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11.
Shoji Watanabe Kyoichi Suga Tsutomu Fujita Nobuo Takasaka 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1974,24(11):639-643
Various terpene alcohols were prepared from isoprene oligomers via two steps: epoxidation with peracetic acid and isomerisation with aluminium triisopropoxide. For example, 2-methylene-6-methyl-7-octene-1-o1 was prepared from 2,6-dimethyl-1,7-octadiene. From 2,6-dimethyl-2,7-octadiene, 3,3,6-trimethyl-1,5-heptadiene, 2,7-dimethyl-2,6-octadiene, 2,6-dimethyl-1,3,6-octatriene, 1-methyl-4-isopropenyl-1-cyclohexene, and 1,5-dimethyl-1,5-cyclooctadiene, the corresponding alcohols were obtained, respectively. 相似文献
12.
Synthesis of Thermally Stable χ-Alumina by Thermal Decomposition of Aluminum Isopropoxide in Toluene
Okorn Mekasuwandumrong Hiroshi Kominami Piyasan Praserthdam Masashi Inoue 《Journal of the American Ceramic Society》2004,87(8):1543-1549
Thermal decomposition of aluminum isopropoxide in toluene at 315°C resulted in χ-alumina that had high thermal stability, whereas the reaction at lower temperatures resulted in formation of an amorphous product. The χ-alumina thus obtained directly transformed to α-alumina at ∼1150°C, bypassing the other transition alumina phases, whereas the amorphous product transformed to γ-alumina and then to θ-alumina before final transformation to α-alumina. When the χ-alumina, solvothermally synthesized at 315°C, was recovered by the removal of the solvent at the reaction temperature, thermal stability of the product was improved further. This procedure is convenient because it avoids bothersome work-up processes that yield large-surface-area and large-pore-volume alumina. 相似文献
13.
Tsutomu Osawa Masashi Ando Saori Sakai Tadao Harada Osamu Takayasu 《Catalysis Letters》2005,105(1-2):41-45
The role of acetic acid added to the reaction media for the enantio-differentiating hydrogenation of methyl acetoacetate over
a (R,R)-tartaric acid-in-situ-modified nickel catalyst was studied from the viewpoint of the hydrogenation rate during repeated
runs. The hydrogenation of methyl acetoacetate on the “enantio-differentiating sites” of a tartaric acid-modified nickel catalyst
was specifically accelerated by the acetic acid added to the reaction media to increase the enantio-differentiating ability
of the catalyst. In order to increase the enantio-differentiating ability, the addition of acetic acid to the reaction media
was required in each run during the repeated use of the catalyst. 相似文献
14.
Masahiro Tatsumisago Tsutomu Minami Masami Tanaka 《Journal of the American Ceramic Society》1981,64(7):97-C-
A new technique combining a thermal-image furnace and a twin roller is described for quenching the melt to form glass. The technique was applied to the simple system Li2 O-SiO2 , since its fundamental parameters in the estimation of critical cooling rate are available. Glass flakes were obtained in the composition Li4 SiO4 , for which a very large critical cooling rate (∼109 K·s−1 ) was needed for glass formation. 相似文献
15.
Reaction of N,N-di(β-hydroxyethyl)dithiocarbamate ion with poly(vinyl chloride) (PVC) was undertaken, and the reaction with metal ions of the polymer obtained was investigated. The effect of γ-irradiation on the reaction with metal ion was also studied. The modified PVC (PHDC) obtained from the reaction with N,N-di(β-hydroxyethyl)dithiocarbamate ion is pale yellow even after reaction at 100°C for 5 hr in dimethylformamide (DMF); it is soluble in dipolar solvents and its chlorine content is decreased considerably. This polymer reacted well with acetate salts of copper(II), nickel(II), zinc(II), and silver(I) heterogeneously in aqueous solution because of the introduction of hydrophilic groups (two hydroxy groups). The reactivity of the metal ions toward the polymer was of the order Ag(I) ? Cu(II) > Ni(II) > Zn(II). From the result of the reaction of γ-irradiated polymer with cupric ion, the polymer was judged to have fairly good antiradiation property. 相似文献
16.
This article reviews the enantio-differentiating hydrogenation of prochiral ketones over a asymmetrically modified catalyst, focusing on the hydrogenation of simple prochiral alkanones. The parameters affecting catalytic activity and enantiodifferentiating ability are considerable in number, and each parameter should be optimized in order to attain a highperformance enantio-differentiating catalyst. Optimization of the parameters and the mode of enantio-differentiation are discussed and compared with the enantio-differentiating hydrogenation of β-ketoesters. 相似文献
17.
Sarawut Rimdusit Wanpen Benjapan Suttichai Assabumrungrat Tsutomu Takeichi Rikio Yokota 《Polymer Engineering and Science》2007,47(4):489-498
Surface segregation in polymer blend systems between 3,3′,4,4′‐biphenyltetracarboxylic dianhydride/4,4′‐diaminodiphenyl ether (s‐BPDA/ODA) polyimide and block copolymer based on polysiloxane‐block‐polyimide (SPI) has been investigated. These polyimide blends, having various compositions of the SPI, were processed by a solution casting method. The glass substrate used in the film‐casting process shows significant effect on the migration of surface segregated species to enrich the air‐exposed surface, whereas the more polar s‐BPDA/ODA tends to remain close to the polar glass substrate. X‐ray photoelectron spectroscopy reveals that even at low SPI concentration, the siloxane moieties in the block copolymer tend to segregate into the air side surface. Contact angle measurement evidently indicates an enrichment of the hydrophobic siloxane fraction on the blend film surface. The average water contact angle of glass side surface is 77°C whereas that of the air side is about 102°C in every blend ratio. This behavior confirms the surface segregation phase separation in these polymer blends. Finally, the surface morphology observed by atomic force microscopy also suggests segregation type of phase separation in these blend systems. POLYM. ENG. SCI., 47:489–498, 2007. © 2007 Society of Plastics Engineers. 相似文献
18.
A metric of the 3D image quality of autostereoscopic displays based on optical measurements is proposed. This metric uses each view's luminance contrast, which is defined as the ratio of maximum luminance at each viewing position to total luminance at that position. Conventional metrics of the autostereoscopic display based on crosstalk, which uses “wanted” and “unwanted” lights. However, in case of the multiple‐views‐type autostereoscopic displays, it is difficult to distinguish exactly which lights are wanted lights and which are unwanted lights. This paper assumes that the wanted light has a maximum luminance at the good stereoscopic viewing position, and the unwanted light also has a maximum luminance at the worst pseudo‐stereoscopic viewing position. By using the maximum luminance that is indexed by view number of the autostereoscopic display, the proposed method enables characterizing stereoscopic viewing conditions without using wanted/unwanted light. A 3D image quality metric called “stereo luminance contrast,” the average of both eyes' contrast, is proposed. The effectiveness of the proposed metric is confirmed by the results of optical measurement analyses of different types of autostereoscopic displays, such as the two‐view, scan‐backlight, multi‐view, and integral. 相似文献
19.
20.
Yoshitsugu Kosugi Tsutomu Kunieda Naoki Azuma 《Journal of the American Oil Chemists' Society》1994,71(4):445-448
Rice bran oil containing 30–50% free fatty acid was continually converted to an oil containing more than 75% of triacylglycerol
(TG) by means of immobilized lipase. The reaction was carried out at 60°C for 24 h with dehydration and reactant mixing by
dry nitrogen flow under a positive nitrogen atmosphere. Enzymatic TG synthesis with evaporation by heating was not suitable
because of the increasing peroxide value of the oil.
Part of this article was presented at the annual meeting of the Japan Oil Chemists' Society at Sendai, Japan, October, 16,
1990. 相似文献