矿用自卸车车架的有限元分析及优化设计

根据某大型矿用自卸车车架的结构样式,建立了车架的有限元模型,并采用惯性释放法计算出不同工况下的车架应力分布情况。同时,对矿山上运行的矿车车架进行了应力测试。对比车架应力分布的实验结果和仿真结果,发现车架的应力误差基本上控制在10%以内,从而验证了有限元分析车架应力的有效性。为了改善车架的性能,设计了车架拓扑结构,并通过结构优化,得到了可靠的车架结构,最后通过仿真分析验证了改进后的车架性能有了大幅度提高。     

凹坑形貌对线接触摩擦副耐磨性的影响

在线接触摩擦副中,非光滑结构单元的凹坑、凸包、波纹、鳞片形态等表面凹坑形貌对其耐磨性有一定的影响,其中凹坑的直径、深度对耐磨性的影响十分显著。以圆形凹坑非光滑形貌为例,采用有限元仿真分析的方法,对非光滑表面凹坑不同直径和深度的磨损过程进行了分析,研究了仿生非光滑表面对摩擦副耐磨性影响的程度。研究结果表明:线性摩擦副工作过程中,凹坑间距为1 000 m的条件下,摩擦副表面的等效应力和摩擦力随着圆形凹坑直径的增大而增大,随其深度的增大而呈抛物线增长;且在凹坑直径为100 m、深度为300 m时,矩形块的耐磨性最优。     

土壤重金属污染评价与去除的可行性方法

利用克里金插值法绘制了重金属元素的空间浓度分布图;然后利用地积累指数法计算了城区各功能区重金属地积累指数的平均值及地积累指数分级频率;再以生活区为例,对土壤中各种重金属进行了相关性分析;最后探讨了重金属污染物在土壤中的累积预测方法和各种重金属去除的可行性方法。     

四川盆地海相页岩气富集条件及勘探开发有利区

历经十余年探索实践,四川盆地海相页岩气勘探取得了一系列进展,锁定五峰组—龙马溪组为最有利产层,提出了一批页岩气富集高产理论,形成了集地质评价、开发优化、优快钻井、体积压裂、工厂化作业、清洁开发等为一体的勘探开发技术,探明了万亿立方米级储量的页岩气大气田。时值中国页岩气勘探发展的重要节点,回顾四川盆地海相页岩气勘探开发历程、梳理五峰组—龙马溪组页岩气在地质条件与富集规律上的成果认识、展望四川盆地海相页岩气勘探的重点接替领域,对推进盆地海相页岩气的勘探开发有积极意义。(1)四川盆地海相页岩气勘探开发经历了4个阶段：评层选区找目标阶段;浅层至中—深层先导试验阶段;浅层至中—深层示范区建设阶段;浅层至中—深层上产、深层评价、常压页岩气评价、立体开发评价、超深层和新层系探索阶段。(2)四川盆地五峰组—龙马溪组的沉积条件优越,深水陆棚相高有机质含量页岩呈连续稳定分布;页岩气主要赋存在有机孔隙中,页岩储层在纵向上集中发育,连续厚度大;川南地区和川东南涪陵区块的构造相对简单,气源持续补给、远离古/今剥蚀区和大型断裂逸散区是页岩气富集保存的有利区;目前,五峰组—龙马溪组的页岩气资源量为33.19×10<...     

油气储运科技创新成果收益递进分成评估

油气储运业务的快速发展对科技创新提出更高要求,科学量化科技创新成果转化应用后取得的经济效益,成为激励创新、驱动发展的主要瓶颈与重大命题。借鉴要素分配、分享经济和收益分成理论,立足于油气储运科技创新成果价值贡献与创效方式、技术基本结构级序,建立科技创新成果收益递进分成评估方法。研究表明：（1）油气科技创新成果转化应用取得的总体经济效益是资本、劳动、技术和管理等生产要素协同作用的结果;（2）油气储运科技创新成果的收益分成率是核心参数,由技术要素分成基准值、技术要素收益递进分成基数、技术创新强度系数等关键参数确定;（3）三级技术要素递进分成基数是实现收益递进分成的关键工具;（4）单项技术的分成比例与技术自身创新创效能力、技术阶段等密切相关。实证表明,该方法可有效解决从总体到单一油气储运技术要素经济价值量化问题,为促进油气储运科技创新发展提供支持。     

Separation of propylene and propane with a microporous metal–organic framework via equilibrium-kinetic synergetic effect

Adsorption separation of olefin and paraffin can greatly lower the energy consumption associated with the currently utilized distillation technique but remains a great challenge. Herein, we report the efficient separation of propylene (C₃H₆) and propane (C₃H₈) in a phosphate anion-functionalized metal–organic framework (MOF) ZnAtzPO₄ by synergetic effect of equilibrium and kinetics. The material features periodically expanded and contracted apertures decorated with electronegative groups, offering eligible pore shape and pore chemistry to effectively trap C₃H₆ under moderate isosteric heat of adsorption (27.5 kJ mol⁻¹) while obstruct the diffusion of C₃H₈. It simultaneously combines excellent thermodynamic selectivity (uptake ratio of 1.71) and kinetic selectivity (~31) for C₃H₆/C₃H₈ separation, meanwhile can be easily regenerated. Breakthrough experiment for C₃H₆/C₃H₈ gas mixture was conducted and confirmed the outstanding separation capability of ZnAtzPO₄. The equilibrium and kinetics cooperative C₃H₆/C₃H₈ adsorption separation was for the first time found in anion-functionalized MOFs, and further confirmed by computational studies.     

Non-coalescence and chain formation of droplets under an alternating current electric field

The dynamic behaviors of two droplets and droplet cluster under an alternating current (AC) electric field are investigated. Two droplets generally undergo transformation from complete coalescence to partial coalescence and finally to non-coalescence as the electric capillary number Ca_p increases. The critical electric capillary number Ca_pc for complete coalescence in the AC electric field remains unchanged and is twice as large as that in the direct current (DC) electric field when the frequency f ≥ 250 Hz. Charge transfer and reversal of electric field result in the reversal of the direction of electric force, which is the fundamental mechanism of non-coalescence of two droplets and chain formation in droplet cluster. The number of rebounds dramatically increases as f increases, promoting the stability of droplet chain. The droplet chains in the high-frequency AC electric field are longer and more stable than those in the low-frequency AC electric field.     

Study of filtered interphase heat transfer using highly resolved CFD–DEM simulations

Accurately predicting the complex inhomogeneous heat transfer behavior in gas–solid fluidized beds is of fundamental importance. In this work, we constitute an enhanced filtered interphase heat transfer coefficient (IHTC) closure by systematically filtering the dataset from highly resolved three-dimensional (3D) computational fluid dynamics–discrete element model simulations. Particularly, effects of several potential filtered variable markers on filtered IHTC predictions are examined by statistical analysis. We reveal the formulated filtered IHTC correction closure manifests a systematic dependence on filtered interphase temperature difference as an additional marker. The proposed closure shows good agreement with the filtered fine-grid simulation data in an a priori analysis. Moreover, the difference of filtered IHTC corrections deduced from 3D Euler–Euler and Euler–Lagrange simulations is quantified. Finally, the comparative analysis between our proposed filtered IHTC formulation and those in literature is implemented. This work holds a potential to facilitate the development of thermal gas–solid flow modeling.     

Surface plasmon resonance-induced Ag-BaTiO3 composites for catalytic performance

Ferroelectric BaTiO₃ was combined with Ag nanoparticles for piezocatalytic and photocatalytic viewpoints. Microstructural characterization (X-ray diffraction and electron microscopy images) revealed that the Ag was successfully bounded with BaTiO₃. X-ray photoelectron spectrum also confirmed the presence of Ag. Further, its performance was examined for dye degradation under visible light (for photocatalysis) and ultrasonication (for piezocatalysis). In both the catalysis processes, there was a significant improvement in Ag-loaded BaTiO₃ sample-based catalytic reactions. Catalytic performance was evaluated for multiple cycles and was found consistent. Scavenger tests were also performed to understand catalytic reactions.     

Effect of zirconia content and particle size on the properties of 3D-printed alumina-based ceramic cores

Alumina-based ceramic cores are used to manufacture the internal structures of hollow alloy blades, requiring both high precision and moderate properties. In this work, zirconia is regarded as a promoter to improve the mechanical properties of sintered ceramic. The effect of zirconia content and particle size on the microstructure and mechanical properties of ceramics was evaluated. The results indicate that the flexural strength of sintered ceramics reached the maximum of 14.5 ± 0.5 MPa when 20 wt% micron-sized (10 μm) zirconia (agglomerate size, consistent with the alumina particle size) was added, and 26.5±2.5 MPa when 15 wt% 0.3 μm zirconia was added. Zirconia with submicron-sized (0.3 μm) particles effectively filled the pores between alumina particles, thus leading to the maximum flexural strength with a relatively low content. The corresponding sintered ceramics had a bulk density of 2.0 g/cm³ and open porosity of 59.6%.