饮用水卫生标准.     

洪灾综合风险结构与综合评价方法(Ⅱ)——微观结构

从模型分析的角度,分析了由洪水风险、防洪工程风险、防洪投资风险、洪泛区风险、洪水生态环境风险和防洪决策风险6个方面所组成的洪灾综合风险特征,构建以洪水为中心的洪灾风险链的微观结构.应用概率论方法,给出了相应的量化概念模型,并提出了具体的研究路线.最后,对洪灾综合风险的结构进行了系统分析,为深入探讨洪灾综合风险分析与管理的具体方法、模型及防洪对策提供了总体研究框架与思路.     

水利工程经济效益风险分析研究

采用层次分析方法，将水利工程经济效益系统分为防洪，发电，灌溉效益子系统，辨识出风险因子，建立了基于最大熵原理（准则）的经济效益风险分析模型，并给出求解方法。本文对总系统经济效益风险进行分析考虑了两种思路：一是对辨识出的风险因子进行概率分析，直接由最大熵模型得出总效益指标的密度函数；二是按照“风险树”的思路，先分析子系统效益的风险特性，再进行风险组合，从而考察总效益的风险性，最后用实例验证了该模型的可行性和实用性。     

变电所微机保护与监控系统

研究了如何利用工业控制微机 IPC 实现对变电所的保护与监控 ,较详细地介绍监控系统的结构组成特点 .实现了微机监控与全数字继电保护技术的有机结合 .运行表明 ,可增强变电所的控制保护功能 ,提高自动化程度 ,同时也提出了实际运行中存在的下位微机在恶劣环境中抗干扰等问题