Robust digital control of a DC–DC buck converter with low frequency samplings

A robust DC?CDC converter which can covers extensive load change and also input voltage changes with one controller is needed. Then the demand to suppress output voltage change becomes still severer. We propose an approximate 2-degree-of-freedom (2DOF) digital controller which realized start-up response and dynamic load response independently. The controller makes a control bandwidth wider, and at the same time makes variations of the output voltage small at sudden changes of a load and an input voltage. In this paper, a new approximate 2DOF digital control system with additional zeros is proposed. Using the additional zeros, the second-order differential transfer characteristics between equivalent disturbances and a output voltage are realized. Therefore, the new controller makes variations of the output voltage smaller and the sudden changes of the load and the input voltage. This controller is actually implement on a DSP and is connected to the DC?CDC converter. Experimental results demonstrate that this type of digital controller can satisfy given severe specifications with low frequency sampling.     

Crystallization process and magnetic properties of Fe100−x,B x (10 ≦ × ≦ 35) amorphous alloys and supersaturated state of boron inα-Fe

Amorphous specimens of Fe_100–x B _x were prepared in the range 10 × 35 at % B by a single-roller method. The crystallization process and the boron concentration dependence of the Curie temperature were examined by differential scanning calorimetry, X-ray diffraction, Mössbauer spectroscopy and magnetic measurements. Two-step crystallization was observed in specimens with× < 17: amorphous amorphous + boron-supersaturated b c c phase (-Fe(B)) t-Fe₃B +-Fe. A single-Fe(B) phase was not observed. The transition temperature from t-Fe₃B to stable (-Fe + t-Fe₂B) sensitively depends on the boron content in the alloys. The crystallization temperature (T _x) of the amorphous alloys was almost unchanged for 17 × 31, but increased remarkably at high boron concentrations of× 33, where the decomposition products consisted of t-Fe₂B and o-FeB. The Curie temperature (T _c) of the amorphous phase was as low as 480 K at× = 10, increased with increasing boron content up to 820 K and then decreased in the high boron concentration alloys of× > 28. A single-Fe(B) phase was not detected in the as-quenched specimens of× = 8 and 10. The phase coexisted with the o-Fe₃B and amorphous phases. The lattice parameter of the phase was 0.2861₀ nm which was smaller than that of pure iron by 2/1000, indicating the substitutional occupation of boron atoms in the b c c lattice.     

Activities of FexO in CaO + CaF2 + SiO2 + FexO quaternary slags by disposable electrochemical oxygen probes

The activities of Fe_xO in CaO + CaF₂ + SiO₂ + Fe_xO quaternary slags were measured by means of solid-oxide galvanic cell. The Fe_xO activities in the slags are influenced by CaF₂ as well as SiO₂. At constant Fe_xO mole fractions, e.g., , at low SiO₂ mole fractions i.e., , the substitution of CaF₂ for CaO has an effect of raising the Fe_xO activity. At higher SiO₂ mole fractions, e.g., , however, such an effect becomes insignificant.     

CO2气体保护的激光焊接12mm厚低碳钢板

采用CO2 作为保护气体消除大熔深激光焊接低碳钢时易发生的气孔问题 ,并对比研究了CO2 和Ar气保护条件下 12mm厚低碳钢板激光焊缝的组织和韧性。焊接试验利用 4kWNd :YAG激光器 ,采用双面深熔焊的方法 ,焊接条件为 4kW激光功率和0 .3 ,0 .5m/min的焊接速度。冲击试验采用一种自行设计的带侧面缺口的三缺口冲击试样 ,以保证断裂全部发生在焊缝。结果表明 ,利用CO2 作保护气体焊接低碳钢板 ,可以有效消除大熔深激光焊接时的气孔问题 ,并获得比Ar气保护下硬度较低 ,冲击韧性高的焊缝。研究工作为解决大功率激光深熔焊时容易发生的气孔问题提供了一条有效途径     

铝合金局部加压凝固及流动数值模拟的研究

局部加压方法是压铸中用于消除铸件厚壁处缩孔缺陷的一种新工艺.本研究通过实验模型测量了不同加压条件下铸件的冷却曲线,分析了局部加压引起的凝固变化.考虑局部加压引起的补缩流动,通过适时修改网格文件、初始和边界条件的方法,模拟了局部加压过程中铝合金的凝固及流动变化,并与实验结果进行了对比,二者基本吻合.     

Approach from physicochemical aspects in membrane filtration

In membrane filtration, solution environment factors such as pH and solvent density are important in controlling the filtration rate and the rejection of the particles and/or the macromolecules. The filtration rate and the rejection in membrane filtration have been investigated from physicochemical aspects. It was shown that the properties of the filter cake formed on the membrane surface play a vital role in determining the filtration rate in mem-brane filtration. It was clearly demonstrated that such filtration behaviors as the filtration rate and the rejection are highly dependent on the electrical nature of the particles and/or the macromolecules. Furthermore, it was shown that the solvent density ρ has a large effect on the steady filtration rate in upward ultrafiltration.     

Interactions oftrans-cinnamic acid,its related phenolic allelochemicals,and abscisic acid in seedling growth and seed germination of lettuce

Phenolic compounds have been identified as the most common allelochemicals produced by higher plants. Inhibitions of cinnamic acid, its related phenolic derivatives, and abscisic acid (ABA) on seedling growth and seed germination of lettuce were studied.trans-Cinnamic acid, ando-,m-, andp-coumaric acids inhibited the growth of etiolated seedlings of lettuce at concentrations higher than 10^–4 M and seed germination above 10^–3 M. Coumarin inhibited seedling growth and seed germination at 10^–5 M or above. Chlorogenic acid inhibited seedling growth above 10^–4 M, but did not inhibit seed germination at 10^–5–5×10^–3 M. Low concentrations (below 10^–3 M) of caffeic and ferulic acids promoted the elongation of hypocotyls, but higher concentrations (over 10^–3 M) inhibited seedling growth and seed germination. These phenolic compounds and abscisic acid had additive inhibitory effects both on seedling growth and seed germination. The inhibition on lettuce was reversed by caffeic and ferulic acids at concentrations lower than 10^–3 M except for the inhibition of germination by coumarin. These results suggest that in naturetrans-cinnamic acid,o-, m-, p-coumaric acids, coumarin, and chlorogenic acid inhibit plant growth regardless of their concentration. However, caffeic and ferulic acids can either promote or inhibit plant growth according to their concentration.     

Phase Formation and Microstructure of Titanium Oxides and Composites Produced by Thermal Plasma Oxidation of Titanium Carbide

The phase formation and microstructure of titanium oxides and composites produced by Ar–O₂ thermal plasma oxidation of titanium carbide powders were investigated in detail by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Relationships between the phase compositions and microstructures of the oxides were established by combined structural and phase analyses, in correlation with synthesis conditions and phase formation mechanisms. It is revealed that vapor condensation favored the formation of anatase, which existed as smaller particles, while liquid/solid oxidation favored the formation of rutile, which appeared as larger particles or composites. A higher oxygen input in the plasma gases (Ar + O₂) enhanced the formation of anatase due to impeded oxidation and evaporation. A small amount of Ti₄O₇ and Ti₃O₅ was detected in the larger particles coexisting with rutile or TiC. These suboxides were formed as intermediates in solid oxidation of TiC or precipitated from the Ti–C–O melt during cooling. Furthermore, extensive cracks, dislocations and stresses were observed in the monolithic rutile and composites, in association with the rapid quenching in this high-temperature in-flight oxidation process.     

Association and physical gelation of ABA triblock copolymer in selective solvent

Association behavior and physical gelation mechanism of ABA triblock copolymer dissolved in B-selective solvent have been studied systematically from dilute to moderately concentrated solutions. Static and dynamic light scattering and nuclear magnetic resonance measurements for dilute solutions of poly(methyl methacrylate)-block-poly(tert-butyl acrylate)-block-poly(methyl methacrylate) (PMMA-PtBuA-PMMA) in 1-butanol (PtBuA selective solvent) indicated that PMMA-PtBuA-PMMA chains are molecularly dissolved above 50 °C. With decreasing temperature, the triblock copolymers form associated micelles consisting PMMA associated core and PtBuA shell. Linear dynamic viscoelastic measurements for solutions with moderate concentration (3.9-12.0 wt%) revealed that the system was viscous sol state at 60 °C. Drastic increase of shear storage modulus (G′) occurred with decreasing temperature, and at 25 °C, G′ showed rubbery plateau with weak frequency dependency, means the formation of elastic physical gel. The consistency between the temperature for micelle formation and that at the increase in G′ indicates that the physical gelation is owing to the network formation as the result of the association of PMMA chains and the bridging PtBuA chains connecting the PMMA cores. Master curves for the dynamic moduli were derived by time-temperature superposition along the frequency axis. Just above sol-gel transition concentration (C_gel), the master curves suggest the existence of fairy amount of aggregate that is not incorporated in the macroscopic network. With the increase in polymer concentration, the master curves become to reveal Maxwell-type viscoelasticity with narrow relaxation time distribution, suggesting the formation of transient network with easily generation and destruction of crosslinks. Concentration dependency of the plateau modulus is stronger than the theoretically expected, means the macroscopic transient network grows with polymer concentration by increasing the fraction of elastically effective bridging PtBuA chain above C_gel.